Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/157968 |
Resumo: | Funding Information: This research was funded by the European Research Council (ERC) under the EU Horizon 2020 research and innovation program [grant reference SCENT-ERC-2014-STG-639123, 2015–2022, and Grant Agreement No. 101069405─ENSURE─ERC-2022-POC1]. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
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Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfactionelectronic nosegas sensinghybrid gelsionic liquidsionogelsElectronic, Optical and Magnetic MaterialsBiomaterialsPolymers and PlasticsMaterials ChemistryFunding Information: This research was funded by the European Research Council (ERC) under the EU Horizon 2020 research and innovation program [grant reference SCENT-ERC-2014-STG-639123, 2015–2022, and Grant Agreement No. 101069405─ENSURE─ERC-2022-POC1]. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.Ionogels and derived materials are assemblies of polymers and ionic liquids characterized by high stability and ionic conductivity, making them interesting choices as gas sensors. In this work, we assessed the effect of the ionic liquid moiety to generate ionogels and hybrid gels as electrical and optical gas sensors. Six ionic liquids consisting of a constant anion (chloride) and distinct cationic head groups were used to generate ionogels and hybrid gels and further tested as gas sensors in customized electronic nose devices. In general, ionogel-based sensors yielded higher classification accuracies of standard volatile organic compounds when compared to hybrid material-based sensors. In addition, the high chemical diversity of ionic liquids is further translated to a high functional diversity in analyte molecular recognition and sensing.UCIBIO - Applied Molecular Biosciences UnitDQ - Departamento de QuímicaRUNOliveira, Ana RitaRamou, EfthymiaPalma, Susana I. C. J.Esteves, CarinaBarbosa, ArménioRoque, Ana Cecília Afonso2023-09-18T22:13:52Z2023-11-082023-11-08T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttp://hdl.handle.net/10362/157968eng2694-2461PURE: 71845945https://doi.org/10.1021/acsmaterialsau.3c00042info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:40:15Zoai:run.unl.pt:10362/157968Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:56:56.008982Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| title |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| spellingShingle |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction Oliveira, Ana Rita electronic nose gas sensing hybrid gels ionic liquids ionogels Electronic, Optical and Magnetic Materials Biomaterials Polymers and Plastics Materials Chemistry |
| title_short |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| title_full |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| title_fullStr |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| title_full_unstemmed |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| title_sort |
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction |
| author |
Oliveira, Ana Rita |
| author_facet |
Oliveira, Ana Rita Ramou, Efthymia Palma, Susana I. C. J. Esteves, Carina Barbosa, Arménio Roque, Ana Cecília Afonso |
| author_role |
author |
| author2 |
Ramou, Efthymia Palma, Susana I. C. J. Esteves, Carina Barbosa, Arménio Roque, Ana Cecília Afonso |
| author2_role |
author author author author author |
| dc.contributor.none.fl_str_mv |
UCIBIO - Applied Molecular Biosciences Unit DQ - Departamento de Química RUN |
| dc.contributor.author.fl_str_mv |
Oliveira, Ana Rita Ramou, Efthymia Palma, Susana I. C. J. Esteves, Carina Barbosa, Arménio Roque, Ana Cecília Afonso |
| dc.subject.por.fl_str_mv |
electronic nose gas sensing hybrid gels ionic liquids ionogels Electronic, Optical and Magnetic Materials Biomaterials Polymers and Plastics Materials Chemistry |
| topic |
electronic nose gas sensing hybrid gels ionic liquids ionogels Electronic, Optical and Magnetic Materials Biomaterials Polymers and Plastics Materials Chemistry |
| description |
Funding Information: This research was funded by the European Research Council (ERC) under the EU Horizon 2020 research and innovation program [grant reference SCENT-ERC-2014-STG-639123, 2015–2022, and Grant Agreement No. 101069405─ENSURE─ERC-2022-POC1]. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023-09-18T22:13:52Z 2023-11-08 2023-11-08T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/157968 |
| url |
http://hdl.handle.net/10362/157968 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
2694-2461 PURE: 71845945 https://doi.org/10.1021/acsmaterialsau.3c00042 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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9 application/pdf |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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