Selective hydrolysis of wheat straw hemicellulose using high-pressure CO2 as catalyst 

• Autor(a) principal: Relvas, F.
• Data de Publicação: 2015
• Outros Autores: Morais, Ana Rita C., Lukasik, Rafal M.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/10400.9/2882
• topic: Hydrolysis; Lignocellulosic residues; Hemicellulose; Wheat Straw

The processing of wheat straw using high-pressure CO2–H2O technology was studied with the objective to evaluate the effect of CO2 as catalyst on the hydrothermal production of hemicellulose-derived sugars either as oligomers or as monomers. Also, the reduction of the crystallinity of the cellulose-rich fraction was assessed. Over a range of reaction conditions (0 to 50 bar of initial CO2 pressure and 0 to 45 minutes of holding time, at T ¼ 180 C), the addition of CO2 to water-based processes led to the in situ formation of carbonic acid, which allowed us to obtain a higher dissolution of wheat straw hemicellulose. Furthermore, this approach led to a xylo-oligosaccharide (XOS) rich fraction, yielding 79.6 g of XOS per 100 g of the initial xylan content (at 50 bar of initial CO2 pressure and 12 min of residence time) while the water-only process gave only 70.8 g of XOS per 100 g of initial xylan content. Furthermore, for higher pressures of CO2, a decrease in oligosaccharide content was found and was counterbalanced by production of monomer sugars, achieving a maximum of 5.7 g L1 at the severest condition.