Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]

Detalhes bibliográficos
Autor(a) principal: Mendes, Marta
Data de Publicação: 2017
Outros Autores: Da Costa Ribeiro, Ana Paula, Alegria, Elisabete, Martins, Luisa, Pombeiro, Armando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/6990
Resumo: A simple and mild (room temperature) process for oxidation of o-, m- or p-xylene to the corresponding methylbenzyl alcohols, tolualdehydes and toluic acids, using H2O2 (30% aqueous solution) and the iron(II) C-scorpionate [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) catalyst is presented. Remarkably, after 5 min of reaction an overall oxygenates yield of 22% (TOF = 1.3 × 102 h−1) was obtained. The effects of reaction parameters, such as reaction time, temperature, amount of catalyst, type and amount of oxidant are reported and discussed.
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spelling Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]XyleneOxidationScorpionateIronHydrogen peroxideA simple and mild (room temperature) process for oxidation of o-, m- or p-xylene to the corresponding methylbenzyl alcohols, tolualdehydes and toluic acids, using H2O2 (30% aqueous solution) and the iron(II) C-scorpionate [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) catalyst is presented. Remarkably, after 5 min of reaction an overall oxygenates yield of 22% (TOF = 1.3 × 102 h−1) was obtained. The effects of reaction parameters, such as reaction time, temperature, amount of catalyst, type and amount of oxidant are reported and discussed.ElsevierRCIPLMendes, MartaDa Costa Ribeiro, Ana PaulaAlegria, ElisabeteMartins, LuisaPombeiro, Armando2017-05-09T10:29:15Z2017-03-292017-03-29T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/6990engMENDES, Marta; [et al] – Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]. Polyhedron. ISSN . Vol. 125 (2017), pp. 151-1550277-5387https://doi.org/10.1016/j.poly.2016.10.037metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:52:28Zoai:repositorio.ipl.pt:10400.21/6990Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:16:02.195593Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
title Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
spellingShingle Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
Mendes, Marta
Xylene
Oxidation
Scorpionate
Iron
Hydrogen peroxide
title_short Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
title_full Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
title_fullStr Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
title_full_unstemmed Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
title_sort Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]
author Mendes, Marta
author_facet Mendes, Marta
Da Costa Ribeiro, Ana Paula
Alegria, Elisabete
Martins, Luisa
Pombeiro, Armando
author_role author
author2 Da Costa Ribeiro, Ana Paula
Alegria, Elisabete
Martins, Luisa
Pombeiro, Armando
author2_role author
author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Mendes, Marta
Da Costa Ribeiro, Ana Paula
Alegria, Elisabete
Martins, Luisa
Pombeiro, Armando
dc.subject.por.fl_str_mv Xylene
Oxidation
Scorpionate
Iron
Hydrogen peroxide
topic Xylene
Oxidation
Scorpionate
Iron
Hydrogen peroxide
description A simple and mild (room temperature) process for oxidation of o-, m- or p-xylene to the corresponding methylbenzyl alcohols, tolualdehydes and toluic acids, using H2O2 (30% aqueous solution) and the iron(II) C-scorpionate [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) catalyst is presented. Remarkably, after 5 min of reaction an overall oxygenates yield of 22% (TOF = 1.3 × 102 h−1) was obtained. The effects of reaction parameters, such as reaction time, temperature, amount of catalyst, type and amount of oxidant are reported and discussed.
publishDate 2017
dc.date.none.fl_str_mv 2017-05-09T10:29:15Z
2017-03-29
2017-03-29T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/6990
url http://hdl.handle.net/10400.21/6990
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv MENDES, Marta; [et al] – Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]. Polyhedron. ISSN . Vol. 125 (2017), pp. 151-155
0277-5387
https://doi.org/10.1016/j.poly.2016.10.037
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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