Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity

Detalhes bibliográficos
Autor(a) principal: Rauter, A.P.
Data de Publicação: 2004
Outros Autores: Canda, T., Justino, Jorge, Ismael, M.I., Figueiredo, J.A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.15/4376
Resumo: This work reports the synthesis of sugar epoxides and their derivatives obtained by reaction with the dianion of phenyl selenoacetic acid. Approaches to the introduction of α,β-unsaturated carbonyl units in pyranoid systems were investigated. Preparation of a protected D-glycero-hex-3-enepyranosid-2-ulose and of a D-erythro-hex-2-enono-1,5-lactone is described. Some of the synthesized compounds possess insecticidal activity against fruit flies, house flies, and white flies.
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spelling Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activitysugar epoxidesphenylseleno sugarsα,β-unsaturated carbonyl moietyinsecticidal activityThis work reports the synthesis of sugar epoxides and their derivatives obtained by reaction with the dianion of phenyl selenoacetic acid. Approaches to the introduction of α,β-unsaturated carbonyl units in pyranoid systems were investigated. Preparation of a protected D-glycero-hex-3-enepyranosid-2-ulose and of a D-erythro-hex-2-enono-1,5-lactone is described. Some of the synthesized compounds possess insecticidal activity against fruit flies, house flies, and white flies.Treaty of Windsor Programme, British Council, Ministério da Ciência e do Ensino SuperiorTaylor and FrancisRepositório Científico do Instituto Politécnico de SantarémRauter, A.P.Canda, T.Justino, JorgeIsmael, M.I.Figueiredo, J.A.2023-04-03T14:03:35Z20042004-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.15/4376engRauter, A.P.; Canda, T.; Justino, J.; Ismael, M.I. & Figueiredo, J.A. (2004) Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity. Journal of Carbohydrate Chemistry, 23(4): 239-251. https://doi.org/10.1081/CAR-2000300770732-8303https://doi.org/10.1081/CAR-200030077info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-21T07:37:46Zoai:repositorio.ipsantarem.pt:10400.15/4376Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:56:00.987856Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
title Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
spellingShingle Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
Rauter, A.P.
sugar epoxides
phenylseleno sugars
α,β-unsaturated carbonyl moiety
insecticidal activity
title_short Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
title_full Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
title_fullStr Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
title_full_unstemmed Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
title_sort Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity
author Rauter, A.P.
author_facet Rauter, A.P.
Canda, T.
Justino, Jorge
Ismael, M.I.
Figueiredo, J.A.
author_role author
author2 Canda, T.
Justino, Jorge
Ismael, M.I.
Figueiredo, J.A.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Repositório Científico do Instituto Politécnico de Santarém
dc.contributor.author.fl_str_mv Rauter, A.P.
Canda, T.
Justino, Jorge
Ismael, M.I.
Figueiredo, J.A.
dc.subject.por.fl_str_mv sugar epoxides
phenylseleno sugars
α,β-unsaturated carbonyl moiety
insecticidal activity
topic sugar epoxides
phenylseleno sugars
α,β-unsaturated carbonyl moiety
insecticidal activity
description This work reports the synthesis of sugar epoxides and their derivatives obtained by reaction with the dianion of phenyl selenoacetic acid. Approaches to the introduction of α,β-unsaturated carbonyl units in pyranoid systems were investigated. Preparation of a protected D-glycero-hex-3-enepyranosid-2-ulose and of a D-erythro-hex-2-enono-1,5-lactone is described. Some of the synthesized compounds possess insecticidal activity against fruit flies, house flies, and white flies.
publishDate 2004
dc.date.none.fl_str_mv 2004
2004-01-01T00:00:00Z
2023-04-03T14:03:35Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.15/4376
url http://hdl.handle.net/10400.15/4376
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Rauter, A.P.; Canda, T.; Justino, J.; Ismael, M.I. & Figueiredo, J.A. (2004) Synthesis of phenylseleno sugars from epoxides and of α,β-unsaturated carbonyl derivatives for the study of their insecticidal activity. Journal of Carbohydrate Chemistry, 23(4): 239-251. https://doi.org/10.1081/CAR-200030077
0732-8303
https://doi.org/10.1081/CAR-200030077
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Taylor and Francis
publisher.none.fl_str_mv Taylor and Francis
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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