Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]

Detalhes bibliográficos
Autor(a) principal: Alegria, Elisabete
Data de Publicação: 2005
Outros Autores: Martins, Luisa, Guedes Da Silva, M. Fátima C., Pombeiro, Armando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/12079
Resumo: The complexes [ReCl2{N2C(O)Ph}(Hpz)(PPh3)2] (1) (Hpz = pyrazole), [ReCl2{N2C(O)Ph}(Hpz)2(PPh3)] (2), [ReCl2(HCpz3)(PPh3)][BF4] (3) and [ReCl2(3,5-Me2Hpz)3(PPh3)]Cl (4) were obtained by treatment of the chelate [ReCl2{η2-N,O–N2C(O)Ph}(PPh3)2] (0) with hydrotris(1-pyrazolyl)methane HCpz3 (1,3), pyrazole Hpz (1,2), hydrotris(3,5-dimethyl-1-pyrazolyl)methane HC(3,5-Me2pz)3 (4) or dimethylpyrazole 3,5-Me2Hpz (4). Rupture of a C(sp3)–N bond in HCpz3 or HC(3,5-Me2pz)3, promoted by the Re centre, has occurred in the formation of 1 or 4, respectively. All compounds have been characterized by elemental analyses, IR and NMR spectroscopy, FAB-MS spectrometry, cyclic voltammetry and, for 1 · CH2Cl2 and 3, also by single crystal X-ray analysis. The electrochemical EL Lever parameter has been estimated, for the first time, for the HCpz3 and the benzoyldiazenide NNC(O)Ph ligands.
id RCAP_d8af55b73c934dd1d4cf0038a7b9bf98
oai_identifier_str oai:repositorio.ipl.pt:10400.21/12079
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]RheniumHydrotris(1-pyrazolyl)methanePyrazoleHydrazideDiazenideElectrochemistryThe complexes [ReCl2{N2C(O)Ph}(Hpz)(PPh3)2] (1) (Hpz = pyrazole), [ReCl2{N2C(O)Ph}(Hpz)2(PPh3)] (2), [ReCl2(HCpz3)(PPh3)][BF4] (3) and [ReCl2(3,5-Me2Hpz)3(PPh3)]Cl (4) were obtained by treatment of the chelate [ReCl2{η2-N,O–N2C(O)Ph}(PPh3)2] (0) with hydrotris(1-pyrazolyl)methane HCpz3 (1,3), pyrazole Hpz (1,2), hydrotris(3,5-dimethyl-1-pyrazolyl)methane HC(3,5-Me2pz)3 (4) or dimethylpyrazole 3,5-Me2Hpz (4). Rupture of a C(sp3)–N bond in HCpz3 or HC(3,5-Me2pz)3, promoted by the Re centre, has occurred in the formation of 1 or 4, respectively. All compounds have been characterized by elemental analyses, IR and NMR spectroscopy, FAB-MS spectrometry, cyclic voltammetry and, for 1 · CH2Cl2 and 3, also by single crystal X-ray analysis. The electrochemical EL Lever parameter has been estimated, for the first time, for the HCpz3 and the benzoyldiazenide NNC(O)Ph ligands.ElsevierRCIPLAlegria, ElisabeteMartins, LuisaGuedes Da Silva, M. Fátima C.Pombeiro, Armando2020-07-22T17:20:47Z2005-04-152005-04-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/12079engALEGRIA, Elisabete C. B. A.; [et al] – Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]. Journal of Organometallic Chemistry. ISSN 0022-328X. Vol. 690, N.º 8 (2005), pp. 1947-19580022-328X10.1016/j.jorganchem.2004.11.005metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T10:04:21Zoai:repositorio.ipl.pt:10400.21/12079Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:20:14.371873Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
title Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
spellingShingle Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
Alegria, Elisabete
Rhenium
Hydrotris(1-pyrazolyl)methane
Pyrazole
Hydrazide
Diazenide
Electrochemistry
title_short Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
title_full Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
title_fullStr Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
title_full_unstemmed Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
title_sort Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]
author Alegria, Elisabete
author_facet Alegria, Elisabete
Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
author_role author
author2 Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
author2_role author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Alegria, Elisabete
Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
dc.subject.por.fl_str_mv Rhenium
Hydrotris(1-pyrazolyl)methane
Pyrazole
Hydrazide
Diazenide
Electrochemistry
topic Rhenium
Hydrotris(1-pyrazolyl)methane
Pyrazole
Hydrazide
Diazenide
Electrochemistry
description The complexes [ReCl2{N2C(O)Ph}(Hpz)(PPh3)2] (1) (Hpz = pyrazole), [ReCl2{N2C(O)Ph}(Hpz)2(PPh3)] (2), [ReCl2(HCpz3)(PPh3)][BF4] (3) and [ReCl2(3,5-Me2Hpz)3(PPh3)]Cl (4) were obtained by treatment of the chelate [ReCl2{η2-N,O–N2C(O)Ph}(PPh3)2] (0) with hydrotris(1-pyrazolyl)methane HCpz3 (1,3), pyrazole Hpz (1,2), hydrotris(3,5-dimethyl-1-pyrazolyl)methane HC(3,5-Me2pz)3 (4) or dimethylpyrazole 3,5-Me2Hpz (4). Rupture of a C(sp3)–N bond in HCpz3 or HC(3,5-Me2pz)3, promoted by the Re centre, has occurred in the formation of 1 or 4, respectively. All compounds have been characterized by elemental analyses, IR and NMR spectroscopy, FAB-MS spectrometry, cyclic voltammetry and, for 1 · CH2Cl2 and 3, also by single crystal X-ray analysis. The electrochemical EL Lever parameter has been estimated, for the first time, for the HCpz3 and the benzoyldiazenide NNC(O)Ph ligands.
publishDate 2005
dc.date.none.fl_str_mv 2005-04-15
2005-04-15T00:00:00Z
2020-07-22T17:20:47Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/12079
url http://hdl.handle.net/10400.21/12079
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv ALEGRIA, Elisabete C. B. A.; [et al] – Syntheses and properties of Re(III) complexes derived from hydrotris(1-pyrazolyl)methanes: molecular structure of [ReCl2(HCpz3)(PPh3)][BF4]. Journal of Organometallic Chemistry. ISSN 0022-328X. Vol. 690, N.º 8 (2005), pp. 1947-1958
0022-328X
10.1016/j.jorganchem.2004.11.005
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799133471538413568

Registros relacionados