Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/117156 |
Resumo: | UID/QUI/50006/2019 |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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7160 |
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Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranesChitosan membranesChromium recoveryNanofiltrationReverse osmosisTannery effluentChemical Engineering (miscellaneous)Process Chemistry and TechnologyFiltration and SeparationSDG 6 - Clean Water and SanitationSDG 11 - Sustainable Cities and CommunitiesUID/QUI/50006/2019The objective of this work is to develop an appropriate technology for environmentally sound membrane-based purification of a tannery effluent assuring, simultaneously, the recovery of chromium, considered as the most hazardous inorganic water pollutant extensively used in leather tanning. A comparison between the permeate fluxes obtained during treatment of a synthetic tannery effluent through nanofiltration (NF270 and NF90 membranes) and reverse osmosis (BW30 and SW30) membranes was first performed. Then, a dedicated polymeric membrane was prepared by coating chitosan (cs) on a polyethersulfone (PES) microfiltration membrane (cs-PES MFO22) support. The resulting membrane was characterized by Fourier Transforms Infrared Spectroscopy Attenuated Total Reflectance (FTIR-ATR), Emission Scanning Electronic Microscopy (SEM) to confirm the process of surface modification and cross-linking of chitosan with glutaraldehyde. This membrane was found to be highly effective for chromium removal (>99%), which was more than eight times higher in reference to monovalent cations (e.g., Na+ and K+) and more than six times higher in reference to the divalent cations (Mg2+ and Ca2+) studied. The reverse osmosis permeate conforms to local Algerian regulations regarding being discharged directly into the natural environment (in this case, Reghaia Lake) or into urban sewers linked to wastewater biological treatment stations. While the SW30 membrane proved to be the most effective for purification of the tannery effluent, the chitosan modified membrane proved to be appropriate for recovery of chromium from the reverse osmosis concentrate.DQ - Departamento de QuímicaLAQV@REQUIMTERUNZakmout, AsmaaSadi, FatmaPortugal, Carla A. M.Crespo, João G.Velizarov, Svetlozar2021-05-05T23:27:36Z2020-11-282020-11-28T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article20application/pdfhttp://hdl.handle.net/10362/117156eng0076-6356PURE: 28469134https://doi.org/10.3390/membranes10120378info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:00:13Zoai:run.unl.pt:10362/117156Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:43:30.472925Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
title |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
spellingShingle |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes Zakmout, Asmaa Chitosan membranes Chromium recovery Nanofiltration Reverse osmosis Tannery effluent Chemical Engineering (miscellaneous) Process Chemistry and Technology Filtration and Separation SDG 6 - Clean Water and Sanitation SDG 11 - Sustainable Cities and Communities |
title_short |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
title_full |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
title_fullStr |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
title_full_unstemmed |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
title_sort |
Tannery effluent treatment by nanofiltration, reverse osmosis and chitosan modified membranes |
author |
Zakmout, Asmaa |
author_facet |
Zakmout, Asmaa Sadi, Fatma Portugal, Carla A. M. Crespo, João G. Velizarov, Svetlozar |
author_role |
author |
author2 |
Sadi, Fatma Portugal, Carla A. M. Crespo, João G. Velizarov, Svetlozar |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
DQ - Departamento de Química LAQV@REQUIMTE RUN |
dc.contributor.author.fl_str_mv |
Zakmout, Asmaa Sadi, Fatma Portugal, Carla A. M. Crespo, João G. Velizarov, Svetlozar |
dc.subject.por.fl_str_mv |
Chitosan membranes Chromium recovery Nanofiltration Reverse osmosis Tannery effluent Chemical Engineering (miscellaneous) Process Chemistry and Technology Filtration and Separation SDG 6 - Clean Water and Sanitation SDG 11 - Sustainable Cities and Communities |
topic |
Chitosan membranes Chromium recovery Nanofiltration Reverse osmosis Tannery effluent Chemical Engineering (miscellaneous) Process Chemistry and Technology Filtration and Separation SDG 6 - Clean Water and Sanitation SDG 11 - Sustainable Cities and Communities |
description |
UID/QUI/50006/2019 |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-11-28 2020-11-28T00:00:00Z 2021-05-05T23:27:36Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/117156 |
url |
http://hdl.handle.net/10362/117156 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0076-6356 PURE: 28469134 https://doi.org/10.3390/membranes10120378 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
20 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1799138044605890560 |