Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005 |
Resumo: | The effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface. |
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Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solutionazo dyesmild steelinhibitorssurface morphologyThe effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface.Sociedade Portuguesa de Electroquímica2013-03-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005Portugaliae Electrochimica Acta v.31 n.2 2013reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005Nagiub,A.M.Mahross,M.H.Khalil,H.F.Y.Mahran,B.N.A.Yehia,M.M.El-Sabbah,M.M.B.info:eu-repo/semantics/openAccess2024-02-06T17:07:13Zoai:scielo:S0872-19042013000200005Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:13.900138Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
title |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
spellingShingle |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution Nagiub,A.M. azo dyes mild steel inhibitors surface morphology |
title_short |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
title_full |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
title_fullStr |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
title_full_unstemmed |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
title_sort |
Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution |
author |
Nagiub,A.M. |
author_facet |
Nagiub,A.M. Mahross,M.H. Khalil,H.F.Y. Mahran,B.N.A. Yehia,M.M. El-Sabbah,M.M.B. |
author_role |
author |
author2 |
Mahross,M.H. Khalil,H.F.Y. Mahran,B.N.A. Yehia,M.M. El-Sabbah,M.M.B. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Nagiub,A.M. Mahross,M.H. Khalil,H.F.Y. Mahran,B.N.A. Yehia,M.M. El-Sabbah,M.M.B. |
dc.subject.por.fl_str_mv |
azo dyes mild steel inhibitors surface morphology |
topic |
azo dyes mild steel inhibitors surface morphology |
description |
The effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-03-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.31 n.2 2013 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137290992222208 |