Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution

Detalhes bibliográficos
Autor(a) principal: Nagiub,A.M.
Data de Publicação: 2013
Outros Autores: Mahross,M.H., Khalil,H.F.Y., Mahran,B.N.A., Yehia,M.M., El-Sabbah,M.M.B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005
Resumo: The effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface.
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spelling Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solutionazo dyesmild steelinhibitorssurface morphologyThe effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface.Sociedade Portuguesa de Electroquímica2013-03-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005Portugaliae Electrochimica Acta v.31 n.2 2013reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005Nagiub,A.M.Mahross,M.H.Khalil,H.F.Y.Mahran,B.N.A.Yehia,M.M.El-Sabbah,M.M.B.info:eu-repo/semantics/openAccess2024-02-06T17:07:13Zoai:scielo:S0872-19042013000200005Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:13.900138Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
title Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
spellingShingle Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
Nagiub,A.M.
azo dyes
mild steel
inhibitors
surface morphology
title_short Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
title_full Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
title_fullStr Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
title_full_unstemmed Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
title_sort Azo Dye Compounds as Corrosion Inhibitors for Dissolution of Mild Steel in Hydrochloric Acid Solution
author Nagiub,A.M.
author_facet Nagiub,A.M.
Mahross,M.H.
Khalil,H.F.Y.
Mahran,B.N.A.
Yehia,M.M.
El-Sabbah,M.M.B.
author_role author
author2 Mahross,M.H.
Khalil,H.F.Y.
Mahran,B.N.A.
Yehia,M.M.
El-Sabbah,M.M.B.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Nagiub,A.M.
Mahross,M.H.
Khalil,H.F.Y.
Mahran,B.N.A.
Yehia,M.M.
El-Sabbah,M.M.B.
dc.subject.por.fl_str_mv azo dyes
mild steel
inhibitors
surface morphology
topic azo dyes
mild steel
inhibitors
surface morphology
description The effect of some mono-, bis- and tris-azo dyes compounds on the dissolution of mild steel in 1.0 M HCl solution was studied using weight loss and potentiodynamic polarization measurements. The inhibition efficiency was found to increase with increasing concentration of the inhibitors and with decreasing temperature. The adsorption of different azo dyes on the mild steel surface obeys the Langmuir adsorption isotherm. Polarization studies indicate that the compounds used are mixed type inhibitors. The thermodynamic functions of adsorption processes were calculated from weight loss at different temperatures data and were used to analyze the inhibitor mechanism. The surface morphology of the mild steel specimens was evaluated using SEM and EDAX analysis. To provide an evidence for the formation of the complex, UV-VIS spectra of solutions were investigated. From previous results (I.E.%, ΔGads, SEM, EDAX and UV-VIS spectra) are likely to get into the possiblity of configure the complex on the mild steel surface.
publishDate 2013
dc.date.none.fl_str_mv 2013-03-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042013000200005
dc.language.iso.fl_str_mv eng
language eng
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dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.31 n.2 2013
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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