Vanadium complexes: recent progress in oxidation catalysis
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.21/5856 |
Resumo: | Oxidovanadium complexes and, to a less extent, some non-oxido ones, are widely used as catalysts or catalyst precursors for various oxidative catalytic reactions by H2O2, (BuOOH)-Bu-t or O-2 under mild conditions. Oxidation reactions (oxidation of alkanes and alcohols, epoxidation of alkenes and allylic alcohols, oxidative bromination, sulfoxidation and oxidative Strecker reactions) of organic compounds are the most relevant ones and are reviewed considering the recent advances in the last five years (2010-2014). The main types of both homogeneous and supported vanadium catalysts and the most efficient catalytic systems in the different reactions are presented and compared. The proposed mechanisms of various catalytic oxidation processes are also outlined. (C) 2015 Elsevier B.V. All rights reserved. |
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Vanadium complexes: recent progress in oxidation catalysisOxidovanadium complexesOxidation of alkanesOxidation of alcoholsEpoxidationSulfoxidationHomogeneous and supported catalysisOxidovanadium complexes and, to a less extent, some non-oxido ones, are widely used as catalysts or catalyst precursors for various oxidative catalytic reactions by H2O2, (BuOOH)-Bu-t or O-2 under mild conditions. Oxidation reactions (oxidation of alkanes and alcohols, epoxidation of alkenes and allylic alcohols, oxidative bromination, sulfoxidation and oxidative Strecker reactions) of organic compounds are the most relevant ones and are reviewed considering the recent advances in the last five years (2010-2014). The main types of both homogeneous and supported vanadium catalysts and the most efficient catalytic systems in the different reactions are presented and compared. The proposed mechanisms of various catalytic oxidation processes are also outlined. (C) 2015 Elsevier B.V. All rights reserved.Elsevier Science SARCIPLSutradhar, ManasMartins, LuisaGuedes Da Silva, M. Fátima C.Pombeiro, Armando2016-03-14T15:10:55Z2015-10-152015-10-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/5856engSUTRADHAR,Manas; [et al.] - Vanadium complexes: recent progress in oxidation catalysis. Coordination Chemistry Reviews. ISSN.0010-8545. Vol. 301, SI (2015), pp. 200-2390010-854510.1016/j.ccr.2015.01.020metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:49:53Zoai:repositorio.ipl.pt:10400.21/5856Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:15:04.786509Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Vanadium complexes: recent progress in oxidation catalysis |
title |
Vanadium complexes: recent progress in oxidation catalysis |
spellingShingle |
Vanadium complexes: recent progress in oxidation catalysis Sutradhar, Manas Oxidovanadium complexes Oxidation of alkanes Oxidation of alcohols Epoxidation Sulfoxidation Homogeneous and supported catalysis |
title_short |
Vanadium complexes: recent progress in oxidation catalysis |
title_full |
Vanadium complexes: recent progress in oxidation catalysis |
title_fullStr |
Vanadium complexes: recent progress in oxidation catalysis |
title_full_unstemmed |
Vanadium complexes: recent progress in oxidation catalysis |
title_sort |
Vanadium complexes: recent progress in oxidation catalysis |
author |
Sutradhar, Manas |
author_facet |
Sutradhar, Manas Martins, Luisa Guedes Da Silva, M. Fátima C. Pombeiro, Armando |
author_role |
author |
author2 |
Martins, Luisa Guedes Da Silva, M. Fátima C. Pombeiro, Armando |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
RCIPL |
dc.contributor.author.fl_str_mv |
Sutradhar, Manas Martins, Luisa Guedes Da Silva, M. Fátima C. Pombeiro, Armando |
dc.subject.por.fl_str_mv |
Oxidovanadium complexes Oxidation of alkanes Oxidation of alcohols Epoxidation Sulfoxidation Homogeneous and supported catalysis |
topic |
Oxidovanadium complexes Oxidation of alkanes Oxidation of alcohols Epoxidation Sulfoxidation Homogeneous and supported catalysis |
description |
Oxidovanadium complexes and, to a less extent, some non-oxido ones, are widely used as catalysts or catalyst precursors for various oxidative catalytic reactions by H2O2, (BuOOH)-Bu-t or O-2 under mild conditions. Oxidation reactions (oxidation of alkanes and alcohols, epoxidation of alkenes and allylic alcohols, oxidative bromination, sulfoxidation and oxidative Strecker reactions) of organic compounds are the most relevant ones and are reviewed considering the recent advances in the last five years (2010-2014). The main types of both homogeneous and supported vanadium catalysts and the most efficient catalytic systems in the different reactions are presented and compared. The proposed mechanisms of various catalytic oxidation processes are also outlined. (C) 2015 Elsevier B.V. All rights reserved. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-10-15 2015-10-15T00:00:00Z 2016-03-14T15:10:55Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.21/5856 |
url |
http://hdl.handle.net/10400.21/5856 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
SUTRADHAR,Manas; [et al.] - Vanadium complexes: recent progress in oxidation catalysis. Coordination Chemistry Reviews. ISSN.0010-8545. Vol. 301, SI (2015), pp. 200-239 0010-8545 10.1016/j.ccr.2015.01.020 |
dc.rights.driver.fl_str_mv |
metadata only access info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
metadata only access |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science SA |
publisher.none.fl_str_mv |
Elsevier Science SA |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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