A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica

Detalhes bibliográficos
Autor(a) principal: Granadeiro, Carlos
Data de Publicação: 2016
Outros Autores: Ribeiro, Susana, Kaczmarek, Anna M., Cunha-Silva, Luis, Almeida, Pedro L., Gago, Sandra, Van Deun, Rik, De Castro, Baltazar, Balula, Salete
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/7145
Resumo: The first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)(2)](9-)) within the porous channels of an ethylene-bridged TIVIAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper.
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spelling A novel red emitting material based on polyoxometalate@periodic mesoporous organosilicaPolyoxometalateMesoporous silicaCompositeLuminescenceLanthanideThe first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)(2)](9-)) within the porous channels of an ethylene-bridged TIVIAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper.ElsevierRCIPLGranadeiro, CarlosRibeiro, SusanaKaczmarek, Anna M.Cunha-Silva, LuisAlmeida, Pedro L.Gago, SandraVan Deun, RikDe Castro, BaltazarBalula, Salete2017-06-05T10:02:52Z2016-112016-11-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/7145engGranadeiro, Carlos M. [et al] - A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica. Microporous and Mesoporous Materials. ISSN: 1387-1811. Vol. 234,(novembro2016), pp. 248-256ISSN: 1387-181110.1016/j.micromeso.2016.07.023metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:52:50Zoai:repositorio.ipl.pt:10400.21/7145Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:16:09.317600Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
title A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
spellingShingle A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
Granadeiro, Carlos
Polyoxometalate
Mesoporous silica
Composite
Luminescence
Lanthanide
title_short A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
title_full A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
title_fullStr A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
title_full_unstemmed A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
title_sort A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
author Granadeiro, Carlos
author_facet Granadeiro, Carlos
Ribeiro, Susana
Kaczmarek, Anna M.
Cunha-Silva, Luis
Almeida, Pedro L.
Gago, Sandra
Van Deun, Rik
De Castro, Baltazar
Balula, Salete
author_role author
author2 Ribeiro, Susana
Kaczmarek, Anna M.
Cunha-Silva, Luis
Almeida, Pedro L.
Gago, Sandra
Van Deun, Rik
De Castro, Baltazar
Balula, Salete
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Granadeiro, Carlos
Ribeiro, Susana
Kaczmarek, Anna M.
Cunha-Silva, Luis
Almeida, Pedro L.
Gago, Sandra
Van Deun, Rik
De Castro, Baltazar
Balula, Salete
dc.subject.por.fl_str_mv Polyoxometalate
Mesoporous silica
Composite
Luminescence
Lanthanide
topic Polyoxometalate
Mesoporous silica
Composite
Luminescence
Lanthanide
description The first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)(2)](9-)) within the porous channels of an ethylene-bridged TIVIAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper.
publishDate 2016
dc.date.none.fl_str_mv 2016-11
2016-11-01T00:00:00Z
2017-06-05T10:02:52Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/7145
url http://hdl.handle.net/10400.21/7145
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Granadeiro, Carlos M. [et al] - A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica. Microporous and Mesoporous Materials. ISSN: 1387-1811. Vol. 234,(novembro2016), pp. 248-256
ISSN: 1387-1811
10.1016/j.micromeso.2016.07.023
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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