Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2022 |
| Outros Autores: | , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/145599 |
Resumo: | the contracts of Individual Call to Scientific Employment Stimulus 2020.00835.CEECIND (J.M.M.A.) / 2021.01432.CEECIND (A.B.P.), the Norma Transitória DL 57/2016. Publisher Copyright: © 2022 The Authors. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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7160 |
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Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquidsFluorinated compoundsPorous solid materialsRefrigerantsSeparationSolubilizationChemical Engineering (miscellaneous)Waste Management and DisposalPollutionProcess Chemistry and Technologythe contracts of Individual Call to Scientific Employment Stimulus 2020.00835.CEECIND (J.M.M.A.) / 2021.01432.CEECIND (A.B.P.), the Norma Transitória DL 57/2016. Publisher Copyright: © 2022 The Authors.The Kigali Amendment to the Montreal Protocol limits the global use of fluorinated greenhouse gases (F-gases) and encourages the development of a new generation of refrigerants with lower global warming potential. Therefore, there is a need to develop efficient and sustainable technologies to selectively capture and recycle the F-gases as new environmentally sustainable refrigerants. Here, ionic liquids (ILs) with high F-gas uptake capacity and selectivity were supported on silica and their potential as media for selective F-gas sorption was studied. For this purpose single-component sorption equilibria of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a) were measured at 303.15 K by gravimetry. The sorption data were successfully correlated using classical models of sorption thermodynamics. The results show that the IL supported in the porous volume and on the external surface of the porous silica controls the F-gas uptake in the composites and that changing the IL's cations and anions allows fine-tuning the selectivity of the sorption process. This work brings crucial knowledge for the development of new materials based on ILs for the selective sorption of F-gases.DQ - Departamento de QuímicaLAQV@REQUIMTERUNSosa, Julio E.Ribeiro, Rui P. P. L.Castro, Paulo J.Mota, José P. B.Pereiro, Ana B.Araújo, João M. M.2022-11-17T22:13:01Z2022-122022-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article9application/pdfhttp://hdl.handle.net/10362/145599eng2213-3437PURE: 47016026https://doi.org/10.1016/j.jece.2022.108580info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:26:08Zoai:run.unl.pt:10362/145599Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:52:10.142227Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| title |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| spellingShingle |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids Sosa, Julio E. Fluorinated compounds Porous solid materials Refrigerants Separation Solubilization Chemical Engineering (miscellaneous) Waste Management and Disposal Pollution Process Chemistry and Technology |
| title_short |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| title_full |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| title_fullStr |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| title_full_unstemmed |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| title_sort |
Sorption of fluorinated greenhouse gases in silica-supported fluorinated ionic liquids |
| author |
Sosa, Julio E. |
| author_facet |
Sosa, Julio E. Ribeiro, Rui P. P. L. Castro, Paulo J. Mota, José P. B. Pereiro, Ana B. Araújo, João M. M. |
| author_role |
author |
| author2 |
Ribeiro, Rui P. P. L. Castro, Paulo J. Mota, José P. B. Pereiro, Ana B. Araújo, João M. M. |
| author2_role |
author author author author author |
| dc.contributor.none.fl_str_mv |
DQ - Departamento de Química LAQV@REQUIMTE RUN |
| dc.contributor.author.fl_str_mv |
Sosa, Julio E. Ribeiro, Rui P. P. L. Castro, Paulo J. Mota, José P. B. Pereiro, Ana B. Araújo, João M. M. |
| dc.subject.por.fl_str_mv |
Fluorinated compounds Porous solid materials Refrigerants Separation Solubilization Chemical Engineering (miscellaneous) Waste Management and Disposal Pollution Process Chemistry and Technology |
| topic |
Fluorinated compounds Porous solid materials Refrigerants Separation Solubilization Chemical Engineering (miscellaneous) Waste Management and Disposal Pollution Process Chemistry and Technology |
| description |
the contracts of Individual Call to Scientific Employment Stimulus 2020.00835.CEECIND (J.M.M.A.) / 2021.01432.CEECIND (A.B.P.), the Norma Transitória DL 57/2016. Publisher Copyright: © 2022 The Authors. |
| publishDate |
2022 |
| dc.date.none.fl_str_mv |
2022-11-17T22:13:01Z 2022-12 2022-12-01T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/145599 |
| url |
http://hdl.handle.net/10362/145599 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
2213-3437 PURE: 47016026 https://doi.org/10.1016/j.jece.2022.108580 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
9 application/pdf |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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