Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10198/1132 |
Resumo: | Different types of carbon materials including multi-walled nanotubes (MWNT), carbon xerogels (CX) and activated carbon (AC) were used as supports to prepare platinum catalysts (1% w/w), which were tested in the treatment of aqueous aniline solutions by catalytic wet air oxidation (CWAO). The prepared materials and catalysts were characterized by several techniques (SEM/EDS, TEM, N2 adsorption, TPD and H2 chemisorption). All catalysts presented a very high activity for the removal of aniline and total organic carbon (TOC). Catalyst activity and selectivity toward CO2 formation were found to depend on the nature of the support and concentration of oxygen containing functional groups on the surface of the materials. |
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Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applicationsMulti-walled carbon nanotubes (MWNT)Carbon xerogelsActivated carbonCarbon supported catalystsCatalytic wet air oxidation (CWAO)AnilineDifferent types of carbon materials including multi-walled nanotubes (MWNT), carbon xerogels (CX) and activated carbon (AC) were used as supports to prepare platinum catalysts (1% w/w), which were tested in the treatment of aqueous aniline solutions by catalytic wet air oxidation (CWAO). The prepared materials and catalysts were characterized by several techniques (SEM/EDS, TEM, N2 adsorption, TPD and H2 chemisorption). All catalysts presented a very high activity for the removal of aniline and total organic carbon (TOC). Catalyst activity and selectivity toward CO2 formation were found to depend on the nature of the support and concentration of oxygen containing functional groups on the surface of the materials.ElsevierBiblioteca Digital do IPBGomes, HelderSamant, PurnakalaSerp, PhilippeKalck, PhilippeFigueiredo, JoséFaria, Joaquim2009-03-27T11:30:10Z20042004-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/1132engengGomes, Helder; Samant, Purnakala; Serp, Philippe; Kalck, Philippe; Figueiredo, José; Faria, Joaquim (2004). Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications. Applied Catalysis B: Environmental. ISSN 0926-3373. 54:3, p.175-1820926-3373Applied Catalysis B: Environmental10.1016/j.apcatb.2004.06.009info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:04:28Zoai:bibliotecadigital.ipb.pt:10198/1132Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T22:54:42.543864Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
title |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
spellingShingle |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications Gomes, Helder Multi-walled carbon nanotubes (MWNT) Carbon xerogels Activated carbon Carbon supported catalysts Catalytic wet air oxidation (CWAO) Aniline |
title_short |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
title_full |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
title_fullStr |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
title_full_unstemmed |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
title_sort |
Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications |
author |
Gomes, Helder |
author_facet |
Gomes, Helder Samant, Purnakala Serp, Philippe Kalck, Philippe Figueiredo, José Faria, Joaquim |
author_role |
author |
author2 |
Samant, Purnakala Serp, Philippe Kalck, Philippe Figueiredo, José Faria, Joaquim |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Biblioteca Digital do IPB |
dc.contributor.author.fl_str_mv |
Gomes, Helder Samant, Purnakala Serp, Philippe Kalck, Philippe Figueiredo, José Faria, Joaquim |
dc.subject.por.fl_str_mv |
Multi-walled carbon nanotubes (MWNT) Carbon xerogels Activated carbon Carbon supported catalysts Catalytic wet air oxidation (CWAO) Aniline |
topic |
Multi-walled carbon nanotubes (MWNT) Carbon xerogels Activated carbon Carbon supported catalysts Catalytic wet air oxidation (CWAO) Aniline |
description |
Different types of carbon materials including multi-walled nanotubes (MWNT), carbon xerogels (CX) and activated carbon (AC) were used as supports to prepare platinum catalysts (1% w/w), which were tested in the treatment of aqueous aniline solutions by catalytic wet air oxidation (CWAO). The prepared materials and catalysts were characterized by several techniques (SEM/EDS, TEM, N2 adsorption, TPD and H2 chemisorption). All catalysts presented a very high activity for the removal of aniline and total organic carbon (TOC). Catalyst activity and selectivity toward CO2 formation were found to depend on the nature of the support and concentration of oxygen containing functional groups on the surface of the materials. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004 2004-01-01T00:00:00Z 2009-03-27T11:30:10Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10198/1132 |
url |
http://hdl.handle.net/10198/1132 |
dc.language.iso.fl_str_mv |
eng eng |
language |
eng |
dc.relation.none.fl_str_mv |
Gomes, Helder; Samant, Purnakala; Serp, Philippe; Kalck, Philippe; Figueiredo, José; Faria, Joaquim (2004). Carbon nanotubes and xerogels as supports of well dispersed Pt catalysts for environmental applications. Applied Catalysis B: Environmental. ISSN 0926-3373. 54:3, p.175-182 0926-3373 Applied Catalysis B: Environmental 10.1016/j.apcatb.2004.06.009 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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