Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes

Detalhes bibliográficos
Autor(a) principal: Machado, Beatriz P.
Data de Publicação: 2024
Outros Autores: Celador-Garcia, Maria, Rosa, Vítor, Gomes, Clara S. B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/172273
Resumo: Publisher Copyright: © 2024 by the authors.
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spelling Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth ComplexesA Combined Single-Crystal X-ray Diffraction and Hirshfeld Analysis Approachbis(arylimino)acenaphthene (Aryl-BIAN) ligandsbismuthHirshfeld surface analysisX-ray structureInorganic ChemistryPublisher Copyright: © 2024 by the authors.Dimeric bismuth(III) complexes bearing bis(aryl-imino)acenaphthene (Aryl-BIAN) donor ligands of the general formulae [(Dipp-BIAN)BiCl3]2 2, [(o-iPr-BIAN)BiCl3]2 3, and [(p-iPr-BIAN)BiCl3]2 4, where Dipp = diisopropyl, o-iPr = ortho-isopropyl and p-iPr = para-isopropyl, were prepared by reaction of the corresponding neutral BIAN ligand with BiCl3, under inert atmosphere conditions. X-ray studies were performed, and their molecular structures were determined. The individual contributions of intermolecular interactions to crystal packing have been quantified by means of Hirsfeld surface analysis.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNMachado, Beatriz P.Celador-Garcia, MariaRosa, VítorGomes, Clara S. B.2024-09-23T22:22:17Z2024-05-042024-05-04T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article13application/pdfhttp://hdl.handle.net/10362/172273eng2304-6740PURE: 99817082https://doi.org/10.3390/inorganics12050135info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-09-30T01:41:49Zoai:run.unl.pt:10362/172273Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-09-30T01:41:49Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
A Combined Single-Crystal X-ray Diffraction and Hirshfeld Analysis Approach
title Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
spellingShingle Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
Machado, Beatriz P.
bis(arylimino)acenaphthene (Aryl-BIAN) ligands
bismuth
Hirshfeld surface analysis
X-ray structure
Inorganic Chemistry
title_short Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
title_full Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
title_fullStr Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
title_full_unstemmed Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
title_sort Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes
author Machado, Beatriz P.
author_facet Machado, Beatriz P.
Celador-Garcia, Maria
Rosa, Vítor
Gomes, Clara S. B.
author_role author
author2 Celador-Garcia, Maria
Rosa, Vítor
Gomes, Clara S. B.
author2_role author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Machado, Beatriz P.
Celador-Garcia, Maria
Rosa, Vítor
Gomes, Clara S. B.
dc.subject.por.fl_str_mv bis(arylimino)acenaphthene (Aryl-BIAN) ligands
bismuth
Hirshfeld surface analysis
X-ray structure
Inorganic Chemistry
topic bis(arylimino)acenaphthene (Aryl-BIAN) ligands
bismuth
Hirshfeld surface analysis
X-ray structure
Inorganic Chemistry
description Publisher Copyright: © 2024 by the authors.
publishDate 2024
dc.date.none.fl_str_mv 2024-09-23T22:22:17Z
2024-05-04
2024-05-04T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/172273
url http://hdl.handle.net/10362/172273
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2304-6740
PURE: 99817082
https://doi.org/10.3390/inorganics12050135
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 13
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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