Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)

Detalhes bibliográficos
Autor(a) principal: Inácio, Diogo
Data de Publicação: 2023
Outros Autores: Pinto, Ana Lúcia, Paninho, Ana B., Branco, Luís C., Freitas, Sunny K. S., Cruz, Hugo
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/154622
Resumo: Publisher Copyright: © 2023 by the authors.
id RCAP_e98a03baa6229f7c109f4cd59319bb54
oai_identifier_str oai:run.unl.pt:10362/154622
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)additiveCOVALENT Organic Frameworks (COFs)dyedye-sensitized solar cell (DSSC)photoanodeChemical Engineering(all)Materials Science(all)SDG 7 - Affordable and Clean EnergySDG 15 - Life on LandPublisher Copyright: © 2023 by the authors.Five Covalent Organic Frameworks (COFs) were synthesized and applied to Dye-Sensitized Solar Cells (DSSCs) as dyes and additives. These porous nanomaterials are based on cheap, abundant commercially available ionic dyes (thionin acetate RIO-43, Bismarck brown Y RIO-55 and pararosaniline hydrochloride RIO-70), and antibiotics (dapsone RIO-60) are used as building blocks. The reticular innovative organic framework RIO-60 is the most promising dye for DSSCs. It possesses a short-circuit current density (Jsc) of 1.00 mA/cm2, an open-circuit voltage (Voc) of 329 mV, a fill factor (FF) of 0.59, and a cell efficiency (η) of 0.19%. These values are higher than those previously reported for COFs in similar devices. This first approach using the RIO family provides a good perspective on its application in DSSCs as a dye or photoanode dye enhancer, helping to increase the cell’s lifespan.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNInácio, DiogoPinto, Ana LúciaPaninho, Ana B.Branco, Luís C.Freitas, Sunny K. S.Cruz, Hugo2023-06-29T22:17:27Z2023-03-282023-03-28T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article17application/pdfhttp://hdl.handle.net/10362/154622eng2079-4991PURE: 64821543https://doi.org/10.3390/nano13071204info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:37:06Zoai:run.unl.pt:10362/154622Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:55:42.152774Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
title Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
spellingShingle Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
Inácio, Diogo
additive
COVALENT Organic Frameworks (COFs)
dye
dye-sensitized solar cell (DSSC)
photoanode
Chemical Engineering(all)
Materials Science(all)
SDG 7 - Affordable and Clean Energy
SDG 15 - Life on Land
title_short Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
title_full Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
title_fullStr Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
title_full_unstemmed Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
title_sort Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
author Inácio, Diogo
author_facet Inácio, Diogo
Pinto, Ana Lúcia
Paninho, Ana B.
Branco, Luís C.
Freitas, Sunny K. S.
Cruz, Hugo
author_role author
author2 Pinto, Ana Lúcia
Paninho, Ana B.
Branco, Luís C.
Freitas, Sunny K. S.
Cruz, Hugo
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Inácio, Diogo
Pinto, Ana Lúcia
Paninho, Ana B.
Branco, Luís C.
Freitas, Sunny K. S.
Cruz, Hugo
dc.subject.por.fl_str_mv additive
COVALENT Organic Frameworks (COFs)
dye
dye-sensitized solar cell (DSSC)
photoanode
Chemical Engineering(all)
Materials Science(all)
SDG 7 - Affordable and Clean Energy
SDG 15 - Life on Land
topic additive
COVALENT Organic Frameworks (COFs)
dye
dye-sensitized solar cell (DSSC)
photoanode
Chemical Engineering(all)
Materials Science(all)
SDG 7 - Affordable and Clean Energy
SDG 15 - Life on Land
description Publisher Copyright: © 2023 by the authors.
publishDate 2023
dc.date.none.fl_str_mv 2023-06-29T22:17:27Z
2023-03-28
2023-03-28T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/154622
url http://hdl.handle.net/10362/154622
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2079-4991
PURE: 64821543
https://doi.org/10.3390/nano13071204
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 17
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799138143699468288