Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/154622 |
Resumo: | Publisher Copyright: © 2023 by the authors. |
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Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs)additiveCOVALENT Organic Frameworks (COFs)dyedye-sensitized solar cell (DSSC)photoanodeChemical Engineering(all)Materials Science(all)SDG 7 - Affordable and Clean EnergySDG 15 - Life on LandPublisher Copyright: © 2023 by the authors.Five Covalent Organic Frameworks (COFs) were synthesized and applied to Dye-Sensitized Solar Cells (DSSCs) as dyes and additives. These porous nanomaterials are based on cheap, abundant commercially available ionic dyes (thionin acetate RIO-43, Bismarck brown Y RIO-55 and pararosaniline hydrochloride RIO-70), and antibiotics (dapsone RIO-60) are used as building blocks. The reticular innovative organic framework RIO-60 is the most promising dye for DSSCs. It possesses a short-circuit current density (Jsc) of 1.00 mA/cm2, an open-circuit voltage (Voc) of 329 mV, a fill factor (FF) of 0.59, and a cell efficiency (η) of 0.19%. These values are higher than those previously reported for COFs in similar devices. This first approach using the RIO family provides a good perspective on its application in DSSCs as a dye or photoanode dye enhancer, helping to increase the cell’s lifespan.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNInácio, DiogoPinto, Ana LúciaPaninho, Ana B.Branco, Luís C.Freitas, Sunny K. S.Cruz, Hugo2023-06-29T22:17:27Z2023-03-282023-03-28T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article17application/pdfhttp://hdl.handle.net/10362/154622eng2079-4991PURE: 64821543https://doi.org/10.3390/nano13071204info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:37:06Zoai:run.unl.pt:10362/154622Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:55:42.152774Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
title |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
spellingShingle |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) Inácio, Diogo additive COVALENT Organic Frameworks (COFs) dye dye-sensitized solar cell (DSSC) photoanode Chemical Engineering(all) Materials Science(all) SDG 7 - Affordable and Clean Energy SDG 15 - Life on Land |
title_short |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
title_full |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
title_fullStr |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
title_full_unstemmed |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
title_sort |
Application of Covalent Organic Frameworks (COFs) as Dyes and Additives for Dye-Sensitized Solar Cells (DSSCs) |
author |
Inácio, Diogo |
author_facet |
Inácio, Diogo Pinto, Ana Lúcia Paninho, Ana B. Branco, Luís C. Freitas, Sunny K. S. Cruz, Hugo |
author_role |
author |
author2 |
Pinto, Ana Lúcia Paninho, Ana B. Branco, Luís C. Freitas, Sunny K. S. Cruz, Hugo |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
dc.contributor.author.fl_str_mv |
Inácio, Diogo Pinto, Ana Lúcia Paninho, Ana B. Branco, Luís C. Freitas, Sunny K. S. Cruz, Hugo |
dc.subject.por.fl_str_mv |
additive COVALENT Organic Frameworks (COFs) dye dye-sensitized solar cell (DSSC) photoanode Chemical Engineering(all) Materials Science(all) SDG 7 - Affordable and Clean Energy SDG 15 - Life on Land |
topic |
additive COVALENT Organic Frameworks (COFs) dye dye-sensitized solar cell (DSSC) photoanode Chemical Engineering(all) Materials Science(all) SDG 7 - Affordable and Clean Energy SDG 15 - Life on Land |
description |
Publisher Copyright: © 2023 by the authors. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-06-29T22:17:27Z 2023-03-28 2023-03-28T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/154622 |
url |
http://hdl.handle.net/10362/154622 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2079-4991 PURE: 64821543 https://doi.org/10.3390/nano13071204 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
17 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
_version_ |
1799138143699468288 |