Electron and photon induced processes in SF5CF3
Autor(a) principal: | |
---|---|
Data de Publicação: | 2003 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/3347 |
Resumo: | The photo-absorption cross section of trifluoromethyl sulphur pentafluoride, SF5CF3 has been measured using synchrotron radiation in the range of 4–11 eV (310 nm > l > 110 nm) and comparison made with electron energy loss spectroscopy (EELS). The measured VUV cross sections are used to derive the photolysis rate of SF5CF3 in the terrestrial atmosphere. It is estimated that the lifetime for this molecule is the order of a 1000 years and the calculated global warming potential (GWP) is found to be between 17000 and 18100, making it one of the most potent global warming gases in the terrestrial atmosphere. |
id |
RCAP_ea359f83429d2c0c3ca85891938b91aa |
---|---|
oai_identifier_str |
oai:run.unl.pt:10362/3347 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
Electron and photon induced processes in SF5CF3VUV photo-absorptionSynchrotron radiationGreenhouse gasPhotolysis ratesThe photo-absorption cross section of trifluoromethyl sulphur pentafluoride, SF5CF3 has been measured using synchrotron radiation in the range of 4–11 eV (310 nm > l > 110 nm) and comparison made with electron energy loss spectroscopy (EELS). The measured VUV cross sections are used to derive the photolysis rate of SF5CF3 in the terrestrial atmosphere. It is estimated that the lifetime for this molecule is the order of a 1000 years and the calculated global warming potential (GWP) is found to be between 17000 and 18100, making it one of the most potent global warming gases in the terrestrial atmosphere.Radiation Physics and ChemistryRUNLimão-Vieira, P.Kendall, P.AEden, S.Mason, N.J.Heinesch, J.Hubin-Franskin, M.J.Delwiche, J.Giuliani, A.2010-04-13T10:11:23Z2003-092003-09-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/3347eng0969-806Xinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T03:33:13Zoai:run.unl.pt:10362/3347Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:15:21.097872Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Electron and photon induced processes in SF5CF3 |
title |
Electron and photon induced processes in SF5CF3 |
spellingShingle |
Electron and photon induced processes in SF5CF3 Limão-Vieira, P. VUV photo-absorption Synchrotron radiation Greenhouse gas Photolysis rates |
title_short |
Electron and photon induced processes in SF5CF3 |
title_full |
Electron and photon induced processes in SF5CF3 |
title_fullStr |
Electron and photon induced processes in SF5CF3 |
title_full_unstemmed |
Electron and photon induced processes in SF5CF3 |
title_sort |
Electron and photon induced processes in SF5CF3 |
author |
Limão-Vieira, P. |
author_facet |
Limão-Vieira, P. Kendall, P.A Eden, S. Mason, N.J. Heinesch, J. Hubin-Franskin, M.J. Delwiche, J. Giuliani, A. |
author_role |
author |
author2 |
Kendall, P.A Eden, S. Mason, N.J. Heinesch, J. Hubin-Franskin, M.J. Delwiche, J. Giuliani, A. |
author2_role |
author author author author author author author |
dc.contributor.none.fl_str_mv |
RUN |
dc.contributor.author.fl_str_mv |
Limão-Vieira, P. Kendall, P.A Eden, S. Mason, N.J. Heinesch, J. Hubin-Franskin, M.J. Delwiche, J. Giuliani, A. |
dc.subject.por.fl_str_mv |
VUV photo-absorption Synchrotron radiation Greenhouse gas Photolysis rates |
topic |
VUV photo-absorption Synchrotron radiation Greenhouse gas Photolysis rates |
description |
The photo-absorption cross section of trifluoromethyl sulphur pentafluoride, SF5CF3 has been measured using synchrotron radiation in the range of 4–11 eV (310 nm > l > 110 nm) and comparison made with electron energy loss spectroscopy (EELS). The measured VUV cross sections are used to derive the photolysis rate of SF5CF3 in the terrestrial atmosphere. It is estimated that the lifetime for this molecule is the order of a 1000 years and the calculated global warming potential (GWP) is found to be between 17000 and 18100, making it one of the most potent global warming gases in the terrestrial atmosphere. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-09 2003-09-01T00:00:00Z 2010-04-13T10:11:23Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/3347 |
url |
http://hdl.handle.net/10362/3347 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0969-806X |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Radiation Physics and Chemistry |
publisher.none.fl_str_mv |
Radiation Physics and Chemistry |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
_version_ |
1799137805104840704 |