Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004 |
Resumo: | The inhibition effect of 2-amino, 5-ethyl-1, 3, 4 thiadiazole (TTD) compound on the corrosion of type 304 stainless steel in 3 M H2SO4 test solution was investigated using potentiodynamic polarization, weight loss techniques and open circuit potential measurements. Results showed TTD to be very effective with an average inhibition efficiency of 98% from weight loss analysis and 87% from polarization test. Data from open circuit potential measurement are well within passivation potentials at specific concentrations of TTD. Scanning electron microscopy showed the effect of the inhibiting compound on the surface topography of the steel, while X-ray diffractometry determined the phase compounds formed on the surface due to inhibitor adhesion. Adsorption of the compound was determined to obey the Langmuir isotherm model. Thermodynamic calculations showed the inhibition process occurred through chemisorption mechanism and results from statistical analysis revealed the overwhelming influence of inhibitor concentration over exposure time on the inhibition performance of the compound. |
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Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acidcorrosioninhibitorsulphuric acidadsorptionLangmuirsteelThe inhibition effect of 2-amino, 5-ethyl-1, 3, 4 thiadiazole (TTD) compound on the corrosion of type 304 stainless steel in 3 M H2SO4 test solution was investigated using potentiodynamic polarization, weight loss techniques and open circuit potential measurements. Results showed TTD to be very effective with an average inhibition efficiency of 98% from weight loss analysis and 87% from polarization test. Data from open circuit potential measurement are well within passivation potentials at specific concentrations of TTD. Scanning electron microscopy showed the effect of the inhibiting compound on the surface topography of the steel, while X-ray diffractometry determined the phase compounds formed on the surface due to inhibitor adhesion. Adsorption of the compound was determined to obey the Langmuir isotherm model. Thermodynamic calculations showed the inhibition process occurred through chemisorption mechanism and results from statistical analysis revealed the overwhelming influence of inhibitor concentration over exposure time on the inhibition performance of the compound.Sociedade Portuguesa de Electroquímica2014-09-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004Portugaliae Electrochimica Acta v.32 n.5 2014reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004Loto,R. T.Loto,C. A.Popoola,A. P. I.Fedotova,T. I.info:eu-repo/semantics/openAccess2024-02-06T17:07:17Zoai:scielo:S0872-19042014000500004Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:16.008369Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
title |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
spellingShingle |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid Loto,R. T. corrosion inhibitor sulphuric acid adsorption Langmuir steel |
title_short |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
title_full |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
title_fullStr |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
title_full_unstemmed |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
title_sort |
Inhibition Effect of 2-Amino, 5-Ethyl-1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid |
author |
Loto,R. T. |
author_facet |
Loto,R. T. Loto,C. A. Popoola,A. P. I. Fedotova,T. I. |
author_role |
author |
author2 |
Loto,C. A. Popoola,A. P. I. Fedotova,T. I. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Loto,R. T. Loto,C. A. Popoola,A. P. I. Fedotova,T. I. |
dc.subject.por.fl_str_mv |
corrosion inhibitor sulphuric acid adsorption Langmuir steel |
topic |
corrosion inhibitor sulphuric acid adsorption Langmuir steel |
description |
The inhibition effect of 2-amino, 5-ethyl-1, 3, 4 thiadiazole (TTD) compound on the corrosion of type 304 stainless steel in 3 M H2SO4 test solution was investigated using potentiodynamic polarization, weight loss techniques and open circuit potential measurements. Results showed TTD to be very effective with an average inhibition efficiency of 98% from weight loss analysis and 87% from polarization test. Data from open circuit potential measurement are well within passivation potentials at specific concentrations of TTD. Scanning electron microscopy showed the effect of the inhibiting compound on the surface topography of the steel, while X-ray diffractometry determined the phase compounds formed on the surface due to inhibitor adhesion. Adsorption of the compound was determined to obey the Langmuir isotherm model. Thermodynamic calculations showed the inhibition process occurred through chemisorption mechanism and results from statistical analysis revealed the overwhelming influence of inhibitor concentration over exposure time on the inhibition performance of the compound. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-09-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042014000500004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.32 n.5 2014 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137291057233920 |