3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone

Detalhes bibliográficos
Autor(a) principal: Cristiano, Maria Lurdes Santos
Data de Publicação: 1995
Outros Autores: Johnstone, Robert A. W., Pratt, M. J.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.1/4239
Resumo: Nitration of 3-hydroxyacetophenone gives 2,6-dinitro-3-hydroxyacetophenone, C8H6N206, in which the nitro groups have entered the sterically least favourable positions in the aromatic nucleus. None of the expected substitution in the 4-position was observed. The two nitro groups flanking the carbonyl side chain are different in that one is in the plane of the aryl ring but the other is twisted well out of the plane.
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spelling 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenoneNitration of 3-hydroxyacetophenone gives 2,6-dinitro-3-hydroxyacetophenone, C8H6N206, in which the nitro groups have entered the sterically least favourable positions in the aromatic nucleus. None of the expected substitution in the 4-position was observed. The two nitro groups flanking the carbonyl side chain are different in that one is in the plane of the aryl ring but the other is twisted well out of the plane.International Union of CrystallographySapientiaCristiano, Maria Lurdes SantosJohnstone, Robert A. W.Pratt, M. J.2014-06-06T17:47:30Z19952014-06-05T09:22:40Z1995-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.1/4239eng0108-2701AUT: MCR00716;info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-11-29T10:25:45Zoai:sapientia.ualg.pt:10400.1/4239Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-11-29T10:25:45Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
title 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
spellingShingle 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
Cristiano, Maria Lurdes Santos
title_short 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
title_full 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
title_fullStr 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
title_full_unstemmed 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
title_sort 3-Hydroxy-2,6-dinitroacetophenone: an unusual substitution pattern resulting from nitration of 3-hydroxyacetophenone
author Cristiano, Maria Lurdes Santos
author_facet Cristiano, Maria Lurdes Santos
Johnstone, Robert A. W.
Pratt, M. J.
author_role author
author2 Johnstone, Robert A. W.
Pratt, M. J.
author2_role author
author
dc.contributor.none.fl_str_mv Sapientia
dc.contributor.author.fl_str_mv Cristiano, Maria Lurdes Santos
Johnstone, Robert A. W.
Pratt, M. J.
description Nitration of 3-hydroxyacetophenone gives 2,6-dinitro-3-hydroxyacetophenone, C8H6N206, in which the nitro groups have entered the sterically least favourable positions in the aromatic nucleus. None of the expected substitution in the 4-position was observed. The two nitro groups flanking the carbonyl side chain are different in that one is in the plane of the aryl ring but the other is twisted well out of the plane.
publishDate 1995
dc.date.none.fl_str_mv 1995
1995-01-01T00:00:00Z
2014-06-06T17:47:30Z
2014-06-05T09:22:40Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.1/4239
url http://hdl.handle.net/10400.1/4239
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0108-2701
AUT: MCR00716;
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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