Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis

Detalhes bibliográficos
Autor(a) principal: Pérez-Mayoral, Elena
Data de Publicação: 2020
Outros Autores: Matos, Inês, Bernardo, Maria, Ventura, Márcia, Fonseca, Isabel M.
Tipo de documento: Outros
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/116277
Resumo: CTM 2014-56668-R project UIDB/50006/2020
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spelling Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesisAtomically dispersed metal catalystsFine chemicalsPorous carbonsCatalysisPhysical and Theoretical ChemistryCTM 2014-56668-R project UIDB/50006/2020Single-atom catalysts (SACs), consisting of metals atomically dispersed on a support, are considered as advanced materials bridging homogeneous and heterogeneous catalysis, representing the catalysis at the limit. The enhanced performance of these catalysts is due to the combination of distinct factors such as well-defined active sites, comprising metal single atoms in different coordination environments also varying its valence state and strongly interacting with the support, in this case porous carbons, maximizing then the metal efficiency in comparison with other metal surfaces consisting of metal clusters and/or metal nanoparticles. The purpose of this review is to summarize the most recent advances in terms of both synthetic strategies of producing porous carbon-derived SACs but also its application to green synthesis of highly valuable compounds, an area in which the homogeneous catalysts are classically used. Porous carbon-derived SACs emerge as a type of new and eco-friendly catalysts with great potential. Different types of carbon forms, such as multi-wall carbon nanotubes (MWCNTs), graphene and graphitic carbon nitride or even others porous carbons derived from Metal–Organic-Frameworks (MOFs) are recognized. Although it represents an area of expansion, experimentally and theoretically, much more future efforts are needed to explore them in green fine chemical synthesis.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNPérez-Mayoral, ElenaMatos, InêsBernardo, MariaVentura, MárciaFonseca, Isabel M.2021-04-27T23:13:33Z2020-12-022020-12-02T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other24application/pdfhttp://hdl.handle.net/10362/116277eng2073-4344PURE: 26865418https://doi.org/10.3390/catal10121407info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:52:10Zoai:run.unl.pt:10362/116277Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:52:10Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
title Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
spellingShingle Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
Pérez-Mayoral, Elena
Atomically dispersed metal catalysts
Fine chemicals
Porous carbons
Catalysis
Physical and Theoretical Chemistry
title_short Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
title_full Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
title_fullStr Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
title_full_unstemmed Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
title_sort Carbon-based materials for the development of highly dispersed metal catalysts: Towards highly performant catalysts for fine chemical synthesis
author Pérez-Mayoral, Elena
author_facet Pérez-Mayoral, Elena
Matos, Inês
Bernardo, Maria
Ventura, Márcia
Fonseca, Isabel M.
author_role author
author2 Matos, Inês
Bernardo, Maria
Ventura, Márcia
Fonseca, Isabel M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Pérez-Mayoral, Elena
Matos, Inês
Bernardo, Maria
Ventura, Márcia
Fonseca, Isabel M.
dc.subject.por.fl_str_mv Atomically dispersed metal catalysts
Fine chemicals
Porous carbons
Catalysis
Physical and Theoretical Chemistry
topic Atomically dispersed metal catalysts
Fine chemicals
Porous carbons
Catalysis
Physical and Theoretical Chemistry
description CTM 2014-56668-R project UIDB/50006/2020
publishDate 2020
dc.date.none.fl_str_mv 2020-12-02
2020-12-02T00:00:00Z
2021-04-27T23:13:33Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/other
format other
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/116277
url http://hdl.handle.net/10362/116277
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2073-4344
PURE: 26865418
https://doi.org/10.3390/catal10121407
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 24
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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