Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells

Detalhes bibliográficos
Autor(a) principal: dos Santos, Débora
Data de Publicação: 2024
Outros Autores: Moreira, Wardleison, de Araújo, Thiago, Bernardo, Maria, Fonseca, Isabel, Ostroski, Indianara, de Barros, Maria Angélica
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/173338
Resumo: This study was partly funded by the National Council for Scientific and Technological Develop-ment—CNPq (Process 200678/2022-1). Publisher Copyright: © 2024 by the authors.
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spelling Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shellsaquatic environmentCO-activationhydrocarbonizationpharmaceuticalspyrolysisAnalytical ChemistryFiltration and SeparationSDG 6 - Clean Water and SanitationSDG 13 - Climate ActionThis study was partly funded by the National Council for Scientific and Technological Develop-ment—CNPq (Process 200678/2022-1). Publisher Copyright: © 2024 by the authors.This study explored the adsorption of acetaminophen and caffeine using CO2-activated biochar (BT-CO2) and hydrochar (HT-CO2) derived from Tingui shell biomass. The experimental data from kinetic and equilibrium adsorption tests were employed in batch and fixed-bed systems. In the batch system, a specific amount of the adsorbent was added to a known volume of the solution, and the mixture was agitated for a set period to allow adsorption to occur. In the fixed-bed system, the solution was passed through a column packed with the adsorbent, allowing for continuous adsorption. These systems pave the way for future research. The findings revealed that HT-CO2 exhibited a greater surface area and a higher presence of oxygen-containing functional groups than BT-CO2. These functional oxygen groups had a notable impact on the adsorption capacity of the adsorbents for pharmaceutical substances. In the batch systems, BT-CO2 demonstrated a maximum adsorption capacity of 221.4 mg g−1 for acetaminophen and 162.7 mg g−1 for caffeine, while HT-CO2 exhibited higher capacities of 383.2 mg g−1 for acetaminophen and 189.7 mg g−1 for caffeine. In the fixed bed configuration, HT-CO2 displayed a maximum adsorption capacity of 82.2 mg g−1 for acetaminophen and 45.60 mg g−1 for caffeine. The predominant mechanisms involved in the removal of acetaminophen and caffeine were identified as H-bonding and π-π bonds. These results underscore the promising potential of these carbons as effective adsorbents for treating water contaminated with pharmaceutical residues, inspiring further exploration in this field and offering hope for the future of water treatment by providing a solid foundation for future research and development.DQ - Departamento de QuímicaLAQV@REQUIMTERUNdos Santos, DéboraMoreira, Wardleisonde Araújo, ThiagoBernardo, MariaFonseca, IsabelOstroski, Indianarade Barros, Maria Angélica2024-10-10T22:39:30Z2024-07-122024-07-12T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article18application/pdfhttp://hdl.handle.net/10362/173338eng2297-8739PURE: 99597051https://doi.org/10.3390/separations11070215info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-10-28T01:38:51Zoai:run.unl.pt:10362/173338Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-10-28T01:38:51Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
title Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
spellingShingle Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
dos Santos, Débora
aquatic environment
CO-activation
hydrocarbonization
pharmaceuticals
pyrolysis
Analytical Chemistry
Filtration and Separation
SDG 6 - Clean Water and Sanitation
SDG 13 - Climate Action
title_short Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
title_full Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
title_fullStr Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
title_full_unstemmed Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
title_sort Removal of Emerging Contaminants from Water by Using Carbon Materials Derived from Tingui Shells
author dos Santos, Débora
author_facet dos Santos, Débora
Moreira, Wardleison
de Araújo, Thiago
Bernardo, Maria
Fonseca, Isabel
Ostroski, Indianara
de Barros, Maria Angélica
author_role author
author2 Moreira, Wardleison
de Araújo, Thiago
Bernardo, Maria
Fonseca, Isabel
Ostroski, Indianara
de Barros, Maria Angélica
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
LAQV@REQUIMTE
RUN
dc.contributor.author.fl_str_mv dos Santos, Débora
Moreira, Wardleison
de Araújo, Thiago
Bernardo, Maria
Fonseca, Isabel
Ostroski, Indianara
de Barros, Maria Angélica
dc.subject.por.fl_str_mv aquatic environment
CO-activation
hydrocarbonization
pharmaceuticals
pyrolysis
Analytical Chemistry
Filtration and Separation
SDG 6 - Clean Water and Sanitation
SDG 13 - Climate Action
topic aquatic environment
CO-activation
hydrocarbonization
pharmaceuticals
pyrolysis
Analytical Chemistry
Filtration and Separation
SDG 6 - Clean Water and Sanitation
SDG 13 - Climate Action
description This study was partly funded by the National Council for Scientific and Technological Develop-ment—CNPq (Process 200678/2022-1). Publisher Copyright: © 2024 by the authors.
publishDate 2024
dc.date.none.fl_str_mv 2024-10-10T22:39:30Z
2024-07-12
2024-07-12T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/173338
url http://hdl.handle.net/10362/173338
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2297-8739
PURE: 99597051
https://doi.org/10.3390/separations11070215
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 18
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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