Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids

Detalhes bibliográficos
Autor(a) principal: Messias, Sofia Alexandra Pereira
Data de Publicação: 2013
Tipo de documento: Dissertação
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/19691
Resumo: The present work studies a method of electrochemical reduction of CO2 for the production of methane and methanol. Thus, a high pressure facility was assembled and tested for this goal. Some cyclic voltammetry experiments were carried out in order to study the electrochemical window of the electrolyte (the ionic liquid [bmim][BF4] plus water). After the initial tests several electrolysis were performed with various electrode materials (copper, nickel, brass and carbon), at different pressures, reaction times and applied potential to study the influence of these parameters in the electrochemical reduction of CO2. The principal product resulting from the electrochemical reduction of CO2 was methane and hydrogen resulting from the electrolysis of water.
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spelling Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquidsElectrochemical reductionCarbon dioxideCyclic voltammetryIonic liquidsDomínio/Área Científica::Engenharia e Tecnologia::Engenharia QuímicaThe present work studies a method of electrochemical reduction of CO2 for the production of methane and methanol. Thus, a high pressure facility was assembled and tested for this goal. Some cyclic voltammetry experiments were carried out in order to study the electrochemical window of the electrolyte (the ionic liquid [bmim][BF4] plus water). After the initial tests several electrolysis were performed with various electrode materials (copper, nickel, brass and carbon), at different pressures, reaction times and applied potential to study the influence of these parameters in the electrochemical reduction of CO2. The principal product resulting from the electrochemical reduction of CO2 was methane and hydrogen resulting from the electrolysis of water.Ponte, Manuel Nunes daMachado, AnaRUNMessias, Sofia Alexandra Pereira2017-01-03T15:58:10Z2013-092017-012013-09-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisapplication/pdfhttp://hdl.handle.net/10362/19691enginfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:24:15Zoai:run.unl.pt:10362/19691Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:24:15Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
title Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
spellingShingle Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
Messias, Sofia Alexandra Pereira
Electrochemical reduction
Carbon dioxide
Cyclic voltammetry
Ionic liquids
Domínio/Área Científica::Engenharia e Tecnologia::Engenharia Química
title_short Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
title_full Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
title_fullStr Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
title_full_unstemmed Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
title_sort Electrochemical Reduction of Carbon Dioxide dissolved in ionic liquids
author Messias, Sofia Alexandra Pereira
author_facet Messias, Sofia Alexandra Pereira
author_role author
dc.contributor.none.fl_str_mv Ponte, Manuel Nunes da
Machado, Ana
RUN
dc.contributor.author.fl_str_mv Messias, Sofia Alexandra Pereira
dc.subject.por.fl_str_mv Electrochemical reduction
Carbon dioxide
Cyclic voltammetry
Ionic liquids
Domínio/Área Científica::Engenharia e Tecnologia::Engenharia Química
topic Electrochemical reduction
Carbon dioxide
Cyclic voltammetry
Ionic liquids
Domínio/Área Científica::Engenharia e Tecnologia::Engenharia Química
description The present work studies a method of electrochemical reduction of CO2 for the production of methane and methanol. Thus, a high pressure facility was assembled and tested for this goal. Some cyclic voltammetry experiments were carried out in order to study the electrochemical window of the electrolyte (the ionic liquid [bmim][BF4] plus water). After the initial tests several electrolysis were performed with various electrode materials (copper, nickel, brass and carbon), at different pressures, reaction times and applied potential to study the influence of these parameters in the electrochemical reduction of CO2. The principal product resulting from the electrochemical reduction of CO2 was methane and hydrogen resulting from the electrolysis of water.
publishDate 2013
dc.date.none.fl_str_mv 2013-09
2013-09-01T00:00:00Z
2017-01-03T15:58:10Z
2017-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/19691
url http://hdl.handle.net/10362/19691
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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