pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/25467 |
Resumo: | Experiments were performed in a laboratory scale bubble column (10 L), to investigate the pH influence on oxygen mass transfer coefficient, in order to achieve a better control of biological processes. The liquid-side mass transfer coefficient, kL, and the specific interfacial area, a, were studied individually. The specific interfacial area was obtained using the new automatic image analysis technique developed by Ferreira et al. (2012). The pH was changed by the addition to the system of the most common acids and base used in biological process: hydrochloric acid (HCl), phosphoric acid (H3PO4) and potassium hydroxide (KOH). The results show that aqueous systems containing HCl, H3PO4 or KOH present lower volumetric liquid side mass transfer coefficient, kLa, in relation to pure systems (distilled water), this decrease being not linear. It was found that the specific interfacial area presents higher values in KOH and HCl solutions in comparison with distilled water. However, an opposite behavior was observed in the liquid-side mass transfer coefficient values. The kL behavior on the impure systems was explained based on bubble surface contamination. Higbie's and Fröessling's equations were adapted in the present work in order to be used in bubble dispersion systems. |
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pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and aBubble columnsBioreactorsMass transferMultiphase reactorspHBubble surface contaminationScience & TechnologyExperiments were performed in a laboratory scale bubble column (10 L), to investigate the pH influence on oxygen mass transfer coefficient, in order to achieve a better control of biological processes. The liquid-side mass transfer coefficient, kL, and the specific interfacial area, a, were studied individually. The specific interfacial area was obtained using the new automatic image analysis technique developed by Ferreira et al. (2012). The pH was changed by the addition to the system of the most common acids and base used in biological process: hydrochloric acid (HCl), phosphoric acid (H3PO4) and potassium hydroxide (KOH). The results show that aqueous systems containing HCl, H3PO4 or KOH present lower volumetric liquid side mass transfer coefficient, kLa, in relation to pure systems (distilled water), this decrease being not linear. It was found that the specific interfacial area presents higher values in KOH and HCl solutions in comparison with distilled water. However, an opposite behavior was observed in the liquid-side mass transfer coefficient values. The kL behavior on the impure systems was explained based on bubble surface contamination. Higbie's and Fröessling's equations were adapted in the present work in order to be used in bubble dispersion systems.Pergamon-Elsevier Science LtdPergamon Press Ltd.Universidade do MinhoFerreira, AntónioCardoso, P.Teixeira, J. A.Rocha, F. A.20132013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/25467eng0009-250910.1016/j.ces.2013.02.020info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:44:14Zoai:repositorium.sdum.uminho.pt:1822/25467Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:41:53.578480Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
title |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
spellingShingle |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a Ferreira, António Bubble columns Bioreactors Mass transfer Multiphase reactors pH Bubble surface contamination Science & Technology |
title_short |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
title_full |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
title_fullStr |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
title_full_unstemmed |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
title_sort |
pH influence on oxygen mass transfer coefficient in a bubble column. Individual characterization of kL and a |
author |
Ferreira, António |
author_facet |
Ferreira, António Cardoso, P. Teixeira, J. A. Rocha, F. A. |
author_role |
author |
author2 |
Cardoso, P. Teixeira, J. A. Rocha, F. A. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Ferreira, António Cardoso, P. Teixeira, J. A. Rocha, F. A. |
dc.subject.por.fl_str_mv |
Bubble columns Bioreactors Mass transfer Multiphase reactors pH Bubble surface contamination Science & Technology |
topic |
Bubble columns Bioreactors Mass transfer Multiphase reactors pH Bubble surface contamination Science & Technology |
description |
Experiments were performed in a laboratory scale bubble column (10 L), to investigate the pH influence on oxygen mass transfer coefficient, in order to achieve a better control of biological processes. The liquid-side mass transfer coefficient, kL, and the specific interfacial area, a, were studied individually. The specific interfacial area was obtained using the new automatic image analysis technique developed by Ferreira et al. (2012). The pH was changed by the addition to the system of the most common acids and base used in biological process: hydrochloric acid (HCl), phosphoric acid (H3PO4) and potassium hydroxide (KOH). The results show that aqueous systems containing HCl, H3PO4 or KOH present lower volumetric liquid side mass transfer coefficient, kLa, in relation to pure systems (distilled water), this decrease being not linear. It was found that the specific interfacial area presents higher values in KOH and HCl solutions in comparison with distilled water. However, an opposite behavior was observed in the liquid-side mass transfer coefficient values. The kL behavior on the impure systems was explained based on bubble surface contamination. Higbie's and Fröessling's equations were adapted in the present work in order to be used in bubble dispersion systems. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013 2013-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/25467 |
url |
http://hdl.handle.net/1822/25467 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0009-2509 10.1016/j.ces.2013.02.020 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd Pergamon Press Ltd. |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd Pergamon Press Ltd. |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799132969315598336 |