Production of porous ceramic materialusing different sources of alumina and calcia
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300739 |
Resumo: | ABSTRACTNumerous papers and publications report the use of microporous calcium hexaluminate (CaO.6Al2O3; CA6) as a key raw material for high temperature insulating materials. This material has unique properties with respect to chemical purity and mineral composition. Another important property of CA6 is its structure, which consists of platelet-shaped crystals that interlock. The free distance between the crystals defines the microporous structure. The low density in combination with the micropores hampers heat transfer by radiation at temperatures exceeding 1000 oC and results in a low thermal conductivity. Given the advantages presented by this material, it is necessary to understand the formation mechanism of CA6 grains in order to better develop the potential applications of this material. CA6 can be fabricated using organic binders to consolidate the Al2O3-CaCO3 powder mixture and to provide green strength so that a green body can be formed and retains the desired shape before heating. However, these organic binders must be completely thermally decomposed so that they do not remain in the sintered body as carbon or ash. Moreover, the use of organic binders releases large volumes of gases such as carbon dioxide from the green body during heating. Therefore, an eco-friendly ceramic fabrication process has been developed that employs an inorganic binder (hydraulic alumina). The aim of the present work was to study the synthesis of porous calcium-hexaluminate ceramics using calcined alumina or hydraulic alumina combined with different sources of calcia (CaCO3 and Ca(OH)2) at different temperatures. The materials produced were characterized by X-ray diffraction, scanning electron microscopy, apparent porosity and mercury intrusion porosimetry. The materials produced by hydraulic alumina presented higher porosity and larger pores compared to those produced from calcined alumina |
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Production of porous ceramic materialusing different sources of alumina and calciaCalcium hexaluminatesynthesisinorganic binderpropertiesABSTRACTNumerous papers and publications report the use of microporous calcium hexaluminate (CaO.6Al2O3; CA6) as a key raw material for high temperature insulating materials. This material has unique properties with respect to chemical purity and mineral composition. Another important property of CA6 is its structure, which consists of platelet-shaped crystals that interlock. The free distance between the crystals defines the microporous structure. The low density in combination with the micropores hampers heat transfer by radiation at temperatures exceeding 1000 oC and results in a low thermal conductivity. Given the advantages presented by this material, it is necessary to understand the formation mechanism of CA6 grains in order to better develop the potential applications of this material. CA6 can be fabricated using organic binders to consolidate the Al2O3-CaCO3 powder mixture and to provide green strength so that a green body can be formed and retains the desired shape before heating. However, these organic binders must be completely thermally decomposed so that they do not remain in the sintered body as carbon or ash. Moreover, the use of organic binders releases large volumes of gases such as carbon dioxide from the green body during heating. Therefore, an eco-friendly ceramic fabrication process has been developed that employs an inorganic binder (hydraulic alumina). The aim of the present work was to study the synthesis of porous calcium-hexaluminate ceramics using calcined alumina or hydraulic alumina combined with different sources of calcia (CaCO3 and Ca(OH)2) at different temperatures. The materials produced were characterized by X-ray diffraction, scanning electron microscopy, apparent porosity and mercury intrusion porosimetry. The materials produced by hydraulic alumina presented higher porosity and larger pores compared to those produced from calcined aluminaLaboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22015-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300739Matéria (Rio de Janeiro) v.20 n.3 2015reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/S1517-707620150003.0078info:eu-repo/semantics/openAccessOliveira,Ivone Regina deLeite,Vitoria Marques CesarLima,Milene Paula Vargas PortoSalomão,Rafaeleng2015-10-21T00:00:00Zoai:scielo:S1517-70762015000300739Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2015-10-21T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
Production of porous ceramic materialusing different sources of alumina and calcia |
title |
Production of porous ceramic materialusing different sources of alumina and calcia |
spellingShingle |
Production of porous ceramic materialusing different sources of alumina and calcia Oliveira,Ivone Regina de Calcium hexaluminate synthesis inorganic binder properties |
title_short |
Production of porous ceramic materialusing different sources of alumina and calcia |
title_full |
Production of porous ceramic materialusing different sources of alumina and calcia |
title_fullStr |
Production of porous ceramic materialusing different sources of alumina and calcia |
title_full_unstemmed |
Production of porous ceramic materialusing different sources of alumina and calcia |
title_sort |
Production of porous ceramic materialusing different sources of alumina and calcia |
author |
Oliveira,Ivone Regina de |
author_facet |
Oliveira,Ivone Regina de Leite,Vitoria Marques Cesar Lima,Milene Paula Vargas Porto Salomão,Rafael |
author_role |
author |
author2 |
Leite,Vitoria Marques Cesar Lima,Milene Paula Vargas Porto Salomão,Rafael |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Oliveira,Ivone Regina de Leite,Vitoria Marques Cesar Lima,Milene Paula Vargas Porto Salomão,Rafael |
dc.subject.por.fl_str_mv |
Calcium hexaluminate synthesis inorganic binder properties |
topic |
Calcium hexaluminate synthesis inorganic binder properties |
description |
ABSTRACTNumerous papers and publications report the use of microporous calcium hexaluminate (CaO.6Al2O3; CA6) as a key raw material for high temperature insulating materials. This material has unique properties with respect to chemical purity and mineral composition. Another important property of CA6 is its structure, which consists of platelet-shaped crystals that interlock. The free distance between the crystals defines the microporous structure. The low density in combination with the micropores hampers heat transfer by radiation at temperatures exceeding 1000 oC and results in a low thermal conductivity. Given the advantages presented by this material, it is necessary to understand the formation mechanism of CA6 grains in order to better develop the potential applications of this material. CA6 can be fabricated using organic binders to consolidate the Al2O3-CaCO3 powder mixture and to provide green strength so that a green body can be formed and retains the desired shape before heating. However, these organic binders must be completely thermally decomposed so that they do not remain in the sintered body as carbon or ash. Moreover, the use of organic binders releases large volumes of gases such as carbon dioxide from the green body during heating. Therefore, an eco-friendly ceramic fabrication process has been developed that employs an inorganic binder (hydraulic alumina). The aim of the present work was to study the synthesis of porous calcium-hexaluminate ceramics using calcined alumina or hydraulic alumina combined with different sources of calcia (CaCO3 and Ca(OH)2) at different temperatures. The materials produced were characterized by X-ray diffraction, scanning electron microscopy, apparent porosity and mercury intrusion porosimetry. The materials produced by hydraulic alumina presented higher porosity and larger pores compared to those produced from calcined alumina |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300739 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300739 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1517-707620150003.0078 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.20 n.3 2015 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
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1752126688859258880 |