Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000100420 |
Resumo: | ABSTRACT The materials sizing in nano-scale is a challenge to be overcome, because the size determined by various methods differ. In order to shed light about the nanomaterials sizing, a modified Scherrer's equation was applied to estimate more accurately the nanostructured titanium dioxide crystal size. The manufactured titanium dioxide-nanostructured powder with nominal average size about 21nm was used as the reference standard to determine the accurate of modified equation. From X-ray diffraction data, an average crystal size about 20.63 nm was achieved for unheated sample. To establish a relation between the result obtained with modified Scherrer's equation and the nominal average crystal size, a statistical treatment and a comparative assessment were performed. The average absolute divergence does not exceed 0.70 nm. The value of crystal size determined from X-ray data was in good agreement with that informed by the supplier. Additionally, the behavior of sample was studied as a function of temperature. |
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Nanostructured titanium dioxide average size from alternative analysis of Scherrer's EquationNanomaterialsScherrer's equationTitanium dioxideABSTRACT The materials sizing in nano-scale is a challenge to be overcome, because the size determined by various methods differ. In order to shed light about the nanomaterials sizing, a modified Scherrer's equation was applied to estimate more accurately the nanostructured titanium dioxide crystal size. The manufactured titanium dioxide-nanostructured powder with nominal average size about 21nm was used as the reference standard to determine the accurate of modified equation. From X-ray diffraction data, an average crystal size about 20.63 nm was achieved for unheated sample. To establish a relation between the result obtained with modified Scherrer's equation and the nominal average crystal size, a statistical treatment and a comparative assessment were performed. The average absolute divergence does not exceed 0.70 nm. The value of crystal size determined from X-ray data was in good agreement with that informed by the supplier. Additionally, the behavior of sample was studied as a function of temperature.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22018-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000100420Matéria (Rio de Janeiro) v.23 n.1 2018reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620170001.0301info:eu-repo/semantics/openAccessLima,Francisco MarconeMartins,Felipe MotaMaia Júnior,Paulo Herbert FrançaAlmeida,Ana Fabíola LeiteFreire,Francisco Nivaldo Aguiareng2018-03-02T00:00:00Zoai:scielo:S1517-70762018000100420Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2018-03-02T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
title |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
spellingShingle |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation Lima,Francisco Marcone Nanomaterials Scherrer's equation Titanium dioxide |
title_short |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
title_full |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
title_fullStr |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
title_full_unstemmed |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
title_sort |
Nanostructured titanium dioxide average size from alternative analysis of Scherrer's Equation |
author |
Lima,Francisco Marcone |
author_facet |
Lima,Francisco Marcone Martins,Felipe Mota Maia Júnior,Paulo Herbert França Almeida,Ana Fabíola Leite Freire,Francisco Nivaldo Aguiar |
author_role |
author |
author2 |
Martins,Felipe Mota Maia Júnior,Paulo Herbert França Almeida,Ana Fabíola Leite Freire,Francisco Nivaldo Aguiar |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Lima,Francisco Marcone Martins,Felipe Mota Maia Júnior,Paulo Herbert França Almeida,Ana Fabíola Leite Freire,Francisco Nivaldo Aguiar |
dc.subject.por.fl_str_mv |
Nanomaterials Scherrer's equation Titanium dioxide |
topic |
Nanomaterials Scherrer's equation Titanium dioxide |
description |
ABSTRACT The materials sizing in nano-scale is a challenge to be overcome, because the size determined by various methods differ. In order to shed light about the nanomaterials sizing, a modified Scherrer's equation was applied to estimate more accurately the nanostructured titanium dioxide crystal size. The manufactured titanium dioxide-nanostructured powder with nominal average size about 21nm was used as the reference standard to determine the accurate of modified equation. From X-ray diffraction data, an average crystal size about 20.63 nm was achieved for unheated sample. To establish a relation between the result obtained with modified Scherrer's equation and the nominal average crystal size, a statistical treatment and a comparative assessment were performed. The average absolute divergence does not exceed 0.70 nm. The value of crystal size determined from X-ray data was in good agreement with that informed by the supplier. Additionally, the behavior of sample was studied as a function of temperature. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000100420 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000100420 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1517-707620170001.0301 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.23 n.1 2018 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
_version_ |
1752126690245476352 |