The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340 |
Resumo: | ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed. |
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The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion testsCarbon steelCorrosionSoluble Salts ContentEpoxyPaintABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340Matéria (Rio de Janeiro) v.25 n.2 2020reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620200002.1048info:eu-repo/semantics/openAccessZimmermann,Camila AparecidaKoslowski,Luciano André DeitosAraújo,Maria Inês SiqueiraSilveira,Marcia Luciane Langeeng2020-07-22T00:00:00Zoai:scielo:S1517-70762020000200340Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2020-07-22T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
title |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
spellingShingle |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests Zimmermann,Camila Aparecida Carbon steel Corrosion Soluble Salts Content Epoxy Paint |
title_short |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
title_full |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
title_fullStr |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
title_full_unstemmed |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
title_sort |
The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests |
author |
Zimmermann,Camila Aparecida |
author_facet |
Zimmermann,Camila Aparecida Koslowski,Luciano André Deitos Araújo,Maria Inês Siqueira Silveira,Marcia Luciane Lange |
author_role |
author |
author2 |
Koslowski,Luciano André Deitos Araújo,Maria Inês Siqueira Silveira,Marcia Luciane Lange |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Zimmermann,Camila Aparecida Koslowski,Luciano André Deitos Araújo,Maria Inês Siqueira Silveira,Marcia Luciane Lange |
dc.subject.por.fl_str_mv |
Carbon steel Corrosion Soluble Salts Content Epoxy Paint |
topic |
Carbon steel Corrosion Soluble Salts Content Epoxy Paint |
description |
ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1517-707620200002.1048 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.25 n.2 2020 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
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1752126693034688512 |