The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests

Detalhes bibliográficos
Autor(a) principal: Zimmermann,Camila Aparecida
Data de Publicação: 2020
Outros Autores: Koslowski,Luciano André Deitos, Araújo,Maria Inês Siqueira, Silveira,Marcia Luciane Lange
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Matéria (Rio de Janeiro. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340
Resumo: ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed.
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spelling The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion testsCarbon steelCorrosionSoluble Salts ContentEpoxyPaintABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340Matéria (Rio de Janeiro) v.25 n.2 2020reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620200002.1048info:eu-repo/semantics/openAccessZimmermann,Camila AparecidaKoslowski,Luciano André DeitosAraújo,Maria Inês SiqueiraSilveira,Marcia Luciane Langeeng2020-07-22T00:00:00Zoai:scielo:S1517-70762020000200340Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2020-07-22T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false
dc.title.none.fl_str_mv The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
title The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
spellingShingle The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
Zimmermann,Camila Aparecida
Carbon steel
Corrosion
Soluble Salts Content
Epoxy
Paint
title_short The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
title_full The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
title_fullStr The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
title_full_unstemmed The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
title_sort The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests
author Zimmermann,Camila Aparecida
author_facet Zimmermann,Camila Aparecida
Koslowski,Luciano André Deitos
Araújo,Maria Inês Siqueira
Silveira,Marcia Luciane Lange
author_role author
author2 Koslowski,Luciano André Deitos
Araújo,Maria Inês Siqueira
Silveira,Marcia Luciane Lange
author2_role author
author
author
dc.contributor.author.fl_str_mv Zimmermann,Camila Aparecida
Koslowski,Luciano André Deitos
Araújo,Maria Inês Siqueira
Silveira,Marcia Luciane Lange
dc.subject.por.fl_str_mv Carbon steel
Corrosion
Soluble Salts Content
Epoxy
Paint
topic Carbon steel
Corrosion
Soluble Salts Content
Epoxy
Paint
description ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed.
publishDate 2020
dc.date.none.fl_str_mv 2020-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/s1517-707620200002.1048
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
dc.source.none.fl_str_mv Matéria (Rio de Janeiro) v.25 n.2 2020
reponame:Matéria (Rio de Janeiro. Online)
instname:Matéria (Rio de Janeiro. Online)
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instname_str Matéria (Rio de Janeiro. Online)
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institution RLAM
reponame_str Matéria (Rio de Janeiro. Online)
collection Matéria (Rio de Janeiro. Online)
repository.name.fl_str_mv Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)
repository.mail.fl_str_mv ||materia@labh2.coppe.ufrj.br
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