Surface and textural characterization of TiO2 pillared organoclays
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300757 |
Resumo: | ABSTRACTTiO2 organoclays are potential adsorbents for aqueous pollutants and subsequently they could favour the photocatalysis of them. For this reason, the study of their surface and textural characteristics is important for the improvement of those processes. In this work TiO2 pillared organoclays were studied. The surfactant (hexadecyltrimethilammonium bromide) was introduced post-pillaring or during the pillaring process. The effect of the use of different acids of hydrolysis and different surfactants ratios was investigated. The clays were characterized by thermogravimetric analysis, infrared spectroscopy and nitrogen sorptometry. It was found that the highest adsorption capacity post-pillaring of the surfactant is near to 0.5 times the CEC of the original pillared clay, independently of the amount of surfactant offered. An increment in the amount of the surfactant introduced only increased the ratio adsorbed as ionic pair. In these samples the CEC measured after the adsorption was between 0.26 and 0.47 times the original CEC. It was observed a decrease in the total pore volume and the BET surface for every sample. The surface hydrophobicity of the samples with post-pillaring adsorption was higher than in those with co-adsorption. In conclusion, it was demonstrated that the incorporation of surfactant modifies the surface and textural properties of the material in different extent in accordance with the incorporation stage and the amount of surfactant used. |
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Surface and textural characterization of TiO2 pillared organoclaysorganoclayspillared claystextural propertiessurface hydrophobicity.ABSTRACTTiO2 organoclays are potential adsorbents for aqueous pollutants and subsequently they could favour the photocatalysis of them. For this reason, the study of their surface and textural characteristics is important for the improvement of those processes. In this work TiO2 pillared organoclays were studied. The surfactant (hexadecyltrimethilammonium bromide) was introduced post-pillaring or during the pillaring process. The effect of the use of different acids of hydrolysis and different surfactants ratios was investigated. The clays were characterized by thermogravimetric analysis, infrared spectroscopy and nitrogen sorptometry. It was found that the highest adsorption capacity post-pillaring of the surfactant is near to 0.5 times the CEC of the original pillared clay, independently of the amount of surfactant offered. An increment in the amount of the surfactant introduced only increased the ratio adsorbed as ionic pair. In these samples the CEC measured after the adsorption was between 0.26 and 0.47 times the original CEC. It was observed a decrease in the total pore volume and the BET surface for every sample. The surface hydrophobicity of the samples with post-pillaring adsorption was higher than in those with co-adsorption. In conclusion, it was demonstrated that the incorporation of surfactant modifies the surface and textural properties of the material in different extent in accordance with the incorporation stage and the amount of surfactant used.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22015-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300757Matéria (Rio de Janeiro) v.20 n.3 2015reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/S1517-707620150003.0080info:eu-repo/semantics/openAccessZacur Vercelone,Sofía SusanaSham,Edgardo LingFarfán Torres,Elsa Mónicaeng2015-10-21T00:00:00Zoai:scielo:S1517-70762015000300757Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2015-10-21T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
Surface and textural characterization of TiO2 pillared organoclays |
title |
Surface and textural characterization of TiO2 pillared organoclays |
spellingShingle |
Surface and textural characterization of TiO2 pillared organoclays Zacur Vercelone,Sofía Susana organoclays pillared clays textural properties surface hydrophobicity. |
title_short |
Surface and textural characterization of TiO2 pillared organoclays |
title_full |
Surface and textural characterization of TiO2 pillared organoclays |
title_fullStr |
Surface and textural characterization of TiO2 pillared organoclays |
title_full_unstemmed |
Surface and textural characterization of TiO2 pillared organoclays |
title_sort |
Surface and textural characterization of TiO2 pillared organoclays |
author |
Zacur Vercelone,Sofía Susana |
author_facet |
Zacur Vercelone,Sofía Susana Sham,Edgardo Ling Farfán Torres,Elsa Mónica |
author_role |
author |
author2 |
Sham,Edgardo Ling Farfán Torres,Elsa Mónica |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Zacur Vercelone,Sofía Susana Sham,Edgardo Ling Farfán Torres,Elsa Mónica |
dc.subject.por.fl_str_mv |
organoclays pillared clays textural properties surface hydrophobicity. |
topic |
organoclays pillared clays textural properties surface hydrophobicity. |
description |
ABSTRACTTiO2 organoclays are potential adsorbents for aqueous pollutants and subsequently they could favour the photocatalysis of them. For this reason, the study of their surface and textural characteristics is important for the improvement of those processes. In this work TiO2 pillared organoclays were studied. The surfactant (hexadecyltrimethilammonium bromide) was introduced post-pillaring or during the pillaring process. The effect of the use of different acids of hydrolysis and different surfactants ratios was investigated. The clays were characterized by thermogravimetric analysis, infrared spectroscopy and nitrogen sorptometry. It was found that the highest adsorption capacity post-pillaring of the surfactant is near to 0.5 times the CEC of the original pillared clay, independently of the amount of surfactant offered. An increment in the amount of the surfactant introduced only increased the ratio adsorbed as ionic pair. In these samples the CEC measured after the adsorption was between 0.26 and 0.47 times the original CEC. It was observed a decrease in the total pore volume and the BET surface for every sample. The surface hydrophobicity of the samples with post-pillaring adsorption was higher than in those with co-adsorption. In conclusion, it was demonstrated that the incorporation of surfactant modifies the surface and textural properties of the material in different extent in accordance with the incorporation stage and the amount of surfactant used. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300757 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762015000300757 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1517-707620150003.0080 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.20 n.3 2015 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
_version_ |
1752126688863453184 |