Electrochemical corrosion characterization of nickel aluminides in acid rain
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000200408 |
Resumo: | ABSTRACT Nickel aluminides have been extensively studied in recent decades to replace superalloys, in some components of aircraft turbines, because they have excellent corrosion resistance. Many industrial cities have the problem of air pollution, which has forced the study of the degradation of these alloys in the presence of acid rain. The aim of this work is to study the electrochemical corrosion behavior of nickel aluminides in a medium of simulated acid rain. Potentiodynamic Polarization, Linear polarization resistance curves, Rp, Nyquist data and Bode curves obtained by electrochemical impedance spectroscopy were used to study the corrosion behavior of two intermetallic compounds. The polarization curves show that both intermetallic Ni3Al and NiAl have very similar corrosion potential, showing a slightly nobler behavior the NiAl intermetallic. The intermetallic Ni3Al has an active-passive behavior where the anode branch presents a general dissolution of the alloy, indicating that it is under cathodic control. NiAl intermetallic shows an active dissolution region, followed by a passive behavior. At longer immersion times, Ni3Al intermetallic has a higher polarization resistance, which means a lower corrosion rate. |
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Electrochemical corrosion characterization of nickel aluminides in acid rainNickel AluminidesElectrochemical impedance spectroscoyAcid RainNanoindentationABSTRACT Nickel aluminides have been extensively studied in recent decades to replace superalloys, in some components of aircraft turbines, because they have excellent corrosion resistance. Many industrial cities have the problem of air pollution, which has forced the study of the degradation of these alloys in the presence of acid rain. The aim of this work is to study the electrochemical corrosion behavior of nickel aluminides in a medium of simulated acid rain. Potentiodynamic Polarization, Linear polarization resistance curves, Rp, Nyquist data and Bode curves obtained by electrochemical impedance spectroscopy were used to study the corrosion behavior of two intermetallic compounds. The polarization curves show that both intermetallic Ni3Al and NiAl have very similar corrosion potential, showing a slightly nobler behavior the NiAl intermetallic. The intermetallic Ni3Al has an active-passive behavior where the anode branch presents a general dissolution of the alloy, indicating that it is under cathodic control. NiAl intermetallic shows an active dissolution region, followed by a passive behavior. At longer immersion times, Ni3Al intermetallic has a higher polarization resistance, which means a lower corrosion rate.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22018-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000200408Matéria (Rio de Janeiro) v.23 n.2 2018reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620180002.0335info:eu-repo/semantics/openAccessPadilla,Engelbert HuapeFlores,Ariosto MedinaRamírez,Claudio AguilarLópez,Ismeli AlfonsoGómez,Luis Béjareng2018-07-19T00:00:00Zoai:scielo:S1517-70762018000200408Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2018-07-19T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
title |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
spellingShingle |
Electrochemical corrosion characterization of nickel aluminides in acid rain Padilla,Engelbert Huape Nickel Aluminides Electrochemical impedance spectroscoy Acid Rain Nanoindentation |
title_short |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
title_full |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
title_fullStr |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
title_full_unstemmed |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
title_sort |
Electrochemical corrosion characterization of nickel aluminides in acid rain |
author |
Padilla,Engelbert Huape |
author_facet |
Padilla,Engelbert Huape Flores,Ariosto Medina Ramírez,Claudio Aguilar López,Ismeli Alfonso Gómez,Luis Béjar |
author_role |
author |
author2 |
Flores,Ariosto Medina Ramírez,Claudio Aguilar López,Ismeli Alfonso Gómez,Luis Béjar |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Padilla,Engelbert Huape Flores,Ariosto Medina Ramírez,Claudio Aguilar López,Ismeli Alfonso Gómez,Luis Béjar |
dc.subject.por.fl_str_mv |
Nickel Aluminides Electrochemical impedance spectroscoy Acid Rain Nanoindentation |
topic |
Nickel Aluminides Electrochemical impedance spectroscoy Acid Rain Nanoindentation |
description |
ABSTRACT Nickel aluminides have been extensively studied in recent decades to replace superalloys, in some components of aircraft turbines, because they have excellent corrosion resistance. Many industrial cities have the problem of air pollution, which has forced the study of the degradation of these alloys in the presence of acid rain. The aim of this work is to study the electrochemical corrosion behavior of nickel aluminides in a medium of simulated acid rain. Potentiodynamic Polarization, Linear polarization resistance curves, Rp, Nyquist data and Bode curves obtained by electrochemical impedance spectroscopy were used to study the corrosion behavior of two intermetallic compounds. The polarization curves show that both intermetallic Ni3Al and NiAl have very similar corrosion potential, showing a slightly nobler behavior the NiAl intermetallic. The intermetallic Ni3Al has an active-passive behavior where the anode branch presents a general dissolution of the alloy, indicating that it is under cathodic control. NiAl intermetallic shows an active dissolution region, followed by a passive behavior. At longer immersion times, Ni3Al intermetallic has a higher polarization resistance, which means a lower corrosion rate. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000200408 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762018000200408 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1517-707620180002.0335 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.23 n.2 2018 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
_version_ |
1752126690307342336 |