Heterogeneous catalytic system for biofuel generation

Detalhes bibliográficos
Autor(a) principal: Mosquera Canchingre, Alex Frederick
Data de Publicação: 2022
Outros Autores: Cruel Sigüenza, Joseph Alfonso, Tacoronte Morales, Juan Enrique, Bernal Villavicencio, Carla, Canchingre Bone, María Elizabeth
Tipo de documento: Artigo
Idioma: spa
Título da fonte: Sapienza (Curitiba)
Texto Completo: https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359
Resumo: The utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction.
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spelling Heterogeneous catalytic system for biofuel generationSistema catalítico heterogéneo para generación de biocombustible Sistema catalítico heterogêneo para geração de biocombustíveisÓleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadilFrying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphateAceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadiloThe utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction.La utilización de aceite de fritura usado (AFU) como recurso eco-sustentable y económico, constituye una estrategia, a escala meso y macro, viable y técnicamente factible a escala de programas de I+D en universidades y en la implementación de políticas de aprovechamiento de residuales con alto valor agregado. El AFU de algunos centros gastronómicos de la Ciudad de Esmeraldas se utilizó como materia prima para la obtención de biocombustible (biodiesel) vía transesterificación en condiciones catalíticas heterogéneas. Como catalizador del proceso se usó fosfato de vanadilo (VOPO4) sintetizado a partir de pentóxido de divanadio agotado proveniente de la síntesis de ácido sulfúrico. Para la obtención de biodiesel se aplicaron procesos de pretratamiento de las materias primas para eliminación de sólidos y disminución de índices de humedad y acidez; combustión en hornos de microondas, calcinación y síntesis sonoquímica para la obtención de catalizador. Utilizando aceite de frituras, fosfato de vanadilo y metanol en un micro reactor, a 115 °C y con 3% de catalizador se obtuvo biodiesel con satisfactorias características y rendimiento. Las condiciones óptimas determinadas del proceso de transesterificación fueron: relación molar aceite/metanol de 1:12,83 y 4,85 horas de reacción.A utilização de óleo de fritura usado (AFU) como recurso eco-sustentável e econômico constitui uma estratégia viável e tecnicamente viável, em meso e macro escala, na escala de programas de P&D em universidades e na implementação de políticas de aproveitamento. alto valor agregado. A AFU de alguns centros gastronômicos da cidade de Esmeraldas foi utilizada como matéria-prima para a obtenção de biocombustível (biodiesel) via transesterificação em condições catalíticas heterogêneas. Fosfato de vanadil (VOPO4) sintetizado a partir de pentóxido de divanádio exaurido da síntese de ácido sulfúrico foi usado como catalisador do processo. Para a obtenção do biodiesel, foram aplicados processos de pré-tratamento da matéria-prima para eliminar sólidos e diminuir os índices de umidade e acidez; combustão em fornos de micro-ondas, calcinação e síntese sonoquímica para obtenção do catalisador. Utilizando óleo de fritura, fosfato de vanadil e metanol em microrreator a 115 °C e com 3% de catalisador, obteve-se biodiesel com características e desempenho satisfatórios. As condições ótimas determinadas para o processo de transesterificação foram: razão molar óleo/metanol de 1:12,83 e 4,85 horas de reação.Sapienza Grupo Editorial2022-05-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/35910.51798/sijis.v3i2.359Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 No. 2 (2022): Multidisciplinary Contributions; 549-559Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 Núm. 2 (2022): Aportes Multidisciplinarios; 549-559Sapienza: International Journal of Interdisciplinary Studies; v. 3 n. 2 (2022): Contribuições Multidisciplinares; 549-5592675-978010.51798/sijis.v3i2reponame:Sapienza (Curitiba)instname:Sapienza Grupo Editorialinstacron:SAPIENZAspahttps://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359/232Copyright (c) 2022 Alex Frederick Mosquera Canchingre, Joseph Alfonso Cruel Sigüenza, Juan Enrique Tacoronte Morales, Carla Bernal Villavicencio, María Elizabeth Canchingre Bonehttps://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessMosquera Canchingre, Alex Frederick Cruel Sigüenza, Joseph AlfonsoTacoronte Morales, Juan Enrique Bernal Villavicencio, Carla Canchingre Bone, María Elizabeth 2022-12-26T21:19:06Zoai:ojs2.journals.sapienzaeditorial.com:article/359Revistahttps://journals.sapienzaeditorial.com/index.php/SIJISPRIhttps://journals.sapienzaeditorial.com/index.php/SIJIS/oaieditor@sapienzaeditorial.com2675-97802675-9780opendoar:2023-01-12T16:42:57.175199Sapienza (Curitiba) - Sapienza Grupo Editorialfalse
dc.title.none.fl_str_mv Heterogeneous catalytic system for biofuel generation
Sistema catalítico heterogéneo para generación de biocombustible
Sistema catalítico heterogêneo para geração de biocombustíveis
title Heterogeneous catalytic system for biofuel generation
spellingShingle Heterogeneous catalytic system for biofuel generation
Mosquera Canchingre, Alex Frederick
Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil
Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate
Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo
title_short Heterogeneous catalytic system for biofuel generation
title_full Heterogeneous catalytic system for biofuel generation
title_fullStr Heterogeneous catalytic system for biofuel generation
title_full_unstemmed Heterogeneous catalytic system for biofuel generation
title_sort Heterogeneous catalytic system for biofuel generation
author Mosquera Canchingre, Alex Frederick
author_facet Mosquera Canchingre, Alex Frederick
Cruel Sigüenza, Joseph Alfonso
Tacoronte Morales, Juan Enrique
Bernal Villavicencio, Carla
Canchingre Bone, María Elizabeth
author_role author
author2 Cruel Sigüenza, Joseph Alfonso
Tacoronte Morales, Juan Enrique
Bernal Villavicencio, Carla
Canchingre Bone, María Elizabeth
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Mosquera Canchingre, Alex Frederick
Cruel Sigüenza, Joseph Alfonso
Tacoronte Morales, Juan Enrique
Bernal Villavicencio, Carla
Canchingre Bone, María Elizabeth
dc.subject.por.fl_str_mv Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil
Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate
Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo
topic Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil
Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate
Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo
description The utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction.
publishDate 2022
dc.date.none.fl_str_mv 2022-05-14
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359
10.51798/sijis.v3i2.359
url https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359
identifier_str_mv 10.51798/sijis.v3i2.359
dc.language.iso.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359/232
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rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Sapienza Grupo Editorial
publisher.none.fl_str_mv Sapienza Grupo Editorial
dc.source.none.fl_str_mv Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 No. 2 (2022): Multidisciplinary Contributions; 549-559
Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 Núm. 2 (2022): Aportes Multidisciplinarios; 549-559
Sapienza: International Journal of Interdisciplinary Studies; v. 3 n. 2 (2022): Contribuições Multidisciplinares; 549-559
2675-9780
10.51798/sijis.v3i2
reponame:Sapienza (Curitiba)
instname:Sapienza Grupo Editorial
instacron:SAPIENZA
instname_str Sapienza Grupo Editorial
instacron_str SAPIENZA
institution SAPIENZA
reponame_str Sapienza (Curitiba)
collection Sapienza (Curitiba)
repository.name.fl_str_mv Sapienza (Curitiba) - Sapienza Grupo Editorial
repository.mail.fl_str_mv editor@sapienzaeditorial.com
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