Heterogeneous catalytic system for biofuel generation
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | spa |
Título da fonte: | Sapienza (Curitiba) |
Texto Completo: | https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359 |
Resumo: | The utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction. |
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Heterogeneous catalytic system for biofuel generationSistema catalítico heterogéneo para generación de biocombustible Sistema catalítico heterogêneo para geração de biocombustíveisÓleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadilFrying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphateAceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadiloThe utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction.La utilización de aceite de fritura usado (AFU) como recurso eco-sustentable y económico, constituye una estrategia, a escala meso y macro, viable y técnicamente factible a escala de programas de I+D en universidades y en la implementación de políticas de aprovechamiento de residuales con alto valor agregado. El AFU de algunos centros gastronómicos de la Ciudad de Esmeraldas se utilizó como materia prima para la obtención de biocombustible (biodiesel) vía transesterificación en condiciones catalíticas heterogéneas. Como catalizador del proceso se usó fosfato de vanadilo (VOPO4) sintetizado a partir de pentóxido de divanadio agotado proveniente de la síntesis de ácido sulfúrico. Para la obtención de biodiesel se aplicaron procesos de pretratamiento de las materias primas para eliminación de sólidos y disminución de índices de humedad y acidez; combustión en hornos de microondas, calcinación y síntesis sonoquímica para la obtención de catalizador. Utilizando aceite de frituras, fosfato de vanadilo y metanol en un micro reactor, a 115 °C y con 3% de catalizador se obtuvo biodiesel con satisfactorias características y rendimiento. Las condiciones óptimas determinadas del proceso de transesterificación fueron: relación molar aceite/metanol de 1:12,83 y 4,85 horas de reacción.A utilização de óleo de fritura usado (AFU) como recurso eco-sustentável e econômico constitui uma estratégia viável e tecnicamente viável, em meso e macro escala, na escala de programas de P&D em universidades e na implementação de políticas de aproveitamento. alto valor agregado. A AFU de alguns centros gastronômicos da cidade de Esmeraldas foi utilizada como matéria-prima para a obtenção de biocombustível (biodiesel) via transesterificação em condições catalíticas heterogêneas. Fosfato de vanadil (VOPO4) sintetizado a partir de pentóxido de divanádio exaurido da síntese de ácido sulfúrico foi usado como catalisador do processo. Para a obtenção do biodiesel, foram aplicados processos de pré-tratamento da matéria-prima para eliminar sólidos e diminuir os índices de umidade e acidez; combustão em fornos de micro-ondas, calcinação e síntese sonoquímica para obtenção do catalisador. Utilizando óleo de fritura, fosfato de vanadil e metanol em microrreator a 115 °C e com 3% de catalisador, obteve-se biodiesel com características e desempenho satisfatórios. As condições ótimas determinadas para o processo de transesterificação foram: razão molar óleo/metanol de 1:12,83 e 4,85 horas de reação.Sapienza Grupo Editorial2022-05-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/35910.51798/sijis.v3i2.359Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 No. 2 (2022): Multidisciplinary Contributions; 549-559Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 Núm. 2 (2022): Aportes Multidisciplinarios; 549-559Sapienza: International Journal of Interdisciplinary Studies; v. 3 n. 2 (2022): Contribuições Multidisciplinares; 549-5592675-978010.51798/sijis.v3i2reponame:Sapienza (Curitiba)instname:Sapienza Grupo Editorialinstacron:SAPIENZAspahttps://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359/232Copyright (c) 2022 Alex Frederick Mosquera Canchingre, Joseph Alfonso Cruel Sigüenza, Juan Enrique Tacoronte Morales, Carla Bernal Villavicencio, María Elizabeth Canchingre Bonehttps://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessMosquera Canchingre, Alex Frederick Cruel Sigüenza, Joseph AlfonsoTacoronte Morales, Juan Enrique Bernal Villavicencio, Carla Canchingre Bone, María Elizabeth 2022-12-26T21:19:06Zoai:ojs2.journals.sapienzaeditorial.com:article/359Revistahttps://journals.sapienzaeditorial.com/index.php/SIJISPRIhttps://journals.sapienzaeditorial.com/index.php/SIJIS/oaieditor@sapienzaeditorial.com2675-97802675-9780opendoar:2023-01-12T16:42:57.175199Sapienza (Curitiba) - Sapienza Grupo Editorialfalse |
dc.title.none.fl_str_mv |
Heterogeneous catalytic system for biofuel generation Sistema catalítico heterogéneo para generación de biocombustible Sistema catalítico heterogêneo para geração de biocombustíveis |
title |
Heterogeneous catalytic system for biofuel generation |
spellingShingle |
Heterogeneous catalytic system for biofuel generation Mosquera Canchingre, Alex Frederick Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo |
title_short |
Heterogeneous catalytic system for biofuel generation |
title_full |
Heterogeneous catalytic system for biofuel generation |
title_fullStr |
Heterogeneous catalytic system for biofuel generation |
title_full_unstemmed |
Heterogeneous catalytic system for biofuel generation |
title_sort |
Heterogeneous catalytic system for biofuel generation |
author |
Mosquera Canchingre, Alex Frederick |
author_facet |
Mosquera Canchingre, Alex Frederick Cruel Sigüenza, Joseph Alfonso Tacoronte Morales, Juan Enrique Bernal Villavicencio, Carla Canchingre Bone, María Elizabeth |
author_role |
author |
author2 |
Cruel Sigüenza, Joseph Alfonso Tacoronte Morales, Juan Enrique Bernal Villavicencio, Carla Canchingre Bone, María Elizabeth |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Mosquera Canchingre, Alex Frederick Cruel Sigüenza, Joseph Alfonso Tacoronte Morales, Juan Enrique Bernal Villavicencio, Carla Canchingre Bone, María Elizabeth |
dc.subject.por.fl_str_mv |
Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo |
topic |
Óleo de fritura; transesterificação; catálise heterogênea; biodiesel; fosfato de vanadil Frying oil; Transesterification; Heterogeneous catalysis; Biodiesel; Vanadyl phosphate Aceite de frituras; Transesterificación; Catálisis heterogénea; Biodiesel; Fosfato de vanadilo |
description |
The utilization of used frying oil (AFU) as an eco-sustainable and economic resource constitutes a viable and technically feasible strategy at the meso and macro scale for R&D programs in universities and in the implementation of policies for the use of waste with high added value. The AFU from some gastronomic centers in the city of Esmeraldas was used as raw material to obtain biofuel (biodiesel) via trans-esterification under heterogeneous catalytic conditions. Vanadyl phosphate (VOPO4) synthesized from depleted divanadium pentoxide from sulfuric acid synthesis was used as a catalyst for the process. To obtain biodiesel, pre-treatment processes were applied to the raw materials to eliminate solids and reduce moisture and acidity indexes; combustion in microwave ovens, calcination and sonochemical synthesis to obtain the catalyst. Using frying oil, vanadyl phosphate and methanol in a micro-reactor, at 115 °C and with 3% catalyst, biodiesel was obtained with satisfactory characteristics and yield. The optimum conditions determined for the trans-esterification process were: oil/methanol molar ratio of 1:12.83 and 4.85 hours of reaction. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-05-14 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359 10.51798/sijis.v3i2.359 |
url |
https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359 |
identifier_str_mv |
10.51798/sijis.v3i2.359 |
dc.language.iso.fl_str_mv |
spa |
language |
spa |
dc.relation.none.fl_str_mv |
https://journals.sapienzaeditorial.com/index.php/SIJIS/article/view/359/232 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by-nc-nd/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Sapienza Grupo Editorial |
publisher.none.fl_str_mv |
Sapienza Grupo Editorial |
dc.source.none.fl_str_mv |
Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 No. 2 (2022): Multidisciplinary Contributions; 549-559 Sapienza: International Journal of Interdisciplinary Studies; Vol. 3 Núm. 2 (2022): Aportes Multidisciplinarios; 549-559 Sapienza: International Journal of Interdisciplinary Studies; v. 3 n. 2 (2022): Contribuições Multidisciplinares; 549-559 2675-9780 10.51798/sijis.v3i2 reponame:Sapienza (Curitiba) instname:Sapienza Grupo Editorial instacron:SAPIENZA |
instname_str |
Sapienza Grupo Editorial |
instacron_str |
SAPIENZA |
institution |
SAPIENZA |
reponame_str |
Sapienza (Curitiba) |
collection |
Sapienza (Curitiba) |
repository.name.fl_str_mv |
Sapienza (Curitiba) - Sapienza Grupo Editorial |
repository.mail.fl_str_mv |
editor@sapienzaeditorial.com |
_version_ |
1797051608338530304 |