FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Engenharia Agrícola |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162020000300374 |
Resumo: | ABSTRACT This study aimed to obtain and evaluate thermodynamic properties and hygroscopic equilibrium isotherms of urunday seeds as a function of air relative humidity and temperature, as well as identify the best-fitted mathematical models for adsorption phenomenon. A static-gravimetric method was used to obtain hygroscopic equilibrium moisture content. Seeds were placed in airtight containers with different saturated saline solutions for relative humidity control. These were then kept in BOD incubator chambers at 10, 20, 30, and 40 °C. Hygroscopic equilibrium moisture content decreased as temperature increased, for the same water activity. The Sigma-Copace model best-fitted seed adsorption data for equilibrium water activity intervals between 0.1129 and 0.8232 (dry basis). Both vaporization latent-heat and differential sorption entropy increased with decreasing hygroscopic equilibrium moisture content. Adsorption process in urunday seeds was controlled by enthalpy. |
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Engenharia Agrícola |
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FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDSwater activityisokineticsorption isothermsMyracrodruon urundeuvarelative humidityABSTRACT This study aimed to obtain and evaluate thermodynamic properties and hygroscopic equilibrium isotherms of urunday seeds as a function of air relative humidity and temperature, as well as identify the best-fitted mathematical models for adsorption phenomenon. A static-gravimetric method was used to obtain hygroscopic equilibrium moisture content. Seeds were placed in airtight containers with different saturated saline solutions for relative humidity control. These were then kept in BOD incubator chambers at 10, 20, 30, and 40 °C. Hygroscopic equilibrium moisture content decreased as temperature increased, for the same water activity. The Sigma-Copace model best-fitted seed adsorption data for equilibrium water activity intervals between 0.1129 and 0.8232 (dry basis). Both vaporization latent-heat and differential sorption entropy increased with decreasing hygroscopic equilibrium moisture content. Adsorption process in urunday seeds was controlled by enthalpy.Associação Brasileira de Engenharia Agrícola2020-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162020000300374Engenharia Agrícola v.40 n.3 2020reponame:Engenharia Agrícolainstname:Associação Brasileira de Engenharia Agrícola (SBEA)instacron:SBEA10.1590/1809-4430-eng.agric.v40n3p374-380/2020info:eu-repo/semantics/openAccessIsquierdo,Eder P.Caldeira,Daniela S. A.Siqueira,Valdiney C.Martins,Elton A. S.Quequeto,Wellytton D.eng2020-08-25T00:00:00Zoai:scielo:S0100-69162020000300374Revistahttp://www.engenhariaagricola.org.br/ORGhttps://old.scielo.br/oai/scielo-oai.phprevistasbea@sbea.org.br||sbea@sbea.org.br1809-44300100-6916opendoar:2020-08-25T00:00Engenharia Agrícola - Associação Brasileira de Engenharia Agrícola (SBEA)false |
dc.title.none.fl_str_mv |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
title |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
spellingShingle |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS Isquierdo,Eder P. water activity isokinetic sorption isotherms Myracrodruon urundeuva relative humidity |
title_short |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
title_full |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
title_fullStr |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
title_full_unstemmed |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
title_sort |
FITTINGS OF ADSORPTION ISOTHERM MODELS AND THERMODYNAMIC PROPERTIES OF URUNDAY SEEDS |
author |
Isquierdo,Eder P. |
author_facet |
Isquierdo,Eder P. Caldeira,Daniela S. A. Siqueira,Valdiney C. Martins,Elton A. S. Quequeto,Wellytton D. |
author_role |
author |
author2 |
Caldeira,Daniela S. A. Siqueira,Valdiney C. Martins,Elton A. S. Quequeto,Wellytton D. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Isquierdo,Eder P. Caldeira,Daniela S. A. Siqueira,Valdiney C. Martins,Elton A. S. Quequeto,Wellytton D. |
dc.subject.por.fl_str_mv |
water activity isokinetic sorption isotherms Myracrodruon urundeuva relative humidity |
topic |
water activity isokinetic sorption isotherms Myracrodruon urundeuva relative humidity |
description |
ABSTRACT This study aimed to obtain and evaluate thermodynamic properties and hygroscopic equilibrium isotherms of urunday seeds as a function of air relative humidity and temperature, as well as identify the best-fitted mathematical models for adsorption phenomenon. A static-gravimetric method was used to obtain hygroscopic equilibrium moisture content. Seeds were placed in airtight containers with different saturated saline solutions for relative humidity control. These were then kept in BOD incubator chambers at 10, 20, 30, and 40 °C. Hygroscopic equilibrium moisture content decreased as temperature increased, for the same water activity. The Sigma-Copace model best-fitted seed adsorption data for equilibrium water activity intervals between 0.1129 and 0.8232 (dry basis). Both vaporization latent-heat and differential sorption entropy increased with decreasing hygroscopic equilibrium moisture content. Adsorption process in urunday seeds was controlled by enthalpy. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162020000300374 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162020000300374 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1809-4430-eng.agric.v40n3p374-380/2020 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Engenharia Agrícola |
publisher.none.fl_str_mv |
Associação Brasileira de Engenharia Agrícola |
dc.source.none.fl_str_mv |
Engenharia Agrícola v.40 n.3 2020 reponame:Engenharia Agrícola instname:Associação Brasileira de Engenharia Agrícola (SBEA) instacron:SBEA |
instname_str |
Associação Brasileira de Engenharia Agrícola (SBEA) |
instacron_str |
SBEA |
institution |
SBEA |
reponame_str |
Engenharia Agrícola |
collection |
Engenharia Agrícola |
repository.name.fl_str_mv |
Engenharia Agrícola - Associação Brasileira de Engenharia Agrícola (SBEA) |
repository.mail.fl_str_mv |
revistasbea@sbea.org.br||sbea@sbea.org.br |
_version_ |
1752126274827976704 |