Structure of the analytical theories of heat
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Revista Brasileira de Ensino de Física (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-11172022000100427 |
Resumo: | We examine the analytical theories of heat developed by Laplace, Poisson and Carnot, and the thermodynamic theories based on the energy conservation and the principle of the increase of entropy formulated by Clausius. We present an analysis of the approaches developed by Maxwell, Gibbs, Planck, Duhem, Nernst, and De Donder as well as the irreversible thermodynamics of Prigogine, and the theory of liquid gas transition of van der Waals. We show that the thermodynamic potentials dominated the development of the theory of thermodynamics since Gibbs. They were introduced by Massieu under the name of characteristic functions and were demonstrated by Gibbs to have the suitable properties to characterize equilibrium of systems with variable composition, and to hold the convexity properties. We also show that the thermodynamic potentials were the relevant quantity in the Duhem approach to thermodynamics and to thermochemistry. |
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Structure of the analytical theories of heatAnalytical theoriestheories of heatthermodynamicsthermochemistryWe examine the analytical theories of heat developed by Laplace, Poisson and Carnot, and the thermodynamic theories based on the energy conservation and the principle of the increase of entropy formulated by Clausius. We present an analysis of the approaches developed by Maxwell, Gibbs, Planck, Duhem, Nernst, and De Donder as well as the irreversible thermodynamics of Prigogine, and the theory of liquid gas transition of van der Waals. We show that the thermodynamic potentials dominated the development of the theory of thermodynamics since Gibbs. They were introduced by Massieu under the name of characteristic functions and were demonstrated by Gibbs to have the suitable properties to characterize equilibrium of systems with variable composition, and to hold the convexity properties. We also show that the thermodynamic potentials were the relevant quantity in the Duhem approach to thermodynamics and to thermochemistry.Sociedade Brasileira de Física2022-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-11172022000100427Revista Brasileira de Ensino de Física v.44 2022reponame:Revista Brasileira de Ensino de Física (Online)instname:Sociedade Brasileira de Física (SBF)instacron:SBF10.1590/1806-9126-rbef-2022-0008info:eu-repo/semantics/openAccessde Oliveira,Mário J.eng2022-03-30T00:00:00Zoai:scielo:S1806-11172022000100427Revistahttp://www.sbfisica.org.br/rbef/https://old.scielo.br/oai/scielo-oai.php||marcio@sbfisica.org.br1806-91261806-1117opendoar:2022-03-30T00:00Revista Brasileira de Ensino de Física (Online) - Sociedade Brasileira de Física (SBF)false |
dc.title.none.fl_str_mv |
Structure of the analytical theories of heat |
title |
Structure of the analytical theories of heat |
spellingShingle |
Structure of the analytical theories of heat de Oliveira,Mário J. Analytical theories theories of heat thermodynamics thermochemistry |
title_short |
Structure of the analytical theories of heat |
title_full |
Structure of the analytical theories of heat |
title_fullStr |
Structure of the analytical theories of heat |
title_full_unstemmed |
Structure of the analytical theories of heat |
title_sort |
Structure of the analytical theories of heat |
author |
de Oliveira,Mário J. |
author_facet |
de Oliveira,Mário J. |
author_role |
author |
dc.contributor.author.fl_str_mv |
de Oliveira,Mário J. |
dc.subject.por.fl_str_mv |
Analytical theories theories of heat thermodynamics thermochemistry |
topic |
Analytical theories theories of heat thermodynamics thermochemistry |
description |
We examine the analytical theories of heat developed by Laplace, Poisson and Carnot, and the thermodynamic theories based on the energy conservation and the principle of the increase of entropy formulated by Clausius. We present an analysis of the approaches developed by Maxwell, Gibbs, Planck, Duhem, Nernst, and De Donder as well as the irreversible thermodynamics of Prigogine, and the theory of liquid gas transition of van der Waals. We show that the thermodynamic potentials dominated the development of the theory of thermodynamics since Gibbs. They were introduced by Massieu under the name of characteristic functions and were demonstrated by Gibbs to have the suitable properties to characterize equilibrium of systems with variable composition, and to hold the convexity properties. We also show that the thermodynamic potentials were the relevant quantity in the Duhem approach to thermodynamics and to thermochemistry. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-11172022000100427 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1806-11172022000100427 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1806-9126-rbef-2022-0008 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
dc.source.none.fl_str_mv |
Revista Brasileira de Ensino de Física v.44 2022 reponame:Revista Brasileira de Ensino de Física (Online) instname:Sociedade Brasileira de Física (SBF) instacron:SBF |
instname_str |
Sociedade Brasileira de Física (SBF) |
instacron_str |
SBF |
institution |
SBF |
reponame_str |
Revista Brasileira de Ensino de Física (Online) |
collection |
Revista Brasileira de Ensino de Física (Online) |
repository.name.fl_str_mv |
Revista Brasileira de Ensino de Física (Online) - Sociedade Brasileira de Física (SBF) |
repository.mail.fl_str_mv |
||marcio@sbfisica.org.br |
_version_ |
1752122425945882624 |