Catalysis with competitive reactions: static and dynamical critical behavior
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Physics |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332003000300010 |
Resumo: | We studied in this work a competitive reaction model between monomers on a catalyst. The catalyst is represented by hypercubic lattices in d = 1, 2 and 3 dimensions. The model is described by the following reactions: A + A -> A2 and A + B -> AB, where A and B are two monomers that arrive at the surface with probabilities yA and yB, respectively. The model is studied in the adsorption controlled limit where the reaction rate is infinitely larger than the adsorption rate. We employ site and pair mean-field approximations as well as static and dynamical Monte Carlo simulations. We show that, for all d, the model exhibits a continuous phase transition between an active steady state and a B-absorbing state, when the parameter yA is varied through a critical value. Monte Carlo simulations and finite-size scaling analysis near the critical point are used to determine the static critical exponents b,n^ and the dynamical critical exponents n||, d, h and z. The results found for this competitive reaction model are in accordance with the conjecture of Grassberger, which states that any system undergoing a continuous phase transition from an active steady state to a single absorbing state, exhibits the same critical behavior of the directed percolation universality class. |
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Brazilian Journal of Physics |
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Catalysis with competitive reactions: static and dynamical critical behaviorWe studied in this work a competitive reaction model between monomers on a catalyst. The catalyst is represented by hypercubic lattices in d = 1, 2 and 3 dimensions. The model is described by the following reactions: A + A -> A2 and A + B -> AB, where A and B are two monomers that arrive at the surface with probabilities yA and yB, respectively. The model is studied in the adsorption controlled limit where the reaction rate is infinitely larger than the adsorption rate. We employ site and pair mean-field approximations as well as static and dynamical Monte Carlo simulations. We show that, for all d, the model exhibits a continuous phase transition between an active steady state and a B-absorbing state, when the parameter yA is varied through a critical value. Monte Carlo simulations and finite-size scaling analysis near the critical point are used to determine the static critical exponents b,n^ and the dynamical critical exponents n||, d, h and z. The results found for this competitive reaction model are in accordance with the conjecture of Grassberger, which states that any system undergoing a continuous phase transition from an active steady state to a single absorbing state, exhibits the same critical behavior of the directed percolation universality class.Sociedade Brasileira de Física2003-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332003000300010Brazilian Journal of Physics v.33 n.3 2003reponame:Brazilian Journal of Physicsinstname:Sociedade Brasileira de Física (SBF)instacron:SBF10.1590/S0103-97332003000300010info:eu-repo/semantics/openAccessCosta,E. C. daFigueiredo,W.eng2003-11-20T00:00:00Zoai:scielo:S0103-97332003000300010Revistahttp://www.sbfisica.org.br/v1/home/index.php/pt/ONGhttps://old.scielo.br/oai/scielo-oai.phpsbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br1678-44480103-9733opendoar:2003-11-20T00:00Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)false |
dc.title.none.fl_str_mv |
Catalysis with competitive reactions: static and dynamical critical behavior |
title |
Catalysis with competitive reactions: static and dynamical critical behavior |
spellingShingle |
Catalysis with competitive reactions: static and dynamical critical behavior Costa,E. C. da |
title_short |
Catalysis with competitive reactions: static and dynamical critical behavior |
title_full |
Catalysis with competitive reactions: static and dynamical critical behavior |
title_fullStr |
Catalysis with competitive reactions: static and dynamical critical behavior |
title_full_unstemmed |
Catalysis with competitive reactions: static and dynamical critical behavior |
title_sort |
Catalysis with competitive reactions: static and dynamical critical behavior |
author |
Costa,E. C. da |
author_facet |
Costa,E. C. da Figueiredo,W. |
author_role |
author |
author2 |
Figueiredo,W. |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Costa,E. C. da Figueiredo,W. |
description |
We studied in this work a competitive reaction model between monomers on a catalyst. The catalyst is represented by hypercubic lattices in d = 1, 2 and 3 dimensions. The model is described by the following reactions: A + A -> A2 and A + B -> AB, where A and B are two monomers that arrive at the surface with probabilities yA and yB, respectively. The model is studied in the adsorption controlled limit where the reaction rate is infinitely larger than the adsorption rate. We employ site and pair mean-field approximations as well as static and dynamical Monte Carlo simulations. We show that, for all d, the model exhibits a continuous phase transition between an active steady state and a B-absorbing state, when the parameter yA is varied through a critical value. Monte Carlo simulations and finite-size scaling analysis near the critical point are used to determine the static critical exponents b,n^ and the dynamical critical exponents n||, d, h and z. The results found for this competitive reaction model are in accordance with the conjecture of Grassberger, which states that any system undergoing a continuous phase transition from an active steady state to a single absorbing state, exhibits the same critical behavior of the directed percolation universality class. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332003000300010 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332003000300010 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-97332003000300010 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
dc.source.none.fl_str_mv |
Brazilian Journal of Physics v.33 n.3 2003 reponame:Brazilian Journal of Physics instname:Sociedade Brasileira de Física (SBF) instacron:SBF |
instname_str |
Sociedade Brasileira de Física (SBF) |
instacron_str |
SBF |
institution |
SBF |
reponame_str |
Brazilian Journal of Physics |
collection |
Brazilian Journal of Physics |
repository.name.fl_str_mv |
Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF) |
repository.mail.fl_str_mv |
sbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br |
_version_ |
1754734860413435904 |