Photophysics of poly(p-phenylene vinylene) films
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Physics |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332004000400035 |
Resumo: | We report on time resolved photoluminescence (PLRT) measurements in poly(p-phenylene vinylene) (PPV) films irradiated by laser in the presence of air. We observe a PL intensity enhancement and a biexponential decay dynamics of PL signal for all irradiated films. These results can be understood in terms of a chain shortening process due to carbonyl incorporation and formation of an energy profile that extends and migrates into the film and enables efficient spectral diffusion of excited carriers to a non-degraded PPV segments by Förster energy transfer. |
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Brazilian Journal of Physics |
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Photophysics of poly(p-phenylene vinylene) filmsWe report on time resolved photoluminescence (PLRT) measurements in poly(p-phenylene vinylene) (PPV) films irradiated by laser in the presence of air. We observe a PL intensity enhancement and a biexponential decay dynamics of PL signal for all irradiated films. These results can be understood in terms of a chain shortening process due to carbonyl incorporation and formation of an energy profile that extends and migrates into the film and enables efficient spectral diffusion of excited carriers to a non-degraded PPV segments by Förster energy transfer.Sociedade Brasileira de Física2004-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332004000400035Brazilian Journal of Physics v.34 n.2b 2004reponame:Brazilian Journal of Physicsinstname:Sociedade Brasileira de Física (SBF)instacron:SBF10.1590/S0103-97332004000400035info:eu-repo/semantics/openAccessAnni,M.Gigli,G.Cingolani,R.Gobato,Y. GalvãoVercik,A.Marletta,A.Guimarães,F.G. E.Faria,R. M.eng2004-08-31T00:00:00Zoai:scielo:S0103-97332004000400035Revistahttp://www.sbfisica.org.br/v1/home/index.php/pt/ONGhttps://old.scielo.br/oai/scielo-oai.phpsbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br1678-44480103-9733opendoar:2004-08-31T00:00Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)false |
dc.title.none.fl_str_mv |
Photophysics of poly(p-phenylene vinylene) films |
title |
Photophysics of poly(p-phenylene vinylene) films |
spellingShingle |
Photophysics of poly(p-phenylene vinylene) films Anni,M. |
title_short |
Photophysics of poly(p-phenylene vinylene) films |
title_full |
Photophysics of poly(p-phenylene vinylene) films |
title_fullStr |
Photophysics of poly(p-phenylene vinylene) films |
title_full_unstemmed |
Photophysics of poly(p-phenylene vinylene) films |
title_sort |
Photophysics of poly(p-phenylene vinylene) films |
author |
Anni,M. |
author_facet |
Anni,M. Gigli,G. Cingolani,R. Gobato,Y. Galvão Vercik,A. Marletta,A. Guimarães,F.G. E. Faria,R. M. |
author_role |
author |
author2 |
Gigli,G. Cingolani,R. Gobato,Y. Galvão Vercik,A. Marletta,A. Guimarães,F.G. E. Faria,R. M. |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Anni,M. Gigli,G. Cingolani,R. Gobato,Y. Galvão Vercik,A. Marletta,A. Guimarães,F.G. E. Faria,R. M. |
description |
We report on time resolved photoluminescence (PLRT) measurements in poly(p-phenylene vinylene) (PPV) films irradiated by laser in the presence of air. We observe a PL intensity enhancement and a biexponential decay dynamics of PL signal for all irradiated films. These results can be understood in terms of a chain shortening process due to carbonyl incorporation and formation of an energy profile that extends and migrates into the film and enables efficient spectral diffusion of excited carriers to a non-degraded PPV segments by Förster energy transfer. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332004000400035 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332004000400035 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-97332004000400035 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
publisher.none.fl_str_mv |
Sociedade Brasileira de Física |
dc.source.none.fl_str_mv |
Brazilian Journal of Physics v.34 n.2b 2004 reponame:Brazilian Journal of Physics instname:Sociedade Brasileira de Física (SBF) instacron:SBF |
instname_str |
Sociedade Brasileira de Física (SBF) |
instacron_str |
SBF |
institution |
SBF |
reponame_str |
Brazilian Journal of Physics |
collection |
Brazilian Journal of Physics |
repository.name.fl_str_mv |
Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF) |
repository.mail.fl_str_mv |
sbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br |
_version_ |
1754734861066698752 |