Near-infrared emission of Nd-PSS films

Detalhes bibliográficos
Autor(a) principal: Silva,Marcelo C.
Data de Publicação: 2006
Outros Autores: Cristovan,Fernando H., Ruggiero,Reinaldo, Cruz,W. O., Marletta,A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Physics
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332006000300071
Resumo: We report a study of a new chemical synthetic route of polystyrene sulphonate (PSS) films doped with neodymium ion (Nd+3) from a neodymium nitrate solution. The UV-Vis-NIR spectrum presents an intense characteristic electronic transition at 800 nm and the infrared spectrum presents low definition bands as a result of Nd3+ coordination with PSS molecule. Additionally, the spectrum of Nd-PSS film presents the same line shape profile of Nd3+ salt in aqueous solution. Selective luminescence spectroscopy measures shows that the incorporation of neodymium ion introduces a red shift bands and a better line shape definition in UV luminescence compared to PSS film, decreasing the interaction between PSS aromatic groups. The near-infrared emission was observed in the large spectrum region from 600 to 800 nm; it is associated with the Nd3+ complex of PSS monomer.
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spelling Near-infrared emission of Nd-PSS filmsPolystyrene sulphonateNeodymium ions and synthesis routeWe report a study of a new chemical synthetic route of polystyrene sulphonate (PSS) films doped with neodymium ion (Nd+3) from a neodymium nitrate solution. The UV-Vis-NIR spectrum presents an intense characteristic electronic transition at 800 nm and the infrared spectrum presents low definition bands as a result of Nd3+ coordination with PSS molecule. Additionally, the spectrum of Nd-PSS film presents the same line shape profile of Nd3+ salt in aqueous solution. Selective luminescence spectroscopy measures shows that the incorporation of neodymium ion introduces a red shift bands and a better line shape definition in UV luminescence compared to PSS film, decreasing the interaction between PSS aromatic groups. The near-infrared emission was observed in the large spectrum region from 600 to 800 nm; it is associated with the Nd3+ complex of PSS monomer.Sociedade Brasileira de Física2006-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332006000300071Brazilian Journal of Physics v.36 n.2a 2006reponame:Brazilian Journal of Physicsinstname:Sociedade Brasileira de Física (SBF)instacron:SBF10.1590/S0103-97332006000300071info:eu-repo/semantics/openAccessSilva,Marcelo C.Cristovan,Fernando H.Ruggiero,ReinaldoCruz,W. O.Marletta,A.eng2006-07-06T00:00:00Zoai:scielo:S0103-97332006000300071Revistahttp://www.sbfisica.org.br/v1/home/index.php/pt/ONGhttps://old.scielo.br/oai/scielo-oai.phpsbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br1678-44480103-9733opendoar:2006-07-06T00:00Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)false
dc.title.none.fl_str_mv Near-infrared emission of Nd-PSS films
title Near-infrared emission of Nd-PSS films
spellingShingle Near-infrared emission of Nd-PSS films
Silva,Marcelo C.
Polystyrene sulphonate
Neodymium ions and synthesis route
title_short Near-infrared emission of Nd-PSS films
title_full Near-infrared emission of Nd-PSS films
title_fullStr Near-infrared emission of Nd-PSS films
title_full_unstemmed Near-infrared emission of Nd-PSS films
title_sort Near-infrared emission of Nd-PSS films
author Silva,Marcelo C.
author_facet Silva,Marcelo C.
Cristovan,Fernando H.
Ruggiero,Reinaldo
Cruz,W. O.
Marletta,A.
author_role author
author2 Cristovan,Fernando H.
Ruggiero,Reinaldo
Cruz,W. O.
Marletta,A.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Silva,Marcelo C.
Cristovan,Fernando H.
Ruggiero,Reinaldo
Cruz,W. O.
Marletta,A.
dc.subject.por.fl_str_mv Polystyrene sulphonate
Neodymium ions and synthesis route
topic Polystyrene sulphonate
Neodymium ions and synthesis route
description We report a study of a new chemical synthetic route of polystyrene sulphonate (PSS) films doped with neodymium ion (Nd+3) from a neodymium nitrate solution. The UV-Vis-NIR spectrum presents an intense characteristic electronic transition at 800 nm and the infrared spectrum presents low definition bands as a result of Nd3+ coordination with PSS molecule. Additionally, the spectrum of Nd-PSS film presents the same line shape profile of Nd3+ salt in aqueous solution. Selective luminescence spectroscopy measures shows that the incorporation of neodymium ion introduces a red shift bands and a better line shape definition in UV luminescence compared to PSS film, decreasing the interaction between PSS aromatic groups. The near-infrared emission was observed in the large spectrum region from 600 to 800 nm; it is associated with the Nd3+ complex of PSS monomer.
publishDate 2006
dc.date.none.fl_str_mv 2006-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332006000300071
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332006000300071
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-97332006000300071
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Física
publisher.none.fl_str_mv Sociedade Brasileira de Física
dc.source.none.fl_str_mv Brazilian Journal of Physics v.36 n.2a 2006
reponame:Brazilian Journal of Physics
instname:Sociedade Brasileira de Física (SBF)
instacron:SBF
instname_str Sociedade Brasileira de Física (SBF)
instacron_str SBF
institution SBF
reponame_str Brazilian Journal of Physics
collection Brazilian Journal of Physics
repository.name.fl_str_mv Brazilian Journal of Physics - Sociedade Brasileira de Física (SBF)
repository.mail.fl_str_mv sbfisica@sbfisica.org.br||sbfisica@sbfisica.org.br
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