A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]

Detalhes bibliográficos
Autor(a) principal: Neves,Ademir
Data de Publicação: 1998
Outros Autores: Romanowski,Stela Maris de Moraes, Vencato,Ivo, Mangrich,Antonio Salvio
Tipo de documento: Relatório
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500003
Resumo: The synthesis, X-ray crystal structure, and spectroscopic properties of the new coordination compound [OV IV(HBIMETEN)], [H3BIMETEN = N , N' - (2-hydroxybenzil) -N-(1-methylimidazole-2-yl-methyl)-N'-hydroxyethil-ethylenediamine] are reported as V IV O2+ complex example containing phenolate and 1-methylimidazole coordinated simultaneously to the metal center. The EPR and UV-Vis properties of the title compound are similar to those observed in [OV IV(tf)].
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spelling A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]VO2+ complexcrystal structureEPRvanadium transferrinThe synthesis, X-ray crystal structure, and spectroscopic properties of the new coordination compound [OV IV(HBIMETEN)], [H3BIMETEN = N , N' - (2-hydroxybenzil) -N-(1-methylimidazole-2-yl-methyl)-N'-hydroxyethil-ethylenediamine] are reported as V IV O2+ complex example containing phenolate and 1-methylimidazole coordinated simultaneously to the metal center. The EPR and UV-Vis properties of the title compound are similar to those observed in [OV IV(tf)].Sociedade Brasileira de Química1998-09-01info:eu-repo/semantics/reportinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500003Journal of the Brazilian Chemical Society v.9 n.5 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000500003info:eu-repo/semantics/openAccessNeves,AdemirRomanowski,Stela Maris de MoraesVencato,IvoMangrich,Antonio Salvioeng2002-11-06T00:00:00Zoai:scielo:S0103-50531998000500003Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
title A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
spellingShingle A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
Neves,Ademir
VO2+ complex
crystal structure
EPR
vanadium transferrin
title_short A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
title_full A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
title_fullStr A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
title_full_unstemmed A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
title_sort A New Biomimetic Model for the Active Site of Oxovanadium(IV)-Transferrins – [OV IV(tf)]
author Neves,Ademir
author_facet Neves,Ademir
Romanowski,Stela Maris de Moraes
Vencato,Ivo
Mangrich,Antonio Salvio
author_role author
author2 Romanowski,Stela Maris de Moraes
Vencato,Ivo
Mangrich,Antonio Salvio
author2_role author
author
author
dc.contributor.author.fl_str_mv Neves,Ademir
Romanowski,Stela Maris de Moraes
Vencato,Ivo
Mangrich,Antonio Salvio
dc.subject.por.fl_str_mv VO2+ complex
crystal structure
EPR
vanadium transferrin
topic VO2+ complex
crystal structure
EPR
vanadium transferrin
description The synthesis, X-ray crystal structure, and spectroscopic properties of the new coordination compound [OV IV(HBIMETEN)], [H3BIMETEN = N , N' - (2-hydroxybenzil) -N-(1-methylimidazole-2-yl-methyl)-N'-hydroxyethil-ethylenediamine] are reported as V IV O2+ complex example containing phenolate and 1-methylimidazole coordinated simultaneously to the metal center. The EPR and UV-Vis properties of the title compound are similar to those observed in [OV IV(tf)].
publishDate 1998
dc.date.none.fl_str_mv 1998-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/report
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format report
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531998000500003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.9 n.5 1998
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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