Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000300434 |
Resumo: | This study evaluates the interaction of volatile corrosion inhibitors (VCIs) of the amino group with the zinc or zinc oxide surface by means of computational calculations using density functional theory (DFT) and comparing with experimental methods such as electrochemical impedance spectroscopy (EIS) and wet chamber tests. The application of these methods allowed indicating the most promising VCI and understanding its mechanism of action. Thus, after the vaporization of VCI molecules, they condense on the surface and form a protective film or a film with oxidizing characteristic, thereby preventing the corrosive action of the chemical species present in the environment. |
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Journal of the Brazilian Chemical Society (Online) |
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Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrodevolatile corrosion inhibitorsdensity functional theoryelectrochemical impedance spectroscopywet test chamberThis study evaluates the interaction of volatile corrosion inhibitors (VCIs) of the amino group with the zinc or zinc oxide surface by means of computational calculations using density functional theory (DFT) and comparing with experimental methods such as electrochemical impedance spectroscopy (EIS) and wet chamber tests. The application of these methods allowed indicating the most promising VCI and understanding its mechanism of action. Thus, after the vaporization of VCI molecules, they condense on the surface and form a protective film or a film with oxidizing characteristic, thereby preventing the corrosive action of the chemical species present in the environment.Sociedade Brasileira de Química2015-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000300434Journal of the Brazilian Chemical Society v.26 n.3 2015reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20140296info:eu-repo/semantics/openAccessTeixeira,Deiver A.Valente Jr.,Marco A. G.Benedetti,Assis V.Feliciano,Gustavo T.Silva,Sebastião C. daFugivara,Cecílio S.eng2017-11-09T00:00:00Zoai:scielo:S0103-50532015000300434Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-11-09T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
title |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
spellingShingle |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode Teixeira,Deiver A. volatile corrosion inhibitors density functional theory electrochemical impedance spectroscopy wet test chamber |
title_short |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
title_full |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
title_fullStr |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
title_full_unstemmed |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
title_sort |
Experimental and Theoretical Studies of Volatile Corrosion Inhibitors Adsorption on Zinc Electrode |
author |
Teixeira,Deiver A. |
author_facet |
Teixeira,Deiver A. Valente Jr.,Marco A. G. Benedetti,Assis V. Feliciano,Gustavo T. Silva,Sebastião C. da Fugivara,Cecílio S. |
author_role |
author |
author2 |
Valente Jr.,Marco A. G. Benedetti,Assis V. Feliciano,Gustavo T. Silva,Sebastião C. da Fugivara,Cecílio S. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Teixeira,Deiver A. Valente Jr.,Marco A. G. Benedetti,Assis V. Feliciano,Gustavo T. Silva,Sebastião C. da Fugivara,Cecílio S. |
dc.subject.por.fl_str_mv |
volatile corrosion inhibitors density functional theory electrochemical impedance spectroscopy wet test chamber |
topic |
volatile corrosion inhibitors density functional theory electrochemical impedance spectroscopy wet test chamber |
description |
This study evaluates the interaction of volatile corrosion inhibitors (VCIs) of the amino group with the zinc or zinc oxide surface by means of computational calculations using density functional theory (DFT) and comparing with experimental methods such as electrochemical impedance spectroscopy (EIS) and wet chamber tests. The application of these methods allowed indicating the most promising VCI and understanding its mechanism of action. Thus, after the vaporization of VCI molecules, they condense on the surface and form a protective film or a film with oxidizing characteristic, thereby preventing the corrosive action of the chemical species present in the environment. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-03-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000300434 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000300434 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20140296 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.26 n.3 2015 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318176983318528 |