Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces
Autor(a) principal: | |
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Data de Publicação: | 1998 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500011 |
Resumo: | Fe(III) was supported on Sb(V) oxide grafted on the silica gel surface and directly on the silica gel surface using ion-exchange and impregnation processes producing Fe/Sb/SiO2 and Fe/SiO2, respectively. The catalytic conversion of ethanol to acetaldehyde was much more efficient using Fe/Sb/SiO2 than Fe/SiO2 as catalyst. This higher efficiency of the former catalyst takes into account two aspects: a) the new phase FeSbO4 formed when Fe/Sb/SiO2 is heat treated and, b) it is higher dispersion on the matrix. |
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Journal of the Brazilian Chemical Society (Online) |
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Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfacesmodified silicasilica supported iron antimonyphase ethanol oxidationFe(III) was supported on Sb(V) oxide grafted on the silica gel surface and directly on the silica gel surface using ion-exchange and impregnation processes producing Fe/Sb/SiO2 and Fe/SiO2, respectively. The catalytic conversion of ethanol to acetaldehyde was much more efficient using Fe/Sb/SiO2 than Fe/SiO2 as catalyst. This higher efficiency of the former catalyst takes into account two aspects: a) the new phase FeSbO4 formed when Fe/Sb/SiO2 is heat treated and, b) it is higher dispersion on the matrix.Sociedade Brasileira de Química1998-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500011Journal of the Brazilian Chemical Society v.9 n.5 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000500011info:eu-repo/semantics/openAccessBenvenutti,Edilson V.Gushikem,Yoshitakaeng2002-11-06T00:00:00Zoai:scielo:S0103-50531998000500011Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
title |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
spellingShingle |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces Benvenutti,Edilson V. modified silica silica supported iron antimony phase ethanol oxidation |
title_short |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
title_full |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
title_fullStr |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
title_full_unstemmed |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
title_sort |
Comparative Study of Catalytic Oxidation of Ethanol to Acetaldehyde Using Fe(III) Dispersed on Sb2O5 Grafted on SiO2 and on Untreated SiO2 Surfaces |
author |
Benvenutti,Edilson V. |
author_facet |
Benvenutti,Edilson V. Gushikem,Yoshitaka |
author_role |
author |
author2 |
Gushikem,Yoshitaka |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Benvenutti,Edilson V. Gushikem,Yoshitaka |
dc.subject.por.fl_str_mv |
modified silica silica supported iron antimony phase ethanol oxidation |
topic |
modified silica silica supported iron antimony phase ethanol oxidation |
description |
Fe(III) was supported on Sb(V) oxide grafted on the silica gel surface and directly on the silica gel surface using ion-exchange and impregnation processes producing Fe/Sb/SiO2 and Fe/SiO2, respectively. The catalytic conversion of ethanol to acetaldehyde was much more efficient using Fe/Sb/SiO2 than Fe/SiO2 as catalyst. This higher efficiency of the former catalyst takes into account two aspects: a) the new phase FeSbO4 formed when Fe/Sb/SiO2 is heat treated and, b) it is higher dispersion on the matrix. |
publishDate |
1998 |
dc.date.none.fl_str_mv |
1998-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500011 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000500011 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50531998000500011 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.9 n.5 1998 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318163435716608 |