Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate

Detalhes bibliográficos
Autor(a) principal: Rehman,Wajid
Data de Publicação: 2005
Outros Autores: Baloch,Musa Kaleem, Badshah,Amin
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500023
Resumo: A series of di and triorganotin(IV) complexes of monomethyl glutarate have been synthesized and characterized through ¹H 13C 119Sn NMR, FT-IR and 119Sn Mössbauer spectroscopy. On the basis of these techniques, it is proposed that the ligand molecule is bound to the tin atom through the carbonyl oxygen. The data reveal that diorganotin(IV) complexes exhibit hexa-coordination with octahedral geometry, while triorganotin(IV) complexes have penta-coordination with trigonal bipyramidal geometry. Biological evaluation against various microorganisms indicate that diorganotin(IV) complexes are less active than the triorganotin(IV) complexes.
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spelling Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarateorganotin(IV)monomethyl glutaratebiological activityA series of di and triorganotin(IV) complexes of monomethyl glutarate have been synthesized and characterized through ¹H 13C 119Sn NMR, FT-IR and 119Sn Mössbauer spectroscopy. On the basis of these techniques, it is proposed that the ligand molecule is bound to the tin atom through the carbonyl oxygen. The data reveal that diorganotin(IV) complexes exhibit hexa-coordination with octahedral geometry, while triorganotin(IV) complexes have penta-coordination with trigonal bipyramidal geometry. Biological evaluation against various microorganisms indicate that diorganotin(IV) complexes are less active than the triorganotin(IV) complexes.Sociedade Brasileira de Química2005-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500023Journal of the Brazilian Chemical Society v.16 n.4 2005reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532005000500023info:eu-repo/semantics/openAccessRehman,WajidBaloch,Musa KaleemBadshah,Amineng2005-08-25T00:00:00Zoai:scielo:S0103-50532005000500023Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2005-08-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
title Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
spellingShingle Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
Rehman,Wajid
organotin(IV)
monomethyl glutarate
biological activity
title_short Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
title_full Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
title_fullStr Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
title_full_unstemmed Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
title_sort Comparative study of structure: activity relationship of di and triorganotin (IV) complexes of monomethyl glutarate
author Rehman,Wajid
author_facet Rehman,Wajid
Baloch,Musa Kaleem
Badshah,Amin
author_role author
author2 Baloch,Musa Kaleem
Badshah,Amin
author2_role author
author
dc.contributor.author.fl_str_mv Rehman,Wajid
Baloch,Musa Kaleem
Badshah,Amin
dc.subject.por.fl_str_mv organotin(IV)
monomethyl glutarate
biological activity
topic organotin(IV)
monomethyl glutarate
biological activity
description A series of di and triorganotin(IV) complexes of monomethyl glutarate have been synthesized and characterized through ¹H 13C 119Sn NMR, FT-IR and 119Sn Mössbauer spectroscopy. On the basis of these techniques, it is proposed that the ligand molecule is bound to the tin atom through the carbonyl oxygen. The data reveal that diorganotin(IV) complexes exhibit hexa-coordination with octahedral geometry, while triorganotin(IV) complexes have penta-coordination with trigonal bipyramidal geometry. Biological evaluation against various microorganisms indicate that diorganotin(IV) complexes are less active than the triorganotin(IV) complexes.
publishDate 2005
dc.date.none.fl_str_mv 2005-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500023
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000500023
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532005000500023
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.16 n.4 2005
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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