Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction

Detalhes bibliográficos
Autor(a) principal: Gamenara,Daniela
Data de Publicação: 2001
Outros Autores: Días,Eduardo, Tancred,Néstor, Heinzen,Horacio, Moyna,Patrick, Forbes,Eric J.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008
Resumo: An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.
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spelling Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reactionHetero Diels-Aldertetra-methyl purpurogallinnitrosobenzeneAn efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.Sociedade Brasileira de Química2001-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008Journal of the Brazilian Chemical Society v.12 n.4 2001reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532001000400008info:eu-repo/semantics/openAccessGamenara,DanielaDías,EduardoTancred,NéstorHeinzen,HoracioMoyna,PatrickForbes,Eric J.eng2001-10-17T00:00:00Zoai:scielo:S0103-50532001000400008Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2001-10-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
title Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
spellingShingle Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
Gamenara,Daniela
Hetero Diels-Alder
tetra-methyl purpurogallin
nitrosobenzene
title_short Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
title_full Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
title_fullStr Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
title_full_unstemmed Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
title_sort Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
author Gamenara,Daniela
author_facet Gamenara,Daniela
Días,Eduardo
Tancred,Néstor
Heinzen,Horacio
Moyna,Patrick
Forbes,Eric J.
author_role author
author2 Días,Eduardo
Tancred,Néstor
Heinzen,Horacio
Moyna,Patrick
Forbes,Eric J.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Gamenara,Daniela
Días,Eduardo
Tancred,Néstor
Heinzen,Horacio
Moyna,Patrick
Forbes,Eric J.
dc.subject.por.fl_str_mv Hetero Diels-Alder
tetra-methyl purpurogallin
nitrosobenzene
topic Hetero Diels-Alder
tetra-methyl purpurogallin
nitrosobenzene
description An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.
publishDate 2001
dc.date.none.fl_str_mv 2001-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532001000400008
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.12 n.4 2001
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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