Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization

Detalhes bibliográficos
Autor(a) principal: Sairre,Mirela Inês de
Data de Publicação: 2008
Outros Autores: Araújo,Luiz Felipe N., Silva,Rosangela da, Donate,Paulo Marcos, Silvério,Cristina A., Okano,Laura T.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000100027
Resumo: Methyl 3-(3-hydroxyphenoxy)acrylate (2), a new and important starting material for several reactions and a potential precursor of the natural product 3-(3-hydroxyphenoxy)-2-propenal (1), was synthesized from resorcinol and methyl propiolate. The trans configuration of the double bond present in 2 was confirmed through a photoisomerization reaction.
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spelling Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerizationmethyl 3-(3-hydroxyphenoxy)acrylate3-(3-hydroxyphenoxy)-2-propenal, photoisomerization reactionsynthesisMethyl 3-(3-hydroxyphenoxy)acrylate (2), a new and important starting material for several reactions and a potential precursor of the natural product 3-(3-hydroxyphenoxy)-2-propenal (1), was synthesized from resorcinol and methyl propiolate. The trans configuration of the double bond present in 2 was confirmed through a photoisomerization reaction.Sociedade Brasileira de Química2008-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000100027Journal of the Brazilian Chemical Society v.19 n.1 2008reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532008000100027info:eu-repo/semantics/openAccessSairre,Mirela Inês deAraújo,Luiz Felipe N.Silva,Rosangela daDonate,Paulo MarcosSilvério,Cristina A.Okano,Laura T.eng2008-03-10T00:00:00Zoai:scielo:S0103-50532008000100027Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-03-10T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
title Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
spellingShingle Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
Sairre,Mirela Inês de
methyl 3-(3-hydroxyphenoxy)acrylate
3-(3-hydroxyphenoxy)-2-propenal, photoisomerization reaction
synthesis
title_short Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
title_full Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
title_fullStr Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
title_full_unstemmed Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
title_sort Synthesis and stereochemical assignment of methyl 3-(3-hydroxyphenoxy) acrylate via cis-trans photoisomerization
author Sairre,Mirela Inês de
author_facet Sairre,Mirela Inês de
Araújo,Luiz Felipe N.
Silva,Rosangela da
Donate,Paulo Marcos
Silvério,Cristina A.
Okano,Laura T.
author_role author
author2 Araújo,Luiz Felipe N.
Silva,Rosangela da
Donate,Paulo Marcos
Silvério,Cristina A.
Okano,Laura T.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Sairre,Mirela Inês de
Araújo,Luiz Felipe N.
Silva,Rosangela da
Donate,Paulo Marcos
Silvério,Cristina A.
Okano,Laura T.
dc.subject.por.fl_str_mv methyl 3-(3-hydroxyphenoxy)acrylate
3-(3-hydroxyphenoxy)-2-propenal, photoisomerization reaction
synthesis
topic methyl 3-(3-hydroxyphenoxy)acrylate
3-(3-hydroxyphenoxy)-2-propenal, photoisomerization reaction
synthesis
description Methyl 3-(3-hydroxyphenoxy)acrylate (2), a new and important starting material for several reactions and a potential precursor of the natural product 3-(3-hydroxyphenoxy)-2-propenal (1), was synthesized from resorcinol and methyl propiolate. The trans configuration of the double bond present in 2 was confirmed through a photoisomerization reaction.
publishDate 2008
dc.date.none.fl_str_mv 2008-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000100027
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000100027
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532008000100027
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.19 n.1 2008
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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