Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source

Detalhes bibliográficos
Autor(a) principal: Li,Zheng
Data de Publicação: 2013
Outros Autores: Li,Rongzhi, Zheng,Huanhuan, Wen,Fei, Li,Hongbo, Yin,Junjun, Yang,Jingya
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013001100005
Resumo: An efficient and eco-friendly method for hydrocyanation of sulfonylimines via one-pot two-step procedure using potassium hexacyanoferrate(II) as a cyanide source, benzoyl chloride as a promoter, and potassium carbonate as a base is described. This protocol has the features of using nontoxic, nonvolatile and inexpensive cyanide source, high yield, and simple work-up procedure.
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spelling Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide sourcesulfonyliminehydrocyanationpotassium hexacyanoferrate(II)Strecker-type reactiongreen chemistryAn efficient and eco-friendly method for hydrocyanation of sulfonylimines via one-pot two-step procedure using potassium hexacyanoferrate(II) as a cyanide source, benzoyl chloride as a promoter, and potassium carbonate as a base is described. This protocol has the features of using nontoxic, nonvolatile and inexpensive cyanide source, high yield, and simple work-up procedure.Sociedade Brasileira de Química2013-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013001100005Journal of the Brazilian Chemical Society v.24 n.11 2013reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20130218info:eu-repo/semantics/openAccessLi,ZhengLi,RongzhiZheng,HuanhuanWen,FeiLi,HongboYin,JunjunYang,Jingyaeng2013-11-19T00:00:00Zoai:scielo:S0103-50532013001100005Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2013-11-19T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
title Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
spellingShingle Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
Li,Zheng
sulfonylimine
hydrocyanation
potassium hexacyanoferrate(II)
Strecker-type reaction
green chemistry
title_short Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
title_full Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
title_fullStr Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
title_full_unstemmed Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
title_sort Hydrocyanation of sulfonylimines using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
author Li,Zheng
author_facet Li,Zheng
Li,Rongzhi
Zheng,Huanhuan
Wen,Fei
Li,Hongbo
Yin,Junjun
Yang,Jingya
author_role author
author2 Li,Rongzhi
Zheng,Huanhuan
Wen,Fei
Li,Hongbo
Yin,Junjun
Yang,Jingya
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Li,Zheng
Li,Rongzhi
Zheng,Huanhuan
Wen,Fei
Li,Hongbo
Yin,Junjun
Yang,Jingya
dc.subject.por.fl_str_mv sulfonylimine
hydrocyanation
potassium hexacyanoferrate(II)
Strecker-type reaction
green chemistry
topic sulfonylimine
hydrocyanation
potassium hexacyanoferrate(II)
Strecker-type reaction
green chemistry
description An efficient and eco-friendly method for hydrocyanation of sulfonylimines via one-pot two-step procedure using potassium hexacyanoferrate(II) as a cyanide source, benzoyl chloride as a promoter, and potassium carbonate as a base is described. This protocol has the features of using nontoxic, nonvolatile and inexpensive cyanide source, high yield, and simple work-up procedure.
publishDate 2013
dc.date.none.fl_str_mv 2013-11-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013001100005
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013001100005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20130218
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.24 n.11 2013
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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