A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis

Detalhes bibliográficos
Autor(a) principal: Catrinck,Tereza C. P. G.
Data de Publicação: 2014
Outros Autores: Dias,Amanda, Aguiar,Maria Clara S., Silvério,Flaviano O., Fidêncio,Paulo H., Pinho,Gevany P.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000700007
Resumo: This work presents the confirmation and optimization of the method for derivatization of glyphosate and aminomethylphosphonic acid (AMPA) using 9-fluorenylmethyl chloroformate (FMOC-Cl) evaluating the parameters: concentration of borate buffer and FMOC-Cl, homogenization time and of reaction, wavelength and solvent washing. The reaction was successfully promoted and the method is simple and easy to perform because it uses five minutes of homogenization and allows ultraviolet analysis immediately after the end of the reaction.
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spelling A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysisFMOC-ClglyphosatederivatizationThis work presents the confirmation and optimization of the method for derivatization of glyphosate and aminomethylphosphonic acid (AMPA) using 9-fluorenylmethyl chloroformate (FMOC-Cl) evaluating the parameters: concentration of borate buffer and FMOC-Cl, homogenization time and of reaction, wavelength and solvent washing. The reaction was successfully promoted and the method is simple and easy to perform because it uses five minutes of homogenization and allows ultraviolet analysis immediately after the end of the reaction.Sociedade Brasileira de Química2014-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000700007Journal of the Brazilian Chemical Society v.25 n.7 2014reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20140096info:eu-repo/semantics/openAccessCatrinck,Tereza C. P. G.Dias,AmandaAguiar,Maria Clara S.Silvério,Flaviano O.Fidêncio,Paulo H.Pinho,Gevany P.eng2014-07-17T00:00:00Zoai:scielo:S0103-50532014000700007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2014-07-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
title A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
spellingShingle A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
Catrinck,Tereza C. P. G.
FMOC-Cl
glyphosate
derivatization
title_short A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
title_full A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
title_fullStr A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
title_full_unstemmed A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
title_sort A simple and efficient method for derivatization of glyphosate and AMPA using 9-fluorenylmethyl chloroformate and spectrophotometric analysis
author Catrinck,Tereza C. P. G.
author_facet Catrinck,Tereza C. P. G.
Dias,Amanda
Aguiar,Maria Clara S.
Silvério,Flaviano O.
Fidêncio,Paulo H.
Pinho,Gevany P.
author_role author
author2 Dias,Amanda
Aguiar,Maria Clara S.
Silvério,Flaviano O.
Fidêncio,Paulo H.
Pinho,Gevany P.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Catrinck,Tereza C. P. G.
Dias,Amanda
Aguiar,Maria Clara S.
Silvério,Flaviano O.
Fidêncio,Paulo H.
Pinho,Gevany P.
dc.subject.por.fl_str_mv FMOC-Cl
glyphosate
derivatization
topic FMOC-Cl
glyphosate
derivatization
description This work presents the confirmation and optimization of the method for derivatization of glyphosate and aminomethylphosphonic acid (AMPA) using 9-fluorenylmethyl chloroformate (FMOC-Cl) evaluating the parameters: concentration of borate buffer and FMOC-Cl, homogenization time and of reaction, wavelength and solvent washing. The reaction was successfully promoted and the method is simple and easy to perform because it uses five minutes of homogenization and allows ultraviolet analysis immediately after the end of the reaction.
publishDate 2014
dc.date.none.fl_str_mv 2014-07-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000700007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000700007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20140096
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.25 n.7 2014
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318176143409152

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