Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN

Detalhes bibliográficos
Autor(a) principal: Silveira,Claudio C.
Data de Publicação: 2007
Outros Autores: Caliari,Vinicius, Vieira,Adriano S., Mendes,Samuel R.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800005
Resumo: Reaction of 1-halo-1-organothio or 1-halo-1-organoseleno alkenes with CuCN in NMP as solvent provides alpha-phenylthio or alpha-phenylseleno acrylonitriles in good yields. The reaction showed a low stereoselectivity and the products were obtained as E/Z mixtures of isomers.
id SBQ-2_479b3cbb7413b76c12c57e6f296412be
oai_identifier_str oai:scielo:S0103-50532007000800005
network_acronym_str SBQ-2
network_name_str Journal of the Brazilian Chemical Society (Online)
repository_id_str
spelling Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCNorganoselenoacrylonitrilesorganothioacrylonitrilesvinylic substitutioncuprous cyanidevinylic chalcogenidesReaction of 1-halo-1-organothio or 1-halo-1-organoseleno alkenes with CuCN in NMP as solvent provides alpha-phenylthio or alpha-phenylseleno acrylonitriles in good yields. The reaction showed a low stereoselectivity and the products were obtained as E/Z mixtures of isomers.Sociedade Brasileira de Química2007-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800005Journal of the Brazilian Chemical Society v.18 n.8 2007reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532007000800005info:eu-repo/semantics/openAccessSilveira,Claudio C.Caliari,ViniciusVieira,Adriano S.Mendes,Samuel R.eng2008-02-12T00:00:00Zoai:scielo:S0103-50532007000800005Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-02-12T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
title Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
spellingShingle Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
Silveira,Claudio C.
organoselenoacrylonitriles
organothioacrylonitriles
vinylic substitution
cuprous cyanide
vinylic chalcogenides
title_short Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
title_full Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
title_fullStr Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
title_full_unstemmed Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
title_sort Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN
author Silveira,Claudio C.
author_facet Silveira,Claudio C.
Caliari,Vinicius
Vieira,Adriano S.
Mendes,Samuel R.
author_role author
author2 Caliari,Vinicius
Vieira,Adriano S.
Mendes,Samuel R.
author2_role author
author
author
dc.contributor.author.fl_str_mv Silveira,Claudio C.
Caliari,Vinicius
Vieira,Adriano S.
Mendes,Samuel R.
dc.subject.por.fl_str_mv organoselenoacrylonitriles
organothioacrylonitriles
vinylic substitution
cuprous cyanide
vinylic chalcogenides
topic organoselenoacrylonitriles
organothioacrylonitriles
vinylic substitution
cuprous cyanide
vinylic chalcogenides
description Reaction of 1-halo-1-organothio or 1-halo-1-organoseleno alkenes with CuCN in NMP as solvent provides alpha-phenylthio or alpha-phenylseleno acrylonitriles in good yields. The reaction showed a low stereoselectivity and the products were obtained as E/Z mixtures of isomers.
publishDate 2007
dc.date.none.fl_str_mv 2007-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800005
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532007000800005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532007000800005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.18 n.8 2007
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318168541233152

Registros relacionados