Electrochemical energy conversion: methanol fuel cell as example
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400003 |
Resumo: | Thermodynamic and kinetic limitations of the electrochemical energy conversion are presented for the case of a methanol/oxygen fuel cell. The detection of intermediates and products is demonstrated using insitu FTIR spectroscopy and online mass spectrometry. The bifunctional catalysis of methanol oxydation by PtRu model surfaces is explained. The formation of HCOOH and HCHO via parallel reaction pathways is discussed. An example of DMFC system technology is presented. |
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Journal of the Brazilian Chemical Society (Online) |
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Electrochemical energy conversion: methanol fuel cell as exampleenergy conversionelectrocatalysisfuel cell systemmethanol oxidationreaction pathwaysThermodynamic and kinetic limitations of the electrochemical energy conversion are presented for the case of a methanol/oxygen fuel cell. The detection of intermediates and products is demonstrated using insitu FTIR spectroscopy and online mass spectrometry. The bifunctional catalysis of methanol oxydation by PtRu model surfaces is explained. The formation of HCOOH and HCHO via parallel reaction pathways is discussed. An example of DMFC system technology is presented.Sociedade Brasileira de Química2003-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400003Journal of the Brazilian Chemical Society v.14 n.4 2003reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532003000400003info:eu-repo/semantics/openAccessVielstich,Wolfeng2003-09-15T00:00:00Zoai:scielo:S0103-50532003000400003Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2003-09-15T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Electrochemical energy conversion: methanol fuel cell as example |
title |
Electrochemical energy conversion: methanol fuel cell as example |
spellingShingle |
Electrochemical energy conversion: methanol fuel cell as example Vielstich,Wolf energy conversion electrocatalysis fuel cell system methanol oxidation reaction pathways |
title_short |
Electrochemical energy conversion: methanol fuel cell as example |
title_full |
Electrochemical energy conversion: methanol fuel cell as example |
title_fullStr |
Electrochemical energy conversion: methanol fuel cell as example |
title_full_unstemmed |
Electrochemical energy conversion: methanol fuel cell as example |
title_sort |
Electrochemical energy conversion: methanol fuel cell as example |
author |
Vielstich,Wolf |
author_facet |
Vielstich,Wolf |
author_role |
author |
dc.contributor.author.fl_str_mv |
Vielstich,Wolf |
dc.subject.por.fl_str_mv |
energy conversion electrocatalysis fuel cell system methanol oxidation reaction pathways |
topic |
energy conversion electrocatalysis fuel cell system methanol oxidation reaction pathways |
description |
Thermodynamic and kinetic limitations of the electrochemical energy conversion are presented for the case of a methanol/oxygen fuel cell. The detection of intermediates and products is demonstrated using insitu FTIR spectroscopy and online mass spectrometry. The bifunctional catalysis of methanol oxydation by PtRu model surfaces is explained. The formation of HCOOH and HCHO via parallel reaction pathways is discussed. An example of DMFC system technology is presented. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400003 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400003 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532003000400003 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.14 n.4 2003 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318165323153408 |