A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000701149 |
Resumo: | Soils with high levels of iron and aluminum, thus negatively the phosphorous availability, affecting crop yields. A prior determination of the soil capacity to adsorb phosphate is relevant to attaining good agricultural performance. To this end, a multi-pumping flow system with pulsed fluidization is proposed. The procedure takes into account the amount of remaining phosphorus (P-rem) in the solution after the adsorption step to indirectly estimate the soil retention capacity. A 1.0 mg L-1 P solution is passed through a fluidized bed column with 50 mg of soil (particles < 0.15 mm), where the analyte is adsorbed. P-rem was spectrophotometrically quantified by the molybdenum blue method. The coefficient of variation (n = 20), limits of detection and quantification (99.7% confidence level), and sampling rate were estimated as 1.54%, 17 and 51 µg L-1 P, and 87 h-1, respectively. Only 0.27 mg (NH4)6Mo7O24 and 0.10 mg SnCl2 were consumed per determination, generating 2.4 mL of waste. The results followed a linear relationship [y = 0.9702x + 1.483 (r = 0.9635; n = 20)] with the reference procedure. In comparison to the reference procedure, 100, 40 and 180-fold reductions in the required soil amount, waste generation and analytical time were attained. |
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A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorptionsolenoid micro-pumpsadsorptionkineticsolid-liquid interactionSoils with high levels of iron and aluminum, thus negatively the phosphorous availability, affecting crop yields. A prior determination of the soil capacity to adsorb phosphate is relevant to attaining good agricultural performance. To this end, a multi-pumping flow system with pulsed fluidization is proposed. The procedure takes into account the amount of remaining phosphorus (P-rem) in the solution after the adsorption step to indirectly estimate the soil retention capacity. A 1.0 mg L-1 P solution is passed through a fluidized bed column with 50 mg of soil (particles < 0.15 mm), where the analyte is adsorbed. P-rem was spectrophotometrically quantified by the molybdenum blue method. The coefficient of variation (n = 20), limits of detection and quantification (99.7% confidence level), and sampling rate were estimated as 1.54%, 17 and 51 µg L-1 P, and 87 h-1, respectively. Only 0.27 mg (NH4)6Mo7O24 and 0.10 mg SnCl2 were consumed per determination, generating 2.4 mL of waste. The results followed a linear relationship [y = 0.9702x + 1.483 (r = 0.9635; n = 20)] with the reference procedure. In comparison to the reference procedure, 100, 40 and 180-fold reductions in the required soil amount, waste generation and analytical time were attained.Sociedade Brasileira de Química2017-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000701149Journal of the Brazilian Chemical Society v.28 n.7 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20160273info:eu-repo/semantics/openAccessMachado,Jeane M. C.Melchert,Wanessa R.Zagatto,Elias A. G.Kamogawa,Marcos Y.eng2017-06-23T00:00:00Zoai:scielo:S0103-50532017000701149Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-06-23T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
title |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
spellingShingle |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption Machado,Jeane M. C. solenoid micro-pumps adsorption kinetic solid-liquid interaction |
title_short |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
title_full |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
title_fullStr |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
title_full_unstemmed |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
title_sort |
A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption |
author |
Machado,Jeane M. C. |
author_facet |
Machado,Jeane M. C. Melchert,Wanessa R. Zagatto,Elias A. G. Kamogawa,Marcos Y. |
author_role |
author |
author2 |
Melchert,Wanessa R. Zagatto,Elias A. G. Kamogawa,Marcos Y. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Machado,Jeane M. C. Melchert,Wanessa R. Zagatto,Elias A. G. Kamogawa,Marcos Y. |
dc.subject.por.fl_str_mv |
solenoid micro-pumps adsorption kinetic solid-liquid interaction |
topic |
solenoid micro-pumps adsorption kinetic solid-liquid interaction |
description |
Soils with high levels of iron and aluminum, thus negatively the phosphorous availability, affecting crop yields. A prior determination of the soil capacity to adsorb phosphate is relevant to attaining good agricultural performance. To this end, a multi-pumping flow system with pulsed fluidization is proposed. The procedure takes into account the amount of remaining phosphorus (P-rem) in the solution after the adsorption step to indirectly estimate the soil retention capacity. A 1.0 mg L-1 P solution is passed through a fluidized bed column with 50 mg of soil (particles < 0.15 mm), where the analyte is adsorbed. P-rem was spectrophotometrically quantified by the molybdenum blue method. The coefficient of variation (n = 20), limits of detection and quantification (99.7% confidence level), and sampling rate were estimated as 1.54%, 17 and 51 µg L-1 P, and 87 h-1, respectively. Only 0.27 mg (NH4)6Mo7O24 and 0.10 mg SnCl2 were consumed per determination, generating 2.4 mL of waste. The results followed a linear relationship [y = 0.9702x + 1.483 (r = 0.9635; n = 20)] with the reference procedure. In comparison to the reference procedure, 100, 40 and 180-fold reductions in the required soil amount, waste generation and analytical time were attained. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-07-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000701149 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000701149 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.21577/0103-5053.20160273 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.28 n.7 2017 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318179586932736 |