Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence

Detalhes bibliográficos
Autor(a) principal: Lima,Priscilla S.
Data de Publicação: 2014
Outros Autores: Ferreira,Leonildo A., Freitas,Luiza H., Rheinheimer,Martin W., Sokolovicz,Yuri C. A., Schrekker,Henri S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001202266
Resumo: The sequential ethenolysis, transesterification and hydrogenation of a model unsaturated renewable oil for the preparation of potential biofuels is reported herein. Ethenolysis conversions of up to 70%, using olive oil, were obtained applying a relatively low 2 bar ethylene pressure and toluene as solvent. The ethenolyzed olive oil was quantitatively transesterified with methanol and, subsequently, hydrogenated with molecular hydrogen over Pd/C, affording access to novel biofuel compositions, including different fractions of biogasoline, biokerosene and biodiesel.
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spelling Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequenceorganometallic catalysiscatalysiselectrocatalysis and photocatalysis (properties and mechanisms)green chemistryThe sequential ethenolysis, transesterification and hydrogenation of a model unsaturated renewable oil for the preparation of potential biofuels is reported herein. Ethenolysis conversions of up to 70%, using olive oil, were obtained applying a relatively low 2 bar ethylene pressure and toluene as solvent. The ethenolyzed olive oil was quantitatively transesterified with methanol and, subsequently, hydrogenated with molecular hydrogen over Pd/C, affording access to novel biofuel compositions, including different fractions of biogasoline, biokerosene and biodiesel.Sociedade Brasileira de Química2014-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001202266Journal of the Brazilian Chemical Society v.25 n.12 2014reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20140208info:eu-repo/semantics/openAccessLima,Priscilla S.Ferreira,Leonildo A.Freitas,Luiza H.Rheinheimer,Martin W.Sokolovicz,Yuri C. A.Schrekker,Henri S.eng2015-11-23T00:00:00Zoai:scielo:S0103-50532014001202266Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2015-11-23T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
title Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
spellingShingle Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
Lima,Priscilla S.
organometallic catalysis
catalysis
electrocatalysis and photocatalysis (properties and mechanisms)
green chemistry
title_short Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
title_full Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
title_fullStr Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
title_full_unstemmed Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
title_sort Unsaturated Renewable Oil Transformation into Novel Biofuel Compositions via an Olefin Metathesis-Transesterification-Hydrogenation Sequence
author Lima,Priscilla S.
author_facet Lima,Priscilla S.
Ferreira,Leonildo A.
Freitas,Luiza H.
Rheinheimer,Martin W.
Sokolovicz,Yuri C. A.
Schrekker,Henri S.
author_role author
author2 Ferreira,Leonildo A.
Freitas,Luiza H.
Rheinheimer,Martin W.
Sokolovicz,Yuri C. A.
Schrekker,Henri S.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Lima,Priscilla S.
Ferreira,Leonildo A.
Freitas,Luiza H.
Rheinheimer,Martin W.
Sokolovicz,Yuri C. A.
Schrekker,Henri S.
dc.subject.por.fl_str_mv organometallic catalysis
catalysis
electrocatalysis and photocatalysis (properties and mechanisms)
green chemistry
topic organometallic catalysis
catalysis
electrocatalysis and photocatalysis (properties and mechanisms)
green chemistry
description The sequential ethenolysis, transesterification and hydrogenation of a model unsaturated renewable oil for the preparation of potential biofuels is reported herein. Ethenolysis conversions of up to 70%, using olive oil, were obtained applying a relatively low 2 bar ethylene pressure and toluene as solvent. The ethenolyzed olive oil was quantitatively transesterified with methanol and, subsequently, hydrogenated with molecular hydrogen over Pd/C, affording access to novel biofuel compositions, including different fractions of biogasoline, biokerosene and biodiesel.
publishDate 2014
dc.date.none.fl_str_mv 2014-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001202266
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001202266
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20140208
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.25 n.12 2014
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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