Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene

Detalhes bibliográficos
Autor(a) principal: Graúdo,José Eugênio J. C.
Data de Publicação: 2000
Outros Autores: Filgueiras,Carlos A. L., Marques-Netto,Antonio, Batista,Alzir A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300006
Resumo: A series of six ferrocene derivatives containing a semicarbazone or thiosemicarbazone side chain was investigated by cyclic voltammetry and positron annihilation lifetime measurements. Both the redox and the electron capture processes took place on the Fe atom. Correlations between the two methods were proposed, taking into account the substituents on the side chain of the compounds, their redox potentials and the probabilities of o-positronium (o-Ps).formation.
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spelling Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocenesemicarbazonethiosemicarbazoneferrocenecyclic voltammetrypositronium formationA series of six ferrocene derivatives containing a semicarbazone or thiosemicarbazone side chain was investigated by cyclic voltammetry and positron annihilation lifetime measurements. Both the redox and the electron capture processes took place on the Fe atom. Correlations between the two methods were proposed, taking into account the substituents on the side chain of the compounds, their redox potentials and the probabilities of o-positronium (o-Ps).formation.Sociedade Brasileira de Química2000-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300006Journal of the Brazilian Chemical Society v.11 n.3 2000reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532000000300006info:eu-repo/semantics/openAccessGraúdo,José Eugênio J. C.Filgueiras,Carlos A. L.Marques-Netto,AntonioBatista,Alzir A.eng2000-11-06T00:00:00Zoai:scielo:S0103-50532000000300006Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2000-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
title Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
spellingShingle Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
Graúdo,José Eugênio J. C.
semicarbazone
thiosemicarbazone
ferrocene
cyclic voltammetry
positronium formation
title_short Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
title_full Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
title_fullStr Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
title_full_unstemmed Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
title_sort Electrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocene
author Graúdo,José Eugênio J. C.
author_facet Graúdo,José Eugênio J. C.
Filgueiras,Carlos A. L.
Marques-Netto,Antonio
Batista,Alzir A.
author_role author
author2 Filgueiras,Carlos A. L.
Marques-Netto,Antonio
Batista,Alzir A.
author2_role author
author
author
dc.contributor.author.fl_str_mv Graúdo,José Eugênio J. C.
Filgueiras,Carlos A. L.
Marques-Netto,Antonio
Batista,Alzir A.
dc.subject.por.fl_str_mv semicarbazone
thiosemicarbazone
ferrocene
cyclic voltammetry
positronium formation
topic semicarbazone
thiosemicarbazone
ferrocene
cyclic voltammetry
positronium formation
description A series of six ferrocene derivatives containing a semicarbazone or thiosemicarbazone side chain was investigated by cyclic voltammetry and positron annihilation lifetime measurements. Both the redox and the electron capture processes took place on the Fe atom. Correlations between the two methods were proposed, taking into account the substituents on the side chain of the compounds, their redox potentials and the probabilities of o-positronium (o-Ps).formation.
publishDate 2000
dc.date.none.fl_str_mv 2000-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300006
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300006
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532000000300006
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.11 n.3 2000
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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