SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products

Detalhes bibliográficos
Autor(a) principal: Coelho,Adriana R. A.
Data de Publicação: 2009
Outros Autores: Oliveira,Ione M. F., Cardeal,Zenilda L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000300018
Resumo: This work presents a method development for analyzing electrocatalytic hydrogenation products of cyclohexanone with the simple, fast and accurate SPME, coupled with classic gas chromatographic methods using flame ionization detection. Preliminar method optimization was made using chemometric tools. LOD and LOQ obtained were 0.50% conversion or 0.78 mg L-1 and 1.20% conversion or 1.86 mg L-1 respectively. The analytical curve obtained displays good linearity (R² = 0.9936).
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spelling SPME-GC-FID method development for analyzing cyclohexanone hydrogenation productsSPMEHECcyclohexanonechemometricsThis work presents a method development for analyzing electrocatalytic hydrogenation products of cyclohexanone with the simple, fast and accurate SPME, coupled with classic gas chromatographic methods using flame ionization detection. Preliminar method optimization was made using chemometric tools. LOD and LOQ obtained were 0.50% conversion or 0.78 mg L-1 and 1.20% conversion or 1.86 mg L-1 respectively. The analytical curve obtained displays good linearity (R² = 0.9936).Sociedade Brasileira de Química2009-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000300018Journal of the Brazilian Chemical Society v.20 n.3 2009reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532009000300018info:eu-repo/semantics/openAccessCoelho,Adriana R. A.Oliveira,Ione M. F.Cardeal,Zenilda L.eng2009-05-25T00:00:00Zoai:scielo:S0103-50532009000300018Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2009-05-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
title SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
spellingShingle SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
Coelho,Adriana R. A.
SPME
HEC
cyclohexanone
chemometrics
title_short SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
title_full SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
title_fullStr SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
title_full_unstemmed SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
title_sort SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products
author Coelho,Adriana R. A.
author_facet Coelho,Adriana R. A.
Oliveira,Ione M. F.
Cardeal,Zenilda L.
author_role author
author2 Oliveira,Ione M. F.
Cardeal,Zenilda L.
author2_role author
author
dc.contributor.author.fl_str_mv Coelho,Adriana R. A.
Oliveira,Ione M. F.
Cardeal,Zenilda L.
dc.subject.por.fl_str_mv SPME
HEC
cyclohexanone
chemometrics
topic SPME
HEC
cyclohexanone
chemometrics
description This work presents a method development for analyzing electrocatalytic hydrogenation products of cyclohexanone with the simple, fast and accurate SPME, coupled with classic gas chromatographic methods using flame ionization detection. Preliminar method optimization was made using chemometric tools. LOD and LOQ obtained were 0.50% conversion or 0.78 mg L-1 and 1.20% conversion or 1.86 mg L-1 respectively. The analytical curve obtained displays good linearity (R² = 0.9936).
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000300018
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000300018
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532009000300018
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.20 n.3 2009
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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