Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools

Detalhes bibliográficos
Autor(a) principal: Buiatte,José Eduardo
Data de Publicação: 2016
Outros Autores: Guimarães,Eloíza, Mitsutake,Hery, Gontijo,Lucas Caixeta, Santos,Douglas Queiroz, Borges Neto,Waldomiro
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100084
Resumo: This paper presents methodologies for monitoring the quality of methyl cotton biodiesel in biodiesel/diesel blends using mid-infrared spectroscopy (MIR) and chemometrics tools. The first method relates to the construction of multivariate control charts with the aim of qualitatively monitoring the samples according to the Brazilian specification for biodiesel in the biodiesel/diesel blends (7.00 ± 0.5% v/v of biodiesel). The second concerns the construction of partial least squares (PLS) to determine the content of the biodiesel in the biodiesel/diesel blend. The PLS model was validated from multivariate figures of merit according to the guidelines of ASTM E1655-05 and IUPAC. The results from both methods were satisfactory for both qualitative and quantitative monitoring. Therefore, the proposed methodologies for monitoring the quality of biodiesel in biodiesel/diesel blends are fast, practical, economical and efficient and can be used by industries and service stations.
id SBQ-2_5ff5d7ca22194db81331eb48d9048a22
oai_identifier_str oai:scielo:S0103-50532016000100084
network_acronym_str SBQ-2
network_name_str Journal of the Brazilian Chemical Society (Online)
repository_id_str
spelling Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Toolsbiodieselmid-infrared spectroscopychemometrics toolsmultivariate control chartsPLSThis paper presents methodologies for monitoring the quality of methyl cotton biodiesel in biodiesel/diesel blends using mid-infrared spectroscopy (MIR) and chemometrics tools. The first method relates to the construction of multivariate control charts with the aim of qualitatively monitoring the samples according to the Brazilian specification for biodiesel in the biodiesel/diesel blends (7.00 ± 0.5% v/v of biodiesel). The second concerns the construction of partial least squares (PLS) to determine the content of the biodiesel in the biodiesel/diesel blend. The PLS model was validated from multivariate figures of merit according to the guidelines of ASTM E1655-05 and IUPAC. The results from both methods were satisfactory for both qualitative and quantitative monitoring. Therefore, the proposed methodologies for monitoring the quality of biodiesel in biodiesel/diesel blends are fast, practical, economical and efficient and can be used by industries and service stations.Sociedade Brasileira de Química2016-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100084Journal of the Brazilian Chemical Society v.27 n.1 2016reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20150251info:eu-repo/semantics/openAccessBuiatte,José EduardoGuimarães,EloízaMitsutake,HeryGontijo,Lucas CaixetaSantos,Douglas QueirozBorges Neto,Waldomiroeng2016-03-09T00:00:00Zoai:scielo:S0103-50532016000100084Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2016-03-09T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
title Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
spellingShingle Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
Buiatte,José Eduardo
biodiesel
mid-infrared spectroscopy
chemometrics tools
multivariate control charts
PLS
title_short Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
title_full Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
title_fullStr Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
title_full_unstemmed Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
title_sort Qualitative and Quantitative Monitoring of Methyl Cotton Biodiesel Content in Biodiesel/Diesel Blends Using MIR Spectroscopy and Chemometrics Tools
author Buiatte,José Eduardo
author_facet Buiatte,José Eduardo
Guimarães,Eloíza
Mitsutake,Hery
Gontijo,Lucas Caixeta
Santos,Douglas Queiroz
Borges Neto,Waldomiro
author_role author
author2 Guimarães,Eloíza
Mitsutake,Hery
Gontijo,Lucas Caixeta
Santos,Douglas Queiroz
Borges Neto,Waldomiro
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Buiatte,José Eduardo
Guimarães,Eloíza
Mitsutake,Hery
Gontijo,Lucas Caixeta
Santos,Douglas Queiroz
Borges Neto,Waldomiro
dc.subject.por.fl_str_mv biodiesel
mid-infrared spectroscopy
chemometrics tools
multivariate control charts
PLS
topic biodiesel
mid-infrared spectroscopy
chemometrics tools
multivariate control charts
PLS
description This paper presents methodologies for monitoring the quality of methyl cotton biodiesel in biodiesel/diesel blends using mid-infrared spectroscopy (MIR) and chemometrics tools. The first method relates to the construction of multivariate control charts with the aim of qualitatively monitoring the samples according to the Brazilian specification for biodiesel in the biodiesel/diesel blends (7.00 ± 0.5% v/v of biodiesel). The second concerns the construction of partial least squares (PLS) to determine the content of the biodiesel in the biodiesel/diesel blend. The PLS model was validated from multivariate figures of merit according to the guidelines of ASTM E1655-05 and IUPAC. The results from both methods were satisfactory for both qualitative and quantitative monitoring. Therefore, the proposed methodologies for monitoring the quality of biodiesel in biodiesel/diesel blends are fast, practical, economical and efficient and can be used by industries and service stations.
publishDate 2016
dc.date.none.fl_str_mv 2016-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100084
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100084
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20150251
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.27 n.1 2016
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318177901871104

Registros relacionados