Structural study and fluorescent property of a novel organic microporous crystalline material
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000100014 |
Resumo: | A novel microporous organic material [(2-{2-[2-(bis-methoxycarbonylmethylamino)phenoxy]ethoxy}-4-benzimidazole-phenyl)methoxycarbonylmethylamino]acetic acid methyl ester 6 was synthesized and characterized by single crystal X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), electron spray ionization-mass spectrometry (ESI-HRMS), X-ray powder diffraction (PXRD), ¹H and 13C NMR. 6 crystallizes in the centrosymmetric monoclinic space group C2/c, with unit cell parameters a = 35.648(3) Å, b = 14.3240(12) Å, c = 15.3693(13) Å, α= 90.00, β= 94.8190(10), γ = 90.00, V = 7820.16 ų and Z = 8 at 296(2) K. As indicated by crystal packing, the molecular conjugation planes arrange along the c axis to form micropores due to the hydrogen bonds. In addition, the fluorescent spectrum and luminescence lifetime were studied for 6. |
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Journal of the Brazilian Chemical Society (Online) |
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Structural study and fluorescent property of a novel organic microporous crystalline materialX-ray diffractionhydrogen bondmicroporosityfluorescenceluminescence lifetimeA novel microporous organic material [(2-{2-[2-(bis-methoxycarbonylmethylamino)phenoxy]ethoxy}-4-benzimidazole-phenyl)methoxycarbonylmethylamino]acetic acid methyl ester 6 was synthesized and characterized by single crystal X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), electron spray ionization-mass spectrometry (ESI-HRMS), X-ray powder diffraction (PXRD), ¹H and 13C NMR. 6 crystallizes in the centrosymmetric monoclinic space group C2/c, with unit cell parameters a = 35.648(3) Å, b = 14.3240(12) Å, c = 15.3693(13) Å, α= 90.00, β= 94.8190(10), γ = 90.00, V = 7820.16 ų and Z = 8 at 296(2) K. As indicated by crystal packing, the molecular conjugation planes arrange along the c axis to form micropores due to the hydrogen bonds. In addition, the fluorescent spectrum and luminescence lifetime were studied for 6.Sociedade Brasileira de Química2014-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000100014Journal of the Brazilian Chemical Society v.25 n.1 2014reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20130276info:eu-repo/semantics/openAccessCheng,ZhaoYang,BingqinYang,MeipanZhang,Binglineng2014-01-28T00:00:00Zoai:scielo:S0103-50532014000100014Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2014-01-28T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Structural study and fluorescent property of a novel organic microporous crystalline material |
title |
Structural study and fluorescent property of a novel organic microporous crystalline material |
spellingShingle |
Structural study and fluorescent property of a novel organic microporous crystalline material Cheng,Zhao X-ray diffraction hydrogen bond microporosity fluorescence luminescence lifetime |
title_short |
Structural study and fluorescent property of a novel organic microporous crystalline material |
title_full |
Structural study and fluorescent property of a novel organic microporous crystalline material |
title_fullStr |
Structural study and fluorescent property of a novel organic microporous crystalline material |
title_full_unstemmed |
Structural study and fluorescent property of a novel organic microporous crystalline material |
title_sort |
Structural study and fluorescent property of a novel organic microporous crystalline material |
author |
Cheng,Zhao |
author_facet |
Cheng,Zhao Yang,Bingqin Yang,Meipan Zhang,Binglin |
author_role |
author |
author2 |
Yang,Bingqin Yang,Meipan Zhang,Binglin |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Cheng,Zhao Yang,Bingqin Yang,Meipan Zhang,Binglin |
dc.subject.por.fl_str_mv |
X-ray diffraction hydrogen bond microporosity fluorescence luminescence lifetime |
topic |
X-ray diffraction hydrogen bond microporosity fluorescence luminescence lifetime |
description |
A novel microporous organic material [(2-{2-[2-(bis-methoxycarbonylmethylamino)phenoxy]ethoxy}-4-benzimidazole-phenyl)methoxycarbonylmethylamino]acetic acid methyl ester 6 was synthesized and characterized by single crystal X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), electron spray ionization-mass spectrometry (ESI-HRMS), X-ray powder diffraction (PXRD), ¹H and 13C NMR. 6 crystallizes in the centrosymmetric monoclinic space group C2/c, with unit cell parameters a = 35.648(3) Å, b = 14.3240(12) Å, c = 15.3693(13) Å, α= 90.00, β= 94.8190(10), γ = 90.00, V = 7820.16 ų and Z = 8 at 296(2) K. As indicated by crystal packing, the molecular conjugation planes arrange along the c axis to form micropores due to the hydrogen bonds. In addition, the fluorescent spectrum and luminescence lifetime were studied for 6. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000100014 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000100014 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20130276 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.25 n.1 2014 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318175687278592 |