NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes

Detalhes bibliográficos
Autor(a) principal: Gucma,Mirosław
Data de Publicação: 2013
Outros Autores: Gołębiewski,W. Marek, Krawczyk,Maria
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000500013
Resumo: The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D ¹H and 13C nuclear magnetic resonance (NMR).
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spelling NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes1,3-dipolar cycloadditionnorbornenesnitrile oxides2D NMRThe 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D ¹H and 13C nuclear magnetic resonance (NMR).Sociedade Brasileira de Química2013-05-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000500013Journal of the Brazilian Chemical Society v.24 n.5 2013reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20130106info:eu-repo/semantics/openAccessGucma,MirosławGołębiewski,W. MarekKrawczyk,Mariaeng2013-06-13T00:00:00Zoai:scielo:S0103-50532013000500013Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2013-06-13T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
title NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
spellingShingle NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
Gucma,Mirosław
1,3-dipolar cycloaddition
norbornenes
nitrile oxides
2D NMR
title_short NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
title_full NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
title_fullStr NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
title_full_unstemmed NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
title_sort NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
author Gucma,Mirosław
author_facet Gucma,Mirosław
Gołębiewski,W. Marek
Krawczyk,Maria
author_role author
author2 Gołębiewski,W. Marek
Krawczyk,Maria
author2_role author
author
dc.contributor.author.fl_str_mv Gucma,Mirosław
Gołębiewski,W. Marek
Krawczyk,Maria
dc.subject.por.fl_str_mv 1,3-dipolar cycloaddition
norbornenes
nitrile oxides
2D NMR
topic 1,3-dipolar cycloaddition
norbornenes
nitrile oxides
2D NMR
description The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D ¹H and 13C nuclear magnetic resonance (NMR).
publishDate 2013
dc.date.none.fl_str_mv 2013-05-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000500013
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000500013
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20130106
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.24 n.5 2013
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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