Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light

Detalhes bibliográficos
Autor(a) principal: Santos,Thiago Augusto D.
Data de Publicação: 2017
Outros Autores: Yotsumoto Neto,Sakae, Macena,Cleidivan S., Luz,Rita de Cássia S., Damos,Flávio S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901752
Resumo: In this study, a photoelectroanalytical sensor for determination of adrenaline based on deoxyribonucleic acid (DNA) and anatase titanium dioxide (TiO2) nanoparticles sensitized with bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) was developed, which we henceforward call BEDT-TTF/DNA/TiO2/ITO. The photoelectroanalytical sensor showed high photocurrent to adrenaline under visible light emitting diode (LED) light irradiation in comparison to each component of the composite material. Under optimized conditions, the BEDT-TTF/DNA/TiO2/ITO sensor shows a linear response range from 10 nmol L-1 up to 100 µmol L-1 with a sensitivity of 8.1 nA L µmol-1 and limit of detection of 1 nmol L-1 for the detection of adrenaline. The photoelectrochemical sensor showed high photocurrent to adrenaline in comparison to photocurrent response to ascorbic acid and uric acid. The BEDT-TTF/DNA/TiO2/ITO photoelectrochemical sensor was successfully applied to urine samples, with recovery values between 96 and 106%.
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spelling Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Lightadrenalinephotoelectrochemical sensorvisible LED lightdeoxyribonucleic acidIn this study, a photoelectroanalytical sensor for determination of adrenaline based on deoxyribonucleic acid (DNA) and anatase titanium dioxide (TiO2) nanoparticles sensitized with bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) was developed, which we henceforward call BEDT-TTF/DNA/TiO2/ITO. The photoelectroanalytical sensor showed high photocurrent to adrenaline under visible light emitting diode (LED) light irradiation in comparison to each component of the composite material. Under optimized conditions, the BEDT-TTF/DNA/TiO2/ITO sensor shows a linear response range from 10 nmol L-1 up to 100 µmol L-1 with a sensitivity of 8.1 nA L µmol-1 and limit of detection of 1 nmol L-1 for the detection of adrenaline. The photoelectrochemical sensor showed high photocurrent to adrenaline in comparison to photocurrent response to ascorbic acid and uric acid. The BEDT-TTF/DNA/TiO2/ITO photoelectrochemical sensor was successfully applied to urine samples, with recovery values between 96 and 106%.Sociedade Brasileira de Química2017-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901752Journal of the Brazilian Chemical Society v.28 n.9 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20170026info:eu-repo/semantics/openAccessSantos,Thiago Augusto D.Yotsumoto Neto,SakaeMacena,Cleidivan S.Luz,Rita de Cássia S.Damos,Flávio S.eng2017-07-28T00:00:00Zoai:scielo:S0103-50532017000901752Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-07-28T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
title Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
spellingShingle Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
Santos,Thiago Augusto D.
adrenaline
photoelectrochemical sensor
visible LED light
deoxyribonucleic acid
title_short Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
title_full Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
title_fullStr Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
title_full_unstemmed Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
title_sort Photoelectroanalytical Detection of Adrenaline Based on DNA and TiO 2 Nanoparticles Sensitized with Bis(ethylenedithio)tetrathiafulvalene Exploiting LED Light
author Santos,Thiago Augusto D.
author_facet Santos,Thiago Augusto D.
Yotsumoto Neto,Sakae
Macena,Cleidivan S.
Luz,Rita de Cássia S.
Damos,Flávio S.
author_role author
author2 Yotsumoto Neto,Sakae
Macena,Cleidivan S.
Luz,Rita de Cássia S.
Damos,Flávio S.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Santos,Thiago Augusto D.
Yotsumoto Neto,Sakae
Macena,Cleidivan S.
Luz,Rita de Cássia S.
Damos,Flávio S.
dc.subject.por.fl_str_mv adrenaline
photoelectrochemical sensor
visible LED light
deoxyribonucleic acid
topic adrenaline
photoelectrochemical sensor
visible LED light
deoxyribonucleic acid
description In this study, a photoelectroanalytical sensor for determination of adrenaline based on deoxyribonucleic acid (DNA) and anatase titanium dioxide (TiO2) nanoparticles sensitized with bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) was developed, which we henceforward call BEDT-TTF/DNA/TiO2/ITO. The photoelectroanalytical sensor showed high photocurrent to adrenaline under visible light emitting diode (LED) light irradiation in comparison to each component of the composite material. Under optimized conditions, the BEDT-TTF/DNA/TiO2/ITO sensor shows a linear response range from 10 nmol L-1 up to 100 µmol L-1 with a sensitivity of 8.1 nA L µmol-1 and limit of detection of 1 nmol L-1 for the detection of adrenaline. The photoelectrochemical sensor showed high photocurrent to adrenaline in comparison to photocurrent response to ascorbic acid and uric acid. The BEDT-TTF/DNA/TiO2/ITO photoelectrochemical sensor was successfully applied to urine samples, with recovery values between 96 and 106%.
publishDate 2017
dc.date.none.fl_str_mv 2017-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901752
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901752
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0103-5053.20170026
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.28 n.9 2017
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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