Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001100021 |
Resumo: | Ionic liquids (ILs) are salts which are liquid at low temperatures, typically with melting points under 100 ºC. In recent years, the properties of many ILs have been extensively studied and have been considered as green solvents capable of replacing traditional organic solvents. Herein, ILs derived from triazole have been synthesized, thus solubility in different solvents increases with the dielectric constant of the considered solvents. Three novel 1,2,3-triazolium-based were used for the pretreatment of sugarcane bagasse. The effect of this pretreatment on lignocellulosic biomass was analyzed by scanning electron microscopy, showing an increase in the exposure surface of the bagasse samples as structural changes in the fiber. |
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Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagassesugarcane bagassesynthesisionic liquidsclick reactionpretreatmentIonic liquids (ILs) are salts which are liquid at low temperatures, typically with melting points under 100 ºC. In recent years, the properties of many ILs have been extensively studied and have been considered as green solvents capable of replacing traditional organic solvents. Herein, ILs derived from triazole have been synthesized, thus solubility in different solvents increases with the dielectric constant of the considered solvents. Three novel 1,2,3-triazolium-based were used for the pretreatment of sugarcane bagasse. The effect of this pretreatment on lignocellulosic biomass was analyzed by scanning electron microscopy, showing an increase in the exposure surface of the bagasse samples as structural changes in the fiber.Sociedade Brasileira de Química2014-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001100021Journal of the Brazilian Chemical Society v.25 n.11 2014reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20140198info:eu-repo/semantics/openAccessCarmo,Arturene M. L.Stroppa,Pedro H. F.Corrales,Roberta C. N. R.Barroso,Anna B. N.Ferreira-Leitão,Viridiana S.Silva,Adilson D.eng2014-11-13T00:00:00Zoai:scielo:S0103-50532014001100021Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2014-11-13T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
title |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
spellingShingle |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse Carmo,Arturene M. L. sugarcane bagasse synthesis ionic liquids click reaction pretreatment |
title_short |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
title_full |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
title_fullStr |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
title_full_unstemmed |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
title_sort |
Synthesis of 1,2,3-triazolium-based ionic liquid and preliminary pretreatment to enhance hydrolysis of sugarcane bagasse |
author |
Carmo,Arturene M. L. |
author_facet |
Carmo,Arturene M. L. Stroppa,Pedro H. F. Corrales,Roberta C. N. R. Barroso,Anna B. N. Ferreira-Leitão,Viridiana S. Silva,Adilson D. |
author_role |
author |
author2 |
Stroppa,Pedro H. F. Corrales,Roberta C. N. R. Barroso,Anna B. N. Ferreira-Leitão,Viridiana S. Silva,Adilson D. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Carmo,Arturene M. L. Stroppa,Pedro H. F. Corrales,Roberta C. N. R. Barroso,Anna B. N. Ferreira-Leitão,Viridiana S. Silva,Adilson D. |
dc.subject.por.fl_str_mv |
sugarcane bagasse synthesis ionic liquids click reaction pretreatment |
topic |
sugarcane bagasse synthesis ionic liquids click reaction pretreatment |
description |
Ionic liquids (ILs) are salts which are liquid at low temperatures, typically with melting points under 100 ºC. In recent years, the properties of many ILs have been extensively studied and have been considered as green solvents capable of replacing traditional organic solvents. Herein, ILs derived from triazole have been synthesized, thus solubility in different solvents increases with the dielectric constant of the considered solvents. Three novel 1,2,3-triazolium-based were used for the pretreatment of sugarcane bagasse. The effect of this pretreatment on lignocellulosic biomass was analyzed by scanning electron microscopy, showing an increase in the exposure surface of the bagasse samples as structural changes in the fiber. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-11-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001100021 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014001100021 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20140198 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.25 n.11 2014 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318176571228160 |